Exploring large pore size alumina and silica-alumina based catalysts for decomposition of lignin
Evaluation of copper doped silica-alumina and γ-alumina catalysts for lignin decomposition was conducted using a suite of chemical analysis protocols that enabled a comprehensive characterization of the reaction product. X-ray diffraction analysis was used to verify the concentration of doped copper...
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| Format: | Article |
| Language: | English |
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AIMS Press
2018-12-01
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| Series: | AIMS Energy |
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| Online Access: | http://www.aimspress.com/article/10.3934/energy.2018.6.993/fulltext.html |
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| author | Sara Pourjafar Jasmine Kreft Honza Bilek Evguenii Kozliak Wayne Seames |
| author_facet | Sara Pourjafar Jasmine Kreft Honza Bilek Evguenii Kozliak Wayne Seames |
| author_sort | Sara Pourjafar |
| collection | DOAJ |
| description | Evaluation of copper doped silica-alumina and γ-alumina catalysts for lignin decomposition was conducted using a suite of chemical analysis protocols that enabled a comprehensive characterization of the reaction product. X-ray diffraction analysis was used to verify the concentration of doped copper on catalyst supports. Then, batch experiments were performed to study the significance of catalyst support type, catalyst dopant concentration, lignin concentration, catalyst-to-lignin ratio, reactor stirring rate and reaction time. Aqueous products were extracted with dichloromethane and analyzed using a detailed gas chromatography-mass spectrophotometry analytical protocol, allowing for quantification of over 20 compounds. Solid residues were analyzed by thermogravimetric analysis and scanning electron microscopy. The highest yield of monomeric products from these screening experiments occurred with 5 wt% Cu on silica-alumina with a 1:1 w/w ratio of catalyst to lignin. A second set of experiments were conducted at these conditions to evaluate the effect of varying the reaction temperature between 300 and 350 ºC. Lower reaction temperatures (300 ºC) resulted in more unreacted lignin while higher temperatures (>350 ºC) led to an increased formation of liquid phase products, but also increased char formation. While the total amount of liquid phase products increased, the combined yield of monomer phenolic products was only 5–7 wt% of the liquid extracted product and statistically independent of temperature and other operational parameters, although the yields of different chemicals varied with temperature. Unlike most pyrolytic processes, the concentration of gas phase products gradually