A High-Performance Optoelectronic Sensor Device for Nitrate Nitrogen in Recirculating Aquaculture Systems

The determination of nitrate nitrogen (NO3-N) in recirculating aquaculture systems is of great significance for the health assessment of the living environment of aquatic animals. Unfortunately, the commonly used spectrophotometric methods often yield unstable results, especially when the ambient te...

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Main Authors: Cong Wang, Zhen Li, Zhongli Pan, Daoliang Li
Format: Article
Language:English
Published: MDPI AG 2018-10-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/18/10/3382
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author Cong Wang
Zhen Li
Zhongli Pan
Daoliang Li
author_facet Cong Wang
Zhen Li
Zhongli Pan
Daoliang Li
author_sort Cong Wang
collection DOAJ
description The determination of nitrate nitrogen (NO3-N) in recirculating aquaculture systems is of great significance for the health assessment of the living environment of aquatic animals. Unfortunately, the commonly used spectrophotometric methods often yield unstable results, especially when the ambient temperature varies greatly in the field measurement. Here, we have developed a novel handheld absorbance measurement sensor based on the thymol-NO3-N chromogenic rearrangement reaction. In terms of hardware, the sensor adopts a dual channel/dual wavelength colorimeter structure that features a modulated light source transmitter and a synchronous detector receiver. The circuit measures the ratio of light absorbed by the sample and reference containers at two LEDs with peak wavelengths at 420 nm and 450 nm. Using the modulated source and synchronous detector rather than a constant (DC) source eliminates measurement errors due to ambient light and low frequency noise and provides higher accuracy. In terms of software, we design a new quantitative analysis algorithm for absorbance by studying colloid absorbing behavior. The application of a buffer operator embedded in the algorithm makes the sensor get the environmental correction function. The results have shown that the sensitivity, repeatability, precision and environmental stability are higher than that by ordinary spectrophotometry. Lastly, we have a brief overview of future work.
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spelling doaj.art-9f492029163f4a89ae482f6b71fc07412022-12-22T04:03:47ZengMDPI AGSensors1424-82202018-10-011810338210.3390/s18103382s18103382A High-Performance Optoelectronic Sensor Device for Nitrate Nitrogen in Recirculating Aquaculture SystemsCong Wang0Zhen Li1Zhongli Pan2Daoliang Li3College of Information and Electrical Engineering, China Agricultural University, Beijing 100083, ChinaCollege of Information and Electrical Engineering, China Agricultural University, Beijing 100083, ChinaHealthy Processed Foods Research Unit, USDA-ARS-WRRC, 800 Buchanan St., Albany, CA 94710, USACollege of Information and Electrical Engineering, China Agricultural University, Beijing 100083, ChinaThe determination of nitrate nitrogen (NO3-N) in recirculating aquaculture systems is of great significance for the health assessment of the living environment of aquatic animals. Unfortunately, the commonly used spectrophotometric methods often yield unstable results, especially when the ambient temperature varies greatly in the field measurement. Here, we have developed a novel handheld absorbance measurement sensor based on the thymol-NO3-N chromogenic rearrangement reaction. In terms of hardware, the sensor adopts a dual channel/dual wavelength colorimeter structure that features a modulated light source transmitter and a synchronous detector receiver. The circuit measures the ratio of light absorbed by the sample and reference containers at two LEDs with peak wavelengths at 420 nm and 450 nm. Using the modulated source and synchronous detector rather than a constant (DC) source eliminates measurement errors due to ambient light and low frequency noise and provides higher accuracy. In terms of software, we design a new quantitative analysis algorithm for absorbance by studying colloid absorbing behavior. The application of a buffer operator embedded in the algorithm makes the sensor get the environmental correction function. The results have shown that the sensitivity, repeatability, precision and environmental stability are higher than that by ordinary spectrophotometry. Lastly, we have a brief overview of future work.http://www.mdpi.com/1424-8220/18/10/3382nitrate nitrogenbuffer operatorabsorbance
spellingShingle Cong Wang
Zhen Li
Zhongli Pan
Daoliang Li
A High-Performance Optoelectronic Sensor Device for Nitrate Nitrogen in Recirculating Aquaculture Systems
Sensors
nitrate nitrogen
buffer operator
absorbance
title A High-Performance Optoelectronic Sensor Device for Nitrate Nitrogen in Recirculating Aquaculture Systems
title_full A High-Performance Optoelectronic Sensor Device for Nitrate Nitrogen in Recirculating Aquaculture Systems
title_fullStr A High-Performance Optoelectronic Sensor Device for Nitrate Nitrogen in Recirculating Aquaculture Systems
title_full_unstemmed A High-Performance Optoelectronic Sensor Device for Nitrate Nitrogen in Recirculating Aquaculture Systems
title_short A High-Performance Optoelectronic Sensor Device for Nitrate Nitrogen in Recirculating Aquaculture Systems
title_sort high performance optoelectronic sensor device for nitrate nitrogen in recirculating aquaculture systems
topic nitrate nitrogen
buffer operator
absorbance
url http://www.mdpi.com/1424-8220/18/10/3382
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