Bis(μ-2-methylquinolin-1-ium-8-olato-κ2O:O′)bis[(2-methylquinolin-1-ium-8-olato-κO)tris(nitrato-κ2O,O′)lanthanum(III)]
The two independent N-heterocycles in the centrosymmetric title compound, [La2(C10H9NO)4(NO3)6], exist in the zwitterionic form. One of these binds to one metal center, whereas the other bridges two metal centers. The La atom is chelated by three nitrate groups and is surrounded by nine O atoms in a...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809019746 |
| _version_ | 1818282680351981568 |
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| author | Yousef Fazaeli Ezzatollah Najafi Mostafa M. Amini Seik Weng Ng |
| author_facet | Yousef Fazaeli Ezzatollah Najafi Mostafa M. Amini Seik Weng Ng |
| author_sort | Yousef Fazaeli |
| collection | DOAJ |
| description | The two independent N-heterocycles in the centrosymmetric title compound, [La2(C10H9NO)4(NO3)6], exist in the zwitterionic form. One of these binds to one metal center, whereas the other bridges two metal centers. The La atom is chelated by three nitrate groups and is surrounded by nine O atoms in a coordination environment based on a distorted monocapped square-antiprism. The dinuclear structure is further stabilized by intramolecular N—H...O(nitrate) hydrogen bonds. |
| first_indexed | 2024-12-13T00:24:52Z |
| format | Article |
| id | doaj.art-9f2677bb72644ed7b453625dae32d21c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:24:52Z |
| publishDate | 2009-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9f2677bb72644ed7b453625dae32d21c2022-12-22T00:05:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657m711m71110.1107/S1600536809019746Bis(μ-2-methylquinolin-1-ium-8-olato-κ2O:O′)bis[(2-methylquinolin-1-ium-8-olato-κO)tris(nitrato-κ2O,O′)lanthanum(III)]Yousef FazaeliEzzatollah NajafiMostafa M. AminiSeik Weng NgThe two independent N-heterocycles in the centrosymmetric title compound, [La2(C10H9NO)4(NO3)6], exist in the zwitterionic form. One of these binds to one metal center, whereas the other bridges two metal centers. The La atom is chelated by three nitrate groups and is surrounded by nine O atoms in a coordination environment based on a distorted monocapped square-antiprism. The dinuclear structure is further stabilized by intramolecular N—H...O(nitrate) hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536809019746 |
| spellingShingle | Yousef Fazaeli Ezzatollah Najafi Mostafa M. Amini Seik Weng Ng Bis(μ-2-methylquinolin-1-ium-8-olato-κ2O:O′)bis[(2-methylquinolin-1-ium-8-olato-κO)tris(nitrato-κ2O,O′)lanthanum(III)] Acta Crystallographica Section E |
| title | Bis(μ-2-methylquinolin-1-ium-8-olato-κ2O:O′)bis[(2-methylquinolin-1-ium-8-olato-κO)tris(nitrato-κ2O,O′)lanthanum(III)] |
| title_full | Bis(μ-2-methylquinolin-1-ium-8-olato-κ2O:O′)bis[(2-methylquinolin-1-ium-8-olato-κO)tris(nitrato-κ2O,O′)lanthanum(III)] |
| title_fullStr | Bis(μ-2-methylquinolin-1-ium-8-olato-κ2O:O′)bis[(2-methylquinolin-1-ium-8-olato-κO)tris(nitrato-κ2O,O′)lanthanum(III)] |
| title_full_unstemmed | Bis(μ-2-methylquinolin-1-ium-8-olato-κ2O:O′)bis[(2-methylquinolin-1-ium-8-olato-κO)tris(nitrato-κ2O,O′)lanthanum(III)] |
| title_short | Bis(μ-2-methylquinolin-1-ium-8-olato-κ2O:O′)bis[(2-methylquinolin-1-ium-8-olato-κO)tris(nitrato-κ2O,O′)lanthanum(III)] |
| title_sort | bis amp 956 2 methylquinolin 1 ium 8 olato amp 954 2o o amp 8242 bis 2 methylquinolin 1 ium 8 olato amp 954 o tris nitrato amp 954 2o o amp 8242 lanthanum iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809019746 |
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