High-Glass-Transition Polyesters Produced with Phthalic Anhydride and Epoxides by Ring-Opening Copolymerization (ROCOP)

High-Glass-Transition Polyesters Produced with Phthalic Anhydride and Epoxides by Ring-Opening Copolymerization (ROCOP)

Polyesters with a high glass transition temperature above 130 °C were obtained from limonene oxide (LO) or vinylcyclohexene oxide (VCHO) and phthalic anhydride (PA) in the presence of commercial salen-type complexes with different metals—Cr, Al, and Mn—as catalysts in combination with 4-(dimethylami...

Full description

Bibliographic Details
Main Authors:	Selena Silvano, Matteo Proverbio, Adriano Vignali, Fabio Bertini, Laura Boggioni
Format:	Article
Language:	English
Published:	MDPI AG 2023-06-01
Series:	Polymers
Subjects:	polyesters salen-type complexes ring-opening copolymerization (ROCOP) epoxides cyclic anhydrides high glass transition temperature
Online Access:	https://www.mdpi.com/2073-4360/15/13/2801

Similar Items

Copolymerization of Phthalic Anhydride with Epoxides Catalyzed by Amine-Bis(Phenolate) Chromium(III) Complexes
by: Wiktor Bukowski, et al.
Published: (2021-05-01)

Copolymerization of epoxides with cyclic anhydrides catalyzed by dinuclear cobalt complexes
by: Yo Hiranoi, et al.
Published: (2018-11-01)

Terpolymerization of CO<sub>2</sub> with Epoxides and Cyclic Organic Anhydrides or Cyclic Esters
by: David Hermann Lamparelli, et al.
Published: (2021-08-01)

Zinc Amido-Oxazolinate Catalyzed Ring Opening Copolymerization and Terpolymerization of Maleic Anhydride and Epoxides
by: Muneer Shaik, et al.
Published: (2020-09-01)

Ring-Opening Copolymerization of Cyclohexene Oxide and Cyclic Anhydrides Catalyzed by Bimetallic Scorpionate Zinc Catalysts
by: Felipe de la Cruz-Martínez, et al.
Published: (2021-05-01)

One-Pot Terpolymerization of Macrolactones with Limonene Oxide and Phtalic Anhydride to Produce di-Block Semi-Aromatic Polyesters
by: Ilaria D’Auria, et al.
Published: (2022-11-01)

Salen-like Chromium and Aluminum Complexes as Catalysts in the Copolymerization of Epoxides with Cyclic Anhydrides for the Synthesis of Polyesters
by: Federica Santulli, et al.
Published: (2023-06-01)

Phthalic anhydride
by: 8096 British Standards Institution
Published: (1964)

Efficient Production of Poly(Cyclohexene Carbonate) via ROCOP of Cyclohexene Oxide and CO<sub>2</sub> Mediated by NNO-Scorpionate Zinc Complexes
by: Sonia Sobrino, et al.
Published: (2020-09-01)

Ring Opening Copolymerization (ROCOP) of boron-containing anhydride with epoxides as a controlled platform to functional polyesters
by: Vidal, F, et al.
Published: (2023)

Mechanistic Insights into the Effects of Ureas and Monomers on the Ring-Opening Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Organic Base/Urea
by: Lihang Jiang, et al.
Published: (2024-04-01)

An Investigation of the Organoborane/Lewis Base Pairs on the Copolymerization of Propylene Oxide with Succinic Anhydride
by: Lan-Fang Hu, et al.
Published: (2020-01-01)

Ternary Copolymerization of Supercritical CO2, Propylene Oxide and Maleic Anhydride
by: Lan ZHENG, et al.
Published: (2017-11-01)

Synergic heterodinuclear catalysts for the ring-opening copolymerization (ROCOP) of epoxides, carbon dioxide, and anhydrides
by: Diment, WT, et al.
Published: (2022)

Practical Epoxidation of Olefins Using Air and Ubiquitous Iron-Based Fluorous Salen Complex
by: Yamato Kato, et al.
Published: (2024-02-01)

Theoretical Study on Epoxide Ring-opening in CO<sub>2</sub>/Epoxide Copolymerization Catalyzed by Bifunctional Salen-Type Cobalt(III) Complexes: Influence of Stereoelectronic Factors
by: Karol Dyduch, et al.
Published: (2021-03-01)

