Synthesis, Structure and Investigation of Germanium(IV) and Copper(II) Complexes with Malic Acid and 1,10ʹ-phenanthroline
Two crystalline compounds of germanium(IV) with malic acid (HMal) and 1,10ʹ-phenanthroline (phen) - [Ge(HMal)2(phen)]•pheh•2H2O (I) and [CuCl(phen)2][Ge(OH)(HMal)2] (II) were synthesized for the first time and characterized by elemental analysis, IR-spectroscopy and thermogravimetric analysis. There...
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| Format: | Article |
| Language: | English |
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Academy of Sciences of Moldova, Institute of Chemistry
2017-12-01
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| Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
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http://cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2016.369-Martsinko.pdf
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| author | Inna Seifullina Elena Martsinko Elena Chebanenko Eleonora Afanasenko Viktoriya Dyakonenko Svitlana Shishkina |
| author_facet | Inna Seifullina Elena Martsinko Elena Chebanenko Eleonora Afanasenko Viktoriya Dyakonenko Svitlana Shishkina |
| author_sort | Inna Seifullina |
| collection | DOAJ |
| description | Two crystalline compounds of germanium(IV) with malic acid (HMal) and 1,10ʹ-phenanthroline (phen) - [Ge(HMal)2(phen)]•pheh•2H2O (I) and [CuCl(phen)2][Ge(OH)(HMal)2] (II) were synthesized for the first time and characterized by elemental analysis, IR-spectroscopy and thermogravimetric analysis. There was elucidated from single-crystal X-ray diffraction that two different forms of Germanium are implemented: Ge4+ (I) and hydrolyzed GeOH3+ (II) to form distorted octahedron and pyramid respectively. |
| first_indexed | 2024-12-16T07:25:06Z |
| format | Article |
| id | doaj.art-9f4658e1ff1b4158a3a851d26b0178d1 |
| institution | Directory Open Access Journal |
| issn | 1857-1727 2345-1688 |
| language | English |
| last_indexed | 2024-12-16T07:25:06Z |
| publishDate | 2017-12-01 |
| publisher | Academy of Sciences of Moldova, Institute of Chemistry |
| record_format | Article |
| series | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| spelling | doaj.art-9f4658e1ff1b4158a3a851d26b0178d12022-12-21T22:39:32ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882017-12-01122283310.19261/cjm.2016.369369Synthesis, Structure and Investigation of Germanium(IV) and Copper(II) Complexes with Malic Acid and 1,10ʹ-phenanthrolineInna Seifullina0Elena Martsinko1Elena Chebanenko2Eleonora Afanasenko3Viktoriya Dyakonenko4Svitlana Shishkina5 I.I. Mechnikov Odessa National University, Odessa 65082, Ukraine I.I. Mechnikov Odessa National University, Odessa 65082, Ukraine I.I. Mechnikov Odessa National University, Odessa 65082, Ukraine I.I. Mechnikov Odessa National University, Odessa 65082, Ukraine SSI “Institute for Single Crystals”, National Academy of Sciences of Ukraine, 60, Nauki Ave., Kharkiv 61001, Ukraine SSI “Institute for Single Crystals”, National Academy of Sciences of Ukraine, 60, Nauki Ave., Kharkiv 61001, Ukraine Two crystalline compounds of germanium(IV) with malic acid (HMal) and 1,10ʹ-phenanthroline (phen) - [Ge(HMal)2(phen)]•pheh•2H2O (I) and [CuCl(phen)2][Ge(OH)(HMal)2] (II) were synthesized for the first time and characterized by elemental analysis, IR-spectroscopy and thermogravimetric analysis. There was elucidated from single-crystal X-ray diffraction that two different forms of Germanium are implemented: Ge4+ (I) and hydrolyzed GeOH3+ (II) to form distorted octahedron and pyramid respectively. http://cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2016.369-Martsinko.pdf germanium(IV) compoundsmalic acid1,10ʹ-phenanthrolinecopper(II) complexstructure |
| spellingShingle | Inna Seifullina Elena Martsinko Elena Chebanenko Eleonora Afanasenko Viktoriya Dyakonenko Svitlana Shishkina Synthesis, Structure and Investigation of Germanium(IV) and Copper(II) Complexes with Malic Acid and 1,10ʹ-phenanthroline Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry germanium(IV) compounds malic acid 1,10ʹ-phenanthroline copper(II) complex structure |
| title | Synthesis, Structure and Investigation of Germanium(IV) and Copper(II) Complexes with Malic Acid and 1,10ʹ-phenanthroline |
| title_full | Synthesis, Structure and Investigation of Germanium(IV) and Copper(II) Complexes with Malic Acid and 1,10ʹ-phenanthroline |
| title_fullStr | Synthesis, Structure and Investigation of Germanium(IV) and Copper(II) Complexes with Malic Acid and 1,10ʹ-phenanthroline |
| title_full_unstemmed | Synthesis, Structure and Investigation of Germanium(IV) and Copper(II) Complexes with Malic Acid and 1,10ʹ-phenanthroline |
| title_short | Synthesis, Structure and Investigation of Germanium(IV) and Copper(II) Complexes with Malic Acid and 1,10ʹ-phenanthroline |
| title_sort | synthesis structure and investigation of germanium iv and copper ii complexes with malic acid and 1 10 phenanthroline |
| topic | germanium(IV) compounds malic acid 1,10ʹ-phenanthroline copper(II) complex structure |
| url |
http://cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2016.369-Martsinko.pdf
|
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