| Summary: | As global power generation is currently relying on fossil fuel-based power plants, more anthropogenic CO<sub>2</sub> is being released into the atmosphere. During the transition period to alternative energy sources, carbon capture and storage seems to be a promising solution. Chemical-looping combustion (CLC) is an energy conversion technology designed for combustion of fossil fuel with advantageous carbon capture capabilities. In this work, a 1D computational fluid dynamics (CFD) multiscale model was developed to study the reduction step in a syngas-based CLC system and was validated using literature data (<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mi>R</mi><mo>=</mo><mn>0.99</mn></mrow></semantics></math></inline-formula>). In order to investigate mass transfer effects, flow rate and particle dimension studies were carried out. Sharper mass transfer rates were seen at lower flow rates and smaller granule sizes due to suppression of diffusion limitations. In addition, a 3D CFD particle model was developed to investigate in depth the reduction within an ilmenite particle, with focus on heat transfer effects. Minor differences of 1 K were seen when comparing temperature changes predicted by the two models during the slightly exothermic reduction reaction with syngas.
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