Zinc(II) Carboxylate Coordination Polymers with Versatile Applications

This review considers the applications of Zn(II) carboxylate-based coordination polymers (Zn-CBCPs), such as sensors, catalysts, species with potential in infections and cancers treatment, as well as storage and drug-carrier materials. The nature of organic luminophores, especially both the rigid ca...

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Main Authors: Gina Vasile Scaeteanu, Catalin Maxim, Mihaela Badea, Rodica Olar
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/3/1132
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author Gina Vasile Scaeteanu
Catalin Maxim
Mihaela Badea
Rodica Olar
author_facet Gina Vasile Scaeteanu
Catalin Maxim
Mihaela Badea
Rodica Olar
author_sort Gina Vasile Scaeteanu
collection DOAJ
description This review considers the applications of Zn(II) carboxylate-based coordination polymers (Zn-CBCPs), such as sensors, catalysts, species with potential in infections and cancers treatment, as well as storage and drug-carrier materials. The nature of organic luminophores, especially both the rigid carboxylate and the ancillary N-donor bridging ligand, together with the alignment in Zn-CBCPs and their intermolecular interaction modulate the luminescence properties and allow the sensing of a variety of inorganic and organic pollutants. The ability of Zn(II) to act as a good Lewis acid allowed the involvement of Zn-CBCPs either in dye elimination from wastewater through photocatalysis or in pathogenic microorganism or tumor inhibition. In addition, the pores developed inside of the network provided the possibility for some species to store gaseous or liquid molecules, as well as to deliver some drugs for improved treatment.
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spelling doaj.art-9f519875172b46828f9e3106c36cfe772023-11-16T17:28:06ZengMDPI AGMolecules1420-30492023-01-01283113210.3390/molecules28031132Zinc(II) Carboxylate Coordination Polymers with Versatile ApplicationsGina Vasile Scaeteanu0Catalin Maxim1Mihaela Badea2Rodica Olar3Department of Soil Sciences, University of Agronomical Sciences and Veterinary Medicine, 59 Mărăști Str., 011464 Bucharest, RomaniaDepartment of Inorganic, Organic Chemistry, Biochemistry and Catalysis, Faculty of Chemistry, University of Bucharest, 90–92 Panduri Str., 050663 Bucharest, RomaniaDepartment of Inorganic, Organic Chemistry, Biochemistry and Catalysis, Faculty of Chemistry, University of Bucharest, 90–92 Panduri Str., 050663 Bucharest, RomaniaDepartment of Inorganic, Organic Chemistry, Biochemistry and Catalysis, Faculty of Chemistry, University of Bucharest, 90–92 Panduri Str., 050663 Bucharest, RomaniaThis review considers the applications of Zn(II) carboxylate-based coordination polymers (Zn-CBCPs), such as sensors, catalysts, species with potential in infections and cancers treatment, as well as storage and drug-carrier materials. The nature of organic luminophores, especially both the rigid carboxylate and the ancillary N-donor bridging ligand, together with the alignment in Zn-CBCPs and their intermolecular interaction modulate the luminescence properties and allow the sensing of a variety of inorganic and organic pollutants. The ability of Zn(II) to act as a good Lewis acid allowed the involvement of Zn-CBCPs either in dye elimination from wastewater through photocatalysis or in pathogenic microorganism or tumor inhibition. In addition, the pores developed inside of the network provided the possibility for some species to store gaseous or liquid molecules, as well as to deliver some drugs for improved treatment.https://www.mdpi.com/1420-3049/28/3/1132zinccoordination polymercarboxylateluminescencesensorstorage
spellingShingle Gina Vasile Scaeteanu
Catalin Maxim
Mihaela Badea
Rodica Olar
Zinc(II) Carboxylate Coordination Polymers with Versatile Applications
Molecules
zinc
coordination polymer
carboxylate
luminescence
sensor
storage
title Zinc(II) Carboxylate Coordination Polymers with Versatile Applications
title_full Zinc(II) Carboxylate Coordination Polymers with Versatile Applications
title_fullStr Zinc(II) Carboxylate Coordination Polymers with Versatile Applications
title_full_unstemmed Zinc(II) Carboxylate Coordination Polymers with Versatile Applications
title_short Zinc(II) Carboxylate Coordination Polymers with Versatile Applications
title_sort zinc ii carboxylate coordination polymers with versatile applications
topic zinc
coordination polymer
carboxylate
luminescence
sensor
storage
url https://www.mdpi.com/1420-3049/28/3/1132
work_keys_str_mv AT ginavasilescaeteanu zinciicarboxylatecoordinationpolymerswithversatileapplications
AT catalinmaxim zinciicarboxylatecoordinationpolymerswithversatileapplications
AT mihaelabadea zinciicarboxylatecoordinationpolymerswithversatileapplications
AT rodicaolar zinciicarboxylatecoordinationpolymerswithversatileapplications