C—I...N short contacts as tools for the construction of the crystal packing in the crystal structure of 3,3′-(ethane-1,2-diyl)bis(6-iodo-3,4-dihydro-2H-1,3-benzoxazine)
The asymmetric unit of the title compound, C18H18I2N2O2, consists of one half-molecule, completed by the application of inversion symmetry. The molecule adopts the typical structure for this class of bis-benxozazines, characterized by an anti orientation of the two benzoxazine rings around the centr...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-05-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989017005047 |
| _version_ | 1818998749986291712 |
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| author | Augusto Rivera Jicli José Rojas Jaime Ríos-Motta Michael Bolte |
| author_facet | Augusto Rivera Jicli José Rojas Jaime Ríos-Motta Michael Bolte |
| author_sort | Augusto Rivera |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, C18H18I2N2O2, consists of one half-molecule, completed by the application of inversion symmetry. The molecule adopts the typical structure for this class of bis-benxozazines, characterized by an anti orientation of the two benzoxazine rings around the central C—C bond. The oxazinic ring adopts a half-chair conformation. In the crystal, molecules are linked by C—I...N short contacts [I...N = 3.378 (2) Å], generating layers lying parallel to the bc plane. |
| first_indexed | 2024-12-20T22:06:29Z |
| format | Article |
| id | doaj.art-9eece40147634446bc88a862172570a3 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T22:06:29Z |
| publishDate | 2017-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-9eece40147634446bc88a862172570a32022-12-21T19:25:15ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-05-0173566466610.1107/S2056989017005047hb7668C—I...N short contacts as tools for the construction of the crystal packing in the crystal structure of 3,3′-(ethane-1,2-diyl)bis(6-iodo-3,4-dihydro-2H-1,3-benzoxazine)Augusto Rivera0Jicli José Rojas1Jaime Ríos-Motta2Michael Bolte3Universidad Nacional de Colombia, Sede Bogotá, Facultad de Ciencias, Departamento de Química, Cra 30 No. 45-03, Bogotá, Código Postal 111321, ColombiaUniversidad Nacional de Colombia, Sede Bogotá, Facultad de Ciencias, Departamento de Química, Cra 30 No. 45-03, Bogotá, Código Postal 111321, ColombiaUniversidad Nacional de Colombia, Sede Bogotá, Facultad de Ciencias, Departamento de Química, Cra 30 No. 45-03, Bogotá, Código Postal 111321, ColombiaInstitut für Anorganische Chemie, J. W. Goethe-Universität Frankfurt, Max-von Laue-Strasse 7, 60438 Frankfurt/Main, GermanyThe asymmetric unit of the title compound, C18H18I2N2O2, consists of one half-molecule, completed by the application of inversion symmetry. The molecule adopts the typical structure for this class of bis-benxozazines, characterized by an anti orientation of the two benzoxazine rings around the central C—C bond. The oxazinic ring adopts a half-chair conformation. In the crystal, molecules are linked by C—I...N short contacts [I...N = 3.378 (2) Å], generating layers lying parallel to the bc plane.http://scripts.iucr.org/cgi-bin/paper?S2056989017005047crystal structureshort contactsbenzoxazinesphenolic resins |
| spellingShingle | Augusto Rivera Jicli José Rojas Jaime Ríos-Motta Michael Bolte C—I...N short contacts as tools for the construction of the crystal packing in the crystal structure of 3,3′-(ethane-1,2-diyl)bis(6-iodo-3,4-dihydro-2H-1,3-benzoxazine) Acta Crystallographica Section E: Crystallographic Communications crystal structure short contacts benzoxazines phenolic resins |
| title | C—I...N short contacts as tools for the construction of the crystal packing in the crystal structure of 3,3′-(ethane-1,2-diyl)bis(6-iodo-3,4-dihydro-2H-1,3-benzoxazine) |
| title_full | C—I...N short contacts as tools for the construction of the crystal packing in the crystal structure of 3,3′-(ethane-1,2-diyl)bis(6-iodo-3,4-dihydro-2H-1,3-benzoxazine) |
| title_fullStr | C—I...N short contacts as tools for the construction of the crystal packing in the crystal structure of 3,3′-(ethane-1,2-diyl)bis(6-iodo-3,4-dihydro-2H-1,3-benzoxazine) |
| title_full_unstemmed | C—I...N short contacts as tools for the construction of the crystal packing in the crystal structure of 3,3′-(ethane-1,2-diyl)bis(6-iodo-3,4-dihydro-2H-1,3-benzoxazine) |
| title_short | C—I...N short contacts as tools for the construction of the crystal packing in the crystal structure of 3,3′-(ethane-1,2-diyl)bis(6-iodo-3,4-dihydro-2H-1,3-benzoxazine) |
| title_sort | c i n short contacts as tools for the construction of the crystal packing in the crystal structure of 3 3 ethane 1 2 diyl bis 6 iodo 3 4 dihydro 2h 1 3 benzoxazine |
| topic | crystal structure short contacts benzoxazines phenolic resins |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989017005047 |
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