NO2 gas response and recovery properties of ambipolar CNT-FETs with various CNT/CNT junctions

Gas sensors based on ambipolar carbon nanotube (CNT) field-effect transistors with various amounts of CNTs were fabricated by dielectrophoretic assembly. The nitrogen dioxide (NO2) gas response and recovery properties of the transistors were measured to investigate the effect of CNT amount on gas re...

Full description

Bibliographic Details
Main Authors: Masafumi Inaba, Kaito Yagi, Naoki Asano, Haruka Omachi, Michihiko Nakano, Junya Suehiro
Format: Article
Language:English
Published: AIP Publishing LLC 2024-03-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/5.0197182
_version_ 1797227644677259264
author Masafumi Inaba
Kaito Yagi
Naoki Asano
Haruka Omachi
Michihiko Nakano
Junya Suehiro
author_facet Masafumi Inaba
Kaito Yagi
Naoki Asano
Haruka Omachi
Michihiko Nakano
Junya Suehiro
author_sort Masafumi Inaba
collection DOAJ
description Gas sensors based on ambipolar carbon nanotube (CNT) field-effect transistors with various amounts of CNTs were fabricated by dielectrophoretic assembly. The nitrogen dioxide (NO2) gas response and recovery properties of the transistors were measured to investigate the effect of CNT amount on gas response. For the device with a small amount of CNTs, responses from the CNT bulk and CNT/electrode contacts were observed. For devices with a large amount of CNTs, in which a network-like structure of CNTs was observed near the electrodes, an increased current in both electron and hole conduction regions was observed compared with that for the device with a small amount of CNTs. The increased current in the electron conduction region rapidly decreased during recovery. This response is consistent with that of CNT/CNT X-type contacts, which have a high resistance before NO2 adsorption. Equivalent circuits of CNT channels with CNT/CNT contacts were developed, allowing the transistor behavior to be qualitatively discussed. Evaluation of time constants revealed that CNT/electrode contacts and CNT/CNT X-type contacts exhibited high NO2 adsorption and desorption rates, respectively.
first_indexed 2024-04-24T14:44:05Z
format Article
id doaj.art-9f811c2325624422bcd98fbac9d4139d
institution Directory Open Access Journal
issn 2158-3226
language English
last_indexed 2024-04-24T14:44:05Z
publishDate 2024-03-01
publisher AIP Publishing LLC
record_format Article
series AIP Advances
spelling doaj.art-9f811c2325624422bcd98fbac9d4139d2024-04-02T20:29:17ZengAIP Publishing LLCAIP Advances2158-32262024-03-01143035140035140-610.1063/5.0197182NO2 gas response and recovery properties of ambipolar CNT-FETs with various CNT/CNT junctionsMasafumi Inaba0Kaito Yagi1Naoki Asano2Haruka Omachi3Michihiko Nakano4Junya Suehiro5Faculty of Information Science and Electrical Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, JapanGraduate School of Information Science and Electrical Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, JapanGraduate School of Information Science and Electrical Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, JapanIntegrated Research Consortium on Chemical Sciences, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, JapanFaculty of Information Science and Electrical Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, JapanFaculty of Information Science and Electrical Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, JapanGas sensors based on ambipolar carbon nanotube (CNT) field-effect transistors with various amounts of CNTs were fabricated by dielectrophoretic assembly. The nitrogen dioxide (NO2) gas response and recovery properties of the transistors were measured to investigate the effect of CNT amount on gas response. For the device with a small amount of CNTs, responses from the CNT bulk and CNT/electrode contacts were observed. For devices with a large amount of CNTs, in which a network-like structure of CNTs was observed near the electrodes, an increased current in both electron and hole conduction regions was observed compared with that for the device with a small amount of CNTs. The increased current in the electron conduction region rapidly decreased during recovery. This response is consistent with that of CNT/CNT X-type contacts, which have a high resistance before NO2 adsorption. Equivalent circuits of CNT channels with CNT/CNT contacts were developed, allowing the transistor behavior to be qualitatively discussed. Evaluation of time constants revealed that CNT/electrode contacts and CNT/CNT X-type contacts exhibited high NO2 adsorption and desorption rates, respectively.http://dx.doi.org/10.1063/5.0197182
spellingShingle Masafumi Inaba
Kaito Yagi
Naoki Asano
Haruka Omachi
Michihiko Nakano
Junya Suehiro
NO2 gas response and recovery properties of ambipolar CNT-FETs with various CNT/CNT junctions
AIP Advances
title NO2 gas response and recovery properties of ambipolar CNT-FETs with various CNT/CNT junctions
title_full NO2 gas response and recovery properties of ambipolar CNT-FETs with various CNT/CNT junctions
title_fullStr NO2 gas response and recovery properties of ambipolar CNT-FETs with various CNT/CNT junctions
title_full_unstemmed NO2 gas response and recovery properties of ambipolar CNT-FETs with various CNT/CNT junctions
title_short NO2 gas response and recovery properties of ambipolar CNT-FETs with various CNT/CNT junctions
title_sort no2 gas response and recovery properties of ambipolar cnt fets with various cnt cnt junctions
url http://dx.doi.org/10.1063/5.0197182
work_keys_str_mv AT masafumiinaba no2gasresponseandrecoverypropertiesofambipolarcntfetswithvariouscntcntjunctions
AT kaitoyagi no2gasresponseandrecoverypropertiesofambipolarcntfetswithvariouscntcntjunctions
AT naokiasano no2gasresponseandrecoverypropertiesofambipolarcntfetswithvariouscntcntjunctions
AT harukaomachi no2gasresponseandrecoverypropertiesofambipolarcntfetswithvariouscntcntjunctions
AT michihikonakano no2gasresponseandrecoverypropertiesofambipolarcntfetswithvariouscntcntjunctions
AT junyasuehiro no2gasresponseandrecoverypropertiesofambipolarcntfetswithvariouscntcntjunctions