Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order Conditions
Computer-based simulations for the three-body recombination reaction of nitrogen (II) oxide with the hydroxyl radical have been used to estimate the error associated with the pseudo-first order approximation under different simulated conditions. For the absolute rate coefficients calculated by divid...
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| Format: | Article |
| Language: | English |
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Turkish Chemical Society
2017-10-01
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| Series: | Journal of the Turkish Chemical Society, Section A: Chemistry |
| Subjects: | |
| Online Access: | http://dergipark.gov.tr/jotcsa/issue/31055/333857#author673603 |
| _version_ | 1797905761935818752 |
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| author | Luca D'Ottone Enunuwe Ochonogor |
| author_facet | Luca D'Ottone Enunuwe Ochonogor |
| author_sort | Luca D'Ottone |
| collection | DOAJ |
| description | Computer-based simulations for the three-body recombination reaction of nitrogen (II) oxide with the hydroxyl radical have been used to estimate the error associated with the pseudo-first order approximation under different simulated conditions. For the absolute rate coefficients calculated by dividing the pseudo-first order constant by the concentration of the reactant in excess, the analysis of the relative error associated with working under pseudo-first order conditions shows that for a reactants’ ratio higher than 10, the relative error is less than 5%. |
| first_indexed | 2024-04-10T10:10:24Z |
| format | Article |
| id | doaj.art-9edbaabeea3249d084e450062ae0ddee |
| institution | Directory Open Access Journal |
| issn | 2149-0120 |
| language | English |
| last_indexed | 2024-04-10T10:10:24Z |
| publishDate | 2017-10-01 |
| publisher | Turkish Chemical Society |
| record_format | Article |
| series | Journal of the Turkish Chemical Society, Section A: Chemistry |
| spelling | doaj.art-9edbaabeea3249d084e450062ae0ddee2023-02-15T16:22:13ZengTurkish Chemical SocietyJournal of the Turkish Chemical Society, Section A: Chemistry2149-01202017-10-0151294010.18596/jotcsa.333857Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order ConditionsLuca D'Ottone0Enunuwe Ochonogor1Miami Dade CollegeCape Peninsula University of TechnologyComputer-based simulations for the three-body recombination reaction of nitrogen (II) oxide with the hydroxyl radical have been used to estimate the error associated with the pseudo-first order approximation under different simulated conditions. For the absolute rate coefficients calculated by dividing the pseudo-first order constant by the concentration of the reactant in excess, the analysis of the relative error associated with working under pseudo-first order conditions shows that for a reactants’ ratio higher than 10, the relative error is less than 5%.http://dergipark.gov.tr/jotcsa/issue/31055/333857#author673603Pseudo-first order conditionsabsolute rate coefficientcomputer simulations |
| spellingShingle | Luca D'Ottone Enunuwe Ochonogor Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order Conditions Journal of the Turkish Chemical Society, Section A: Chemistry Pseudo-first order conditions absolute rate coefficient computer simulations |
| title | Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order Conditions |
| title_full | Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order Conditions |
| title_fullStr | Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order Conditions |
| title_full_unstemmed | Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order Conditions |
| title_short | Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order Conditions |
| title_sort | error analysis of absolute rate coefficient extrapolated under pseudo first order conditions |
| topic | Pseudo-first order conditions absolute rate coefficient computer simulations |
| url | http://dergipark.gov.tr/jotcsa/issue/31055/333857#author673603 |
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