Kinetics of Ion-Capturing/Ion-Releasing Processes in Liquid Crystal Devices Utilizing Contaminated Nanoparticles and Alignment Films

Various types of nanomaterials and alignment layers are considered major components of the next generation of advanced liquid crystal devices. While the steady-state properties of ion-capturing/ion-releasing processes in liquid crystals doped with nanoparticles and sandwiched between alignment films...

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Main Author: Yuriy Garbovskiy
Format: Article
Language:English
Published: MDPI AG 2018-01-01
Series:Nanomaterials
Subjects:
Online Access:http://www.mdpi.com/2079-4991/8/2/59
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author Yuriy Garbovskiy
author_facet Yuriy Garbovskiy
author_sort Yuriy Garbovskiy
collection DOAJ
description Various types of nanomaterials and alignment layers are considered major components of the next generation of advanced liquid crystal devices. While the steady-state properties of ion-capturing/ion-releasing processes in liquid crystals doped with nanoparticles and sandwiched between alignment films are relatively well understood, the kinetics of these phenomena remains practically unexplored. In this paper, the time dependence of ion-capturing/ion-releasing processes in liquid crystal cells utilizing contaminated nanoparticles and alignment layers is analyzed. The ionic contamination of both nanodopants and alignment films governs the switching between ion-capturing and ion-releasing regimes. The time dependence (both monotonous and non-monotonous) of these processes is characterized by time constants originated from the presence of nanoparticles and films, respectively. These time constants depend on the ion adsorption/ion desorption parameters and can be tuned by changing the concentration of nanoparticles, their size, and the cell thickness.
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spelling doaj.art-9ef9abc9ddbf4e52a05fbe57fbcda0002022-12-21T19:05:46ZengMDPI AGNanomaterials2079-49912018-01-01825910.3390/nano8020059nano8020059Kinetics of Ion-Capturing/Ion-Releasing Processes in Liquid Crystal Devices Utilizing Contaminated Nanoparticles and Alignment FilmsYuriy Garbovskiy0UCCS BioFrontiers Center and Department of Physics, University of Colorado Colorado Springs, Colorado Springs, CO 80918, USAVarious types of nanomaterials and alignment layers are considered major components of the next generation of advanced liquid crystal devices. While the steady-state properties of ion-capturing/ion-releasing processes in liquid crystals doped with nanoparticles and sandwiched between alignment films are relatively well understood, the kinetics of these phenomena remains practically unexplored. In this paper, the time dependence of ion-capturing/ion-releasing processes in liquid crystal cells utilizing contaminated nanoparticles and alignment layers is analyzed. The ionic contamination of both nanodopants and alignment films governs the switching between ion-capturing and ion-releasing regimes. The time dependence (both monotonous and non-monotonous) of these processes is characterized by time constants originated from the presence of nanoparticles and films, respectively. These time constants depend on the ion adsorption/ion desorption parameters and can be tuned by changing the concentration of nanoparticles, their size, and the cell thickness.http://www.mdpi.com/2079-4991/8/2/59liquid crystalsionscontaminated nanoparticleskineticsion-capturing filmsion trappingadsorption/desorption
spellingShingle Yuriy Garbovskiy
Kinetics of Ion-Capturing/Ion-Releasing Processes in Liquid Crystal Devices Utilizing Contaminated Nanoparticles and Alignment Films
Nanomaterials
liquid crystals
ions
contaminated nanoparticles
kinetics
ion-capturing films
ion trapping
adsorption/desorption
title Kinetics of Ion-Capturing/Ion-Releasing Processes in Liquid Crystal Devices Utilizing Contaminated Nanoparticles and Alignment Films
title_full Kinetics of Ion-Capturing/Ion-Releasing Processes in Liquid Crystal Devices Utilizing Contaminated Nanoparticles and Alignment Films
title_fullStr Kinetics of Ion-Capturing/Ion-Releasing Processes in Liquid Crystal Devices Utilizing Contaminated Nanoparticles and Alignment Films
title_full_unstemmed Kinetics of Ion-Capturing/Ion-Releasing Processes in Liquid Crystal Devices Utilizing Contaminated Nanoparticles and Alignment Films
title_short Kinetics of Ion-Capturing/Ion-Releasing Processes in Liquid Crystal Devices Utilizing Contaminated Nanoparticles and Alignment Films
title_sort kinetics of ion capturing ion releasing processes in liquid crystal devices utilizing contaminated nanoparticles and alignment films
topic liquid crystals
ions
contaminated nanoparticles
kinetics
ion-capturing films
ion trapping
adsorption/desorption
url http://www.mdpi.com/2079-4991/8/2/59
work_keys_str_mv AT yuriygarbovskiy kineticsofioncapturingionreleasingprocessesinliquidcrystaldevicesutilizingcontaminatednanoparticlesandalignmentfilms