Composite structure and enhanced photocatalytic activity in Mn–Co–Ni–O/LaMnO3 microparticles

A series of Mn–Co–Ni–O/LaMnO _3 composite materials were synthesized through the sol-gel method. The structure of these powders changed from the spinel to a spinel–perovskite mixed phase as the content of LaMnO _3 increased from 0 to 50%. Meanwhile, some grains of composite material were refined to...

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Main Author: Chao Ma
Format: Article
Language:English
Published: IOP Publishing 2020-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/ab90bc
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author Chao Ma
author_facet Chao Ma
author_sort Chao Ma
collection DOAJ
description A series of Mn–Co–Ni–O/LaMnO _3 composite materials were synthesized through the sol-gel method. The structure of these powders changed from the spinel to a spinel–perovskite mixed phase as the content of LaMnO _3 increased from 0 to 50%. Meanwhile, some grains of composite material were refined to form many small particles and distributed among the porous microparticles. According to the absorption spectra of composite samples, the strong absorption structures appeared in visible ranges, especially between 400 and 730 nm. The photocatalytic degradation of tetracycline under the visible light irradiation indicated that the percentage of LaMnO _3 at 50% exhibited the highest degradation rate (70.2%) in 150 min. Its high photocatalytic activity was mainly due to the large surface area, strong visible light absorption and increased ratio of Mn ^3+ /Mn ^4+ ions. These new micro-structured photocatalysts were expected to show considerable potential applications in the water treatment.
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spelling doaj.art-9fb4934cd55642468c4db5b2933661232023-08-09T16:13:39ZengIOP PublishingMaterials Research Express2053-15912020-01-017505501410.1088/2053-1591/ab90bcComposite structure and enhanced photocatalytic activity in Mn–Co–Ni–O/LaMnO3 microparticlesChao Ma0https://orcid.org/0000-0003-2968-0436School of Electronic Engineering, School of Microelectronics, Chengdu Technological University , Chengdu 611730, People’s Republic of ChinaA series of Mn–Co–Ni–O/LaMnO _3 composite materials were synthesized through the sol-gel method. The structure of these powders changed from the spinel to a spinel–perovskite mixed phase as the content of LaMnO _3 increased from 0 to 50%. Meanwhile, some grains of composite material were refined to form many small particles and distributed among the porous microparticles. According to the absorption spectra of composite samples, the strong absorption structures appeared in visible ranges, especially between 400 and 730 nm. The photocatalytic degradation of tetracycline under the visible light irradiation indicated that the percentage of LaMnO _3 at 50% exhibited the highest degradation rate (70.2%) in 150 min. Its high photocatalytic activity was mainly due to the large surface area, strong visible light absorption and increased ratio of Mn ^3+ /Mn ^4+ ions. These new micro-structured photocatalysts were expected to show considerable potential applications in the water treatment.https://doi.org/10.1088/2053-1591/ab90bcspinel–perovskitecomposite materialmicroparticlephotocatalysis
spellingShingle Chao Ma
Composite structure and enhanced photocatalytic activity in Mn–Co–Ni–O/LaMnO3 microparticles
Materials Research Express
spinel–perovskite
composite material
microparticle
photocatalysis
title Composite structure and enhanced photocatalytic activity in Mn–Co–Ni–O/LaMnO3 microparticles
title_full Composite structure and enhanced photocatalytic activity in Mn–Co–Ni–O/LaMnO3 microparticles
title_fullStr Composite structure and enhanced photocatalytic activity in Mn–Co–Ni–O/LaMnO3 microparticles
title_full_unstemmed Composite structure and enhanced photocatalytic activity in Mn–Co–Ni–O/LaMnO3 microparticles
title_short Composite structure and enhanced photocatalytic activity in Mn–Co–Ni–O/LaMnO3 microparticles
title_sort composite structure and enhanced photocatalytic activity in mn co ni o lamno3 microparticles
topic spinel–perovskite
composite material
microparticle
photocatalysis
url https://doi.org/10.1088/2053-1591/ab90bc
work_keys_str_mv AT chaoma compositestructureandenhancedphotocatalyticactivityinmnconiolamno3microparticles