Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ2O1,O6)(nitrato-κ2O,O′)nickel(II)
In the title compound, [Ni(C8H7O3)(NO3)(C12H12N2)2], the asymmetric unit contains a NiII atom, two molecules of 2-(benzylamino)pyridine, a molecule of deprotonated o-vanillin (3-methoxysalicylaldehydate) and a bidentate nitrate anion. The NiII center is six-coordinated by two pyridine N atoms from 2...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809035570 |
| _version_ | 1818906313581658112 |
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| author | Ray J. Butcher Yilma Gultneh Kouassi Ayikoé |
| author_facet | Ray J. Butcher Yilma Gultneh Kouassi Ayikoé |
| author_sort | Ray J. Butcher |
| collection | DOAJ |
| description | In the title compound, [Ni(C8H7O3)(NO3)(C12H12N2)2], the asymmetric unit contains a NiII atom, two molecules of 2-(benzylamino)pyridine, a molecule of deprotonated o-vanillin (3-methoxysalicylaldehydate) and a bidentate nitrate anion. The NiII center is six-coordinated by two pyridine N atoms from 2-(benzylamino)pyridine, two O atoms from o-vanillin and two O atoms from the nitrate anion. The crystal packing shows two hydrogen bonds from the amine N—H group to the deprotonated phenol O atom of the o-vanillin moieties, as well as weak C—H...O secondary interactions. These interactions link the molecules into ribbons in the c direction. The steric requirement of the bidentate nitrate and its small bite angle [61.01 (3)°] cause some orientation of the two 2-(benzylamino)pyridine groups. As a result, this coordination environment of the NiII center is distorted octahedral, as the trans angles range from 158.65 (3) to 175.76 (3)° and the cis angles range from 61.01 (3) (for the bidentate nitrate O atoms) to 102.30 (4)°. |
| first_indexed | 2024-12-19T21:37:15Z |
| format | Article |
| id | doaj.art-9f4ac5616aa4489f91d3abc8dd18bdda |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:37:15Z |
| publishDate | 2009-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9f4ac5616aa4489f91d3abc8dd18bdda2022-12-21T20:04:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510m1193m119410.1107/S1600536809035570Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ2O1,O6)(nitrato-κ2O,O′)nickel(II)Ray J. ButcherYilma GultnehKouassi AyikoéIn the title compound, [Ni(C8H7O3)(NO3)(C12H12N2)2], the asymmetric unit contains a NiII atom, two molecules of 2-(benzylamino)pyridine, a molecule of deprotonated o-vanillin (3-methoxysalicylaldehydate) and a bidentate nitrate anion. The NiII center is six-coordinated by two pyridine N atoms from 2-(benzylamino)pyridine, two O atoms from o-vanillin and two O atoms from the nitrate anion. The crystal packing shows two hydrogen bonds from the amine N—H group to the deprotonated phenol O atom of the o-vanillin moieties, as well as weak C—H...O secondary interactions. These interactions link the molecules into ribbons in the c direction. The steric requirement of the bidentate nitrate and its small bite angle [61.01 (3)°] cause some orientation of the two 2-(benzylamino)pyridine groups. As a result, this coordination environment of the NiII center is distorted octahedral, as the trans angles range from 158.65 (3) to 175.76 (3)° and the cis angles range from 61.01 (3) (for the bidentate nitrate O atoms) to 102.30 (4)°.http://scripts.iucr.org/cgi-bin/paper?S1600536809035570 |
| spellingShingle | Ray J. Butcher Yilma Gultneh Kouassi Ayikoé Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ2O1,O6)(nitrato-κ2O,O′)nickel(II) Acta Crystallographica Section E |
| title | Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ2O1,O6)(nitrato-κ2O,O′)nickel(II) |
| title_full | Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ2O1,O6)(nitrato-κ2O,O′)nickel(II) |
| title_fullStr | Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ2O1,O6)(nitrato-κ2O,O′)nickel(II) |
| title_full_unstemmed | Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ2O1,O6)(nitrato-κ2O,O′)nickel(II) |
| title_short | Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ2O1,O6)(nitrato-κ2O,O′)nickel(II) |
| title_sort | bis 2 benzylamino pyridine amp 954 n 2 formyl 6 methoxyphenolato amp 954 2o1 o6 nitrato amp 954 2o o amp 8242 nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809035570 |
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