Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China

A portable electrochemical system based on rGO/AuNPs/Nafion was constructed for selenium (IV) field determination in coastal seawater of the North Yellow Sea, East China Sea and South China Sea. This system demonstrated a low determination limit (0.03 μg/L), a wide linear range of concentration (0.1...

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Main Authors: Tianzhuo Liu, Dawei Pan, Hong Wei, Yan Liang, Ying Li, Md. Abdur Rahman
Format: Article
Language:English
Published: MDPI AG 2024-02-01
Series:Journal of Marine Science and Engineering
Subjects:
Online Access:https://www.mdpi.com/2077-1312/12/3/398
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author Tianzhuo Liu
Dawei Pan
Hong Wei
Yan Liang
Ying Li
Md. Abdur Rahman
author_facet Tianzhuo Liu
Dawei Pan
Hong Wei
Yan Liang
Ying Li
Md. Abdur Rahman
author_sort Tianzhuo Liu
collection DOAJ
description A portable electrochemical system based on rGO/AuNPs/Nafion was constructed for selenium (IV) field determination in coastal seawater of the North Yellow Sea, East China Sea and South China Sea. This system demonstrated a low determination limit (0.03 μg/L), a wide linear range of concentration (0.1–30 μg/L), exceptional reproducibility and repeatability, and excellent selectivity. Each individual, entire test could be accomplished within 8 min. In Yantai Sishili Bay, the Se (IV) concentrations ranged from 0.16–3.59 μg/L (average 1.43 μg/L). In Shengshan Island, the Se (IV) concentrations ranged from 0.20–5.18 μg/L (average 2.06 μg/L). In Zhelin Bay, the Se (IV) concentrations ranged from 0.87–4.87 μg/L (average 3.13 μg/L). The average concentrations of Se (IV) in surface seawater showcased an increasing trend from the north to the south of China, suggesting Zhelin Bay > Shengshan Island > Sishili Bay. The system develops a new, competitive method for water quality assessment, and contributes to the accurate study of the biogeochemical cycles of selenium.
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spelling doaj.art-9f9e535978ae47f79ff7845ddacf25af2024-03-27T13:49:10ZengMDPI AGJournal of Marine Science and Engineering2077-13122024-02-0112339810.3390/jmse12030398Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of ChinaTianzhuo Liu0Dawei Pan1Hong Wei2Yan Liang3Ying Li4Md. Abdur Rahman5CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environment Engineering Technology of Shandong Province, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environment Engineering Technology of Shandong Province, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environment Engineering Technology of Shandong Province, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environment Engineering Technology of Shandong Province, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, ChinaKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environment Engineering Technology of Shandong Province, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, ChinaA portable electrochemical system based on rGO/AuNPs/Nafion was constructed for selenium (IV) field determination in coastal seawater of the North Yellow Sea, East China Sea and South China Sea. This system demonstrated a low determination limit (0.03 μg/L), a wide linear range of concentration (0.1–30 μg/L), exceptional reproducibility and repeatability, and excellent selectivity. Each individual, entire test could be accomplished within 8 min. In Yantai Sishili Bay, the Se (IV) concentrations ranged from 0.16–3.59 μg/L (average 1.43 μg/L). In Shengshan Island, the Se (IV) concentrations ranged from 0.20–5.18 μg/L (average 2.06 μg/L). In Zhelin Bay, the Se (IV) concentrations ranged from 0.87–4.87 μg/L (average 3.13 μg/L). The average concentrations of Se (IV) in surface seawater showcased an increasing trend from the north to the south of China, suggesting Zhelin Bay > Shengshan Island > Sishili Bay. The system develops a new, competitive method for water quality assessment, and contributes to the accurate study of the biogeochemical cycles of selenium.https://www.mdpi.com/2077-1312/12/3/398seleniumelectrochemical systemfield determinationseawater
spellingShingle Tianzhuo Liu
Dawei Pan
Hong Wei
Yan Liang
Ying Li
Md. Abdur Rahman
Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China
Journal of Marine Science and Engineering
selenium
electrochemical system
field determination
seawater
title Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China
title_full Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China
title_fullStr Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China
title_full_unstemmed Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China
title_short Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China
title_sort field determination and spatial distribution of se iv in coastal seawater of china
topic selenium
electrochemical system
field determination
seawater
url https://www.mdpi.com/2077-1312/12/3/398
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