2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene

The title compound, C43H45NO12, was prepared from the reaction of 2,6-bis(dibromomethyl)pyridine and bisphenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (...

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Main Authors: Jun Hee Kim, Il Yoon, Wonbo Sim, Jai Young Lee
Format: Article
Language:English
Published: International Union of Crystallography 2012-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812038093
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author Jun Hee Kim
Il Yoon
Wonbo Sim
Jai Young Lee
author_facet Jun Hee Kim
Il Yoon
Wonbo Sim
Jai Young Lee
author_sort Jun Hee Kim
collection DOAJ
description The title compound, C43H45NO12, was prepared from the reaction of 2,6-bis(dibromomethyl)pyridine and bisphenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (6)° with the peripheral rings. In the crystal, molecules are linked by weak C—H...O and C—H...π interactions, forming a folded structure.
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spelling doaj.art-a048740b2b87424d9feb59676c6498212022-12-21T19:24:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810o2913o291310.1107/S16005368120380932,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaeneJun Hee KimIl YoonWonbo SimJai Young LeeThe title compound, C43H45NO12, was prepared from the reaction of 2,6-bis(dibromomethyl)pyridine and bisphenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (6)° with the peripheral rings. In the crystal, molecules are linked by weak C—H...O and C—H...π interactions, forming a folded structure.http://scripts.iucr.org/cgi-bin/paper?S1600536812038093
spellingShingle Jun Hee Kim
Il Yoon
Wonbo Sim
Jai Young Lee
2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene
Acta Crystallographica Section E
title 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene
title_full 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene
title_fullStr 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene
title_full_unstemmed 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene
title_short 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene
title_sort 2 9 12 15 18 25 27 34 37 40 43 50 dodecaoxa 56 azaheptacyclo 24 24 5 151 55 03 8 019 24 028 33 044 49 hexapentaconta 3 5 7 19 24 20 22 28 33 29 31 44 46 48 51 53 55 pentadecaene
url http://scripts.iucr.org/cgi-bin/paper?S1600536812038093
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