Application of ICP-MS to Study the Rare Earth Element Characteristics and Sedimentary Environment of Black Shale in the Longmaxi Formation in the Southwestern Sichuan Basin

In order to study the sedimentary environment, tectonic background, and source features of the Longmaxi Formation black shale in the Yanyuan Basin, southwest Sichuan and guide regional shale gas exploration and related research, the rare earth element (REE) composition of these rocks was analyzed by...

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Bibliographic Details
Main Authors: ZHANG Qian, YU Qian, WANG Jian, XIAO Yuan-fu, CHENG Jin-xiang, ZHAO An-kun, ZHANG Bin
Format: Article
Language:English
Published: Science Press, PR China 2018-03-01
Series:Yankuang ceshi
Subjects:
Online Access:http://www.ykcs.ac.cn/cn/article/doi/10.15898/j.cnki.11-2131/td.201705090078
Description
Summary:In order to study the sedimentary environment, tectonic background, and source features of the Longmaxi Formation black shale in the Yanyuan Basin, southwest Sichuan and guide regional shale gas exploration and related research, the rare earth element (REE) composition of these rocks was analyzed by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) in this study. The results show that ΣREEs are low with the enrichment of light rare earth and the depletion of heavy rare earth, and significant differentiation between them. These rocks have an average <i>δ</i>Ce<sub>N</sub> value of 0.87, indicating a weakly negative Ce anomaly. They have <i>δ</i>Eu<sub>N</sub> values of 0.66-1.43 with a large variation, indicating that the composition of the source rock is complex. Average (La/Yb)<sub>S</sub> value of 1.31 indicates that tectonic background of the study area is mainly passive continental margin. The source rocks are mixed ancient sedimentary rocks, granites, and intermediate-mafic rocks. Neagtive <i>δ</i>Ce<sub>S</sub> and positive <i>δ</i>Eu<sub>S</sub> anomalies, as well as La/Ce &lt; 1 indicate that the sedimentary water body is a reducing environment formed by a deep-water shelf sedimentation and affected by a certain degree of hydrothermal sedimentation. Deep-sea hydrothermal fluids can bring rich nutrients, which favours the formation of organic matter. The reduction of a water environment is helpful for the preservation of organic matter, hence making the study area rich in organic matter with a large thickness. It is inferred that the black shale in Longmaxi Formation is a high-quality source rock reservoir.
ISSN:0254-5357