Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hexachloridoantimonate(V)
The asymmetric unit of the title compound, [Sb(C44H28N4)Cl2][SbCl6], consists of one half of an antimony(V) tetraphenylporphyrin complex cation and one half of an hexachloridoantimonate(V) anion. In the complex cation, the SbV atom lies on an inversion center and is octahedrally coordinated by four...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814012653 |
| _version_ | 1798024420954996736 |
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| author | Raoudha Soury Mohamed Salah Belkhiria Michel Giorgi Habib Nasri |
| author_facet | Raoudha Soury Mohamed Salah Belkhiria Michel Giorgi Habib Nasri |
| author_sort | Raoudha Soury |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Sb(C44H28N4)Cl2][SbCl6], consists of one half of an antimony(V) tetraphenylporphyrin complex cation and one half of an hexachloridoantimonate(V) anion. In the complex cation, the SbV atom lies on an inversion center and is octahedrally coordinated by four N atoms from a macrocyclic tetraphenylporphyrinate ligand and two chloride ions. The complex cation has approximately a planar core with a maximum deviation of 0.018 (5) Å from the porphyrin mean plane. The average Sb—N distance is 2.062 (11) Å, while the Sb—Cl distance is 2.355 (1) Å. The SbV atom of the anion is also located on an inversion center. The [SbCl6]− octahedron exhibits rhombic distortion characterized by the Sb—Cl bond lengths [2.311 (3), 2.374 (2) and 2.393 (4) Å]. In the crystal, the cations and anions are linked C—H... Cl hydrogen bonds, forming a layer parallel to (211). |
| first_indexed | 2024-04-11T18:02:15Z |
| format | Article |
| id | doaj.art-9f933ba3786245fa9f800c21cfa27dc6 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:02:15Z |
| publishDate | 2014-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9f933ba3786245fa9f800c21cfa27dc62022-12-22T04:10:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-07-01707m256m25710.1107/S1600536814012653is5356Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hexachloridoantimonate(V)Raoudha Soury0Mohamed Salah Belkhiria1Michel Giorgi2Habib Nasri3Laboratoire de Physico-Chimie des Matériaux, Université de Monastir, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, TunisiaLaboratoire de Physico-Chimie des Matériaux, Université de Monastir, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, TunisiaSpectropole, Université d'Aix-Marseille, Faculté des Science, St-Jérôme, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, FranceLaboratoire de Physico-Chimie des Matériaux, Université de Monastir, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, TunisiaThe asymmetric unit of the title compound, [Sb(C44H28N4)Cl2][SbCl6], consists of one half of an antimony(V) tetraphenylporphyrin complex cation and one half of an hexachloridoantimonate(V) anion. In the complex cation, the SbV atom lies on an inversion center and is octahedrally coordinated by four N atoms from a macrocyclic tetraphenylporphyrinate ligand and two chloride ions. The complex cation has approximately a planar core with a maximum deviation of 0.018 (5) Å from the porphyrin mean plane. The average Sb—N distance is 2.062 (11) Å, while the Sb—Cl distance is 2.355 (1) Å. The SbV atom of the anion is also located on an inversion center. The [SbCl6]− octahedron exhibits rhombic distortion characterized by the Sb—Cl bond lengths [2.311 (3), 2.374 (2) and 2.393 (4) Å]. In the crystal, the cations and anions are linked C—H... Cl hydrogen bonds, forming a layer parallel to (211).http://scripts.iucr.org/cgi-bin/paper?S1600536814012653 |
| spellingShingle | Raoudha Soury Mohamed Salah Belkhiria Michel Giorgi Habib Nasri Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hexachloridoantimonate(V) Acta Crystallographica Section E |
| title | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hexachloridoantimonate(V) |
| title_full | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hexachloridoantimonate(V) |
| title_fullStr | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hexachloridoantimonate(V) |
| title_full_unstemmed | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hexachloridoantimonate(V) |
| title_short | Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N)antimony(V) hexachloridoantimonate(V) |
| title_sort | dichlorido 5 10 15 20 tetraphenylporphyrinato κ4n antimony v hexachloridoantimonate v |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814012653 |
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