2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene
The title compound, C43H45NO12, was prepared from the reaction of 2,6-bis(dibromomethyl)pyridine and bisphenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2012-10-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812038093 |
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author | Jun Hee Kim Il Yoon Wonbo Sim Jai Young Lee |
author_facet | Jun Hee Kim Il Yoon Wonbo Sim Jai Young Lee |
author_sort | Jun Hee Kim |
collection | DOAJ |
description | The title compound, C43H45NO12, was prepared from the reaction of 2,6-bis(dibromomethyl)pyridine and bisphenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (6)° with the peripheral rings. In the crystal, molecules are linked by weak C—H...O and C—H...π interactions, forming a folded structure. |
first_indexed | 2024-12-20T22:48:48Z |
format | Article |
id | doaj.art-a048740b2b87424d9feb59676c649821 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-20T22:48:48Z |
publishDate | 2012-10-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-a048740b2b87424d9feb59676c6498212022-12-21T19:24:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810o2913o291310.1107/S16005368120380932,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaeneJun Hee KimIl YoonWonbo SimJai Young LeeThe title compound, C43H45NO12, was prepared from the reaction of 2,6-bis(dibromomethyl)pyridine and bisphenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (6)° with the peripheral rings. In the crystal, molecules are linked by weak C—H...O and C—H...π interactions, forming a folded structure.http://scripts.iucr.org/cgi-bin/paper?S1600536812038093 |
spellingShingle | Jun Hee Kim Il Yoon Wonbo Sim Jai Young Lee 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene Acta Crystallographica Section E |
title | 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene |
title_full | 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene |
title_fullStr | 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene |
title_full_unstemmed | 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene |
title_short | 2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.151,55.03,8.019,24.028,33.044,49]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene |
title_sort | 2 9 12 15 18 25 27 34 37 40 43 50 dodecaoxa 56 azaheptacyclo 24 24 5 151 55 03 8 019 24 028 33 044 49 hexapentaconta 3 5 7 19 24 20 22 28 33 29 31 44 46 48 51 53 55 pentadecaene |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536812038093 |
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