Cyclic Polyesters with Closed‐Loop Recyclability from A New Chemically Reversible Alternating Copolymerization
by: Xiaoxian Lu, et al.
Published: (2024-01-01)

Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride Hardeners
by: Alejandro Lerma-Canto, et al.
Published: (2023-03-01)

Study of phthalic anhydride and glycerol polycondensation
by: Prudnikova E.A., et al.
Published: (2023-01-01)

DFT Modeling of the Alternating Radical Copolymerization and Alder-Ene Reaction between Maleic Anhydride and Olefins
by: Ilya Nifant’ev, et al.
Published: (2020-03-01)

4Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride
by: Masumeh Gilanizadeh, et al.
Published: (2015-07-01)

Asymmetric Ring-Opening of Epoxides Catalyzed by Metal–Salen Complexes
by: Anna Lidskog, et al.
Published: (2020-06-01)

Electrochemical Epoxidation Catalyzed by Manganese Salen Complex and Carbonate with Boron-Doped Diamond Electrode
by: Pijush Kanti Roy, et al.
Published: (2023-02-01)

Synthesis of novel thermoplastic polyester elastomers with biobased amorphous polyester as the soft segment
by: Yanyan Xu, et al.
Published: (2023-07-01)

Recent Developments in Ring-Opening Copolymerization of Epoxides With CO2 and Cyclic Anhydrides for Biomedical Applications
by: Xue Liang, et al.
Published: (2021-04-01)

Synthesis and Chemical Characterization of Alkyd Resins Using Maleic and Phthalic Anhydrides and Seed oil of Luffa aegyptiaca
by: Marili Funmilayo ZUBAİR, et al.
Published: (2023-08-01)

Synthesis and Conformational Study of a Novel Macrocyclic Chiral(Salen) ligand and its Uranyl and Mn Complexes
by: Rosa M. Toscano, et al.
Published: (2010-03-01)

Post-Modification of Copolymers Obtained by ATRP for an Application in Heterogeneous Asymmetric Salen Catalysis
by: Erigene Bakangura, et al.
Published: (2022-07-01)

Green trimellitic anhydride and hemimellitic anhydride from malic acid
by: Aleksei Ananin, et al.
Published: (2023-01-01)

A Novel Synthesis of Poly(Ester-<i>Alt</i>-Selenide)s by Ring-Opening Copolymerization of γ-Selenobutyrolactone and Epoxy Monomer
by: Ya’nan Wang, et al.
Published: (2020-05-01)

Synthesis and characterization of polyesters derived from glycerol and phthalic acid
by: Danilo Hansen Guimarães, et al.
Published: (2007-09-01)

Copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a (salen)Co(III) complex tethering four quaternary ammonium salts
by: Jong Yeob Jeon, et al.
Published: (2014-08-01)

Oligomeric (Salen)Mn(III) Complexes Featuring Tartrate Linkers Immobilized over Layered Double Hydroxide for Catalytically Asymmetric Epoxidation of Unfunctionalized Olefins
by: Yihong Jia, et al.
Published: (2020-10-01)

Structural Insights of Humins/Epoxidized Linseed Oil/ Hardener Terpolymerization
by: Erol Licsandru, et al.
Published: (2020-07-01)

Synergistic Effects of Epoxidized Soybean Oil and Polyester Fiber on Crumb Rubber Modified Asphalt Using Response Surface Methodology
by: Jie Pan, et al.
Published: (2023-04-01)

Maleic anhydride
by: 8096 British Standards Institution
Published: (1964)

Maleic anhydride /
by: 231772 Trivedi, B. C., et al.
Published: (1982)

Producing Interpenetrating Network from Waste Tires Rubber with commercial Unsaturated Polyester
by: Rasha AL Jarah, et al.
Published: (2022-12-01)

Microwave-Assisted Catalytic Synthesis of Bio-Based Copolymers from Waste Cooking Oil
by: Mahrzadi Noureen Shahi, et al.
Published: (2017-03-01)

Homo- and Copolymerization of Ethylene with Norbornene Catalyzed by Vanadium(III) Phosphine Complexes
by: Giorgia Zanchin, et al.
Published: (2019-05-01)