Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China
A portable electrochemical system based on rGO/AuNPs/Nafion was constructed for selenium (IV) field determination in coastal seawater of the North Yellow Sea, East China Sea and South China Sea. This system demonstrated a low determination limit (0.03 μg/L), a wide linear range of concentration (0.1...
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MDPI AG
2024-02-01
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author | Tianzhuo Liu Dawei Pan Hong Wei Yan Liang Ying Li Md. Abdur Rahman |
author_facet | Tianzhuo Liu Dawei Pan Hong Wei Yan Liang Ying Li Md. Abdur Rahman |
author_sort | Tianzhuo Liu |
collection | DOAJ |
description | A portable electrochemical system based on rGO/AuNPs/Nafion was constructed for selenium (IV) field determination in coastal seawater of the North Yellow Sea, East China Sea and South China Sea. This system demonstrated a low determination limit (0.03 μg/L), a wide linear range of concentration (0.1–30 μg/L), exceptional reproducibility and repeatability, and excellent selectivity. Each individual, entire test could be accomplished within 8 min. In Yantai Sishili Bay, the Se (IV) concentrations ranged from 0.16–3.59 μg/L (average 1.43 μg/L). In Shengshan Island, the Se (IV) concentrations ranged from 0.20–5.18 μg/L (average 2.06 μg/L). In Zhelin Bay, the Se (IV) concentrations ranged from 0.87–4.87 μg/L (average 3.13 μg/L). The average concentrations of Se (IV) in surface seawater showcased an increasing trend from the north to the south of China, suggesting Zhelin Bay > Shengshan Island > Sishili Bay. The system develops a new, competitive method for water quality assessment, and contributes to the accurate study of the biogeochemical cycles of selenium. |
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spelling | doaj.art-9f9e535978ae47f79ff7845ddacf25af2024-03-27T13:49:10ZengMDPI AGJournal of Marine Science and Engineering2077-13122024-02-0112339810.3390/jmse12030398Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of ChinaTianzhuo Liu0Dawei Pan1Hong Wei2Yan Liang3Ying Li4Md. Abdur Rahman5CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environment Engineering Technology of Shandong Province, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environment Engineering Technology of Shandong Province, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environment Engineering Technology of Shandong Province, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environment Engineering Technology of Shandong Province, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, ChinaKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environment Engineering Technology of Shandong Province, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, ChinaA portable electrochemical system based on rGO/AuNPs/Nafion was constructed for selenium (IV) field determination in coastal seawater of the North Yellow Sea, East China Sea and South China Sea. This system demonstrated a low determination limit (0.03 μg/L), a wide linear range of concentration (0.1–30 μg/L), exceptional reproducibility and repeatability, and excellent selectivity. Each individual, entire test could be accomplished within 8 min. In Yantai Sishili Bay, the Se (IV) concentrations ranged from 0.16–3.59 μg/L (average 1.43 μg/L). In Shengshan Island, the Se (IV) concentrations ranged from 0.20–5.18 μg/L (average 2.06 μg/L). In Zhelin Bay, the Se (IV) concentrations ranged from 0.87–4.87 μg/L (average 3.13 μg/L). The average concentrations of Se (IV) in surface seawater showcased an increasing trend from the north to the south of China, suggesting Zhelin Bay > Shengshan Island > Sishili Bay. The system develops a new, competitive method for water quality assessment, and contributes to the accurate study of the biogeochemical cycles of selenium.https://www.mdpi.com/2077-1312/12/3/398seleniumelectrochemical systemfield determinationseawater |
spellingShingle | Tianzhuo Liu Dawei Pan Hong Wei Yan Liang Ying Li Md. Abdur Rahman Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China Journal of Marine Science and Engineering selenium electrochemical system field determination seawater |
title | Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China |
title_full | Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China |
title_fullStr | Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China |
title_full_unstemmed | Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China |
title_short | Field Determination and Spatial Distribution of Se (IV) in Coastal Seawater of China |
title_sort | field determination and spatial distribution of se iv in coastal seawater of china |
topic | selenium electrochemical system field determination seawater |
url | https://www.mdpi.com/2077-1312/12/3/398 |
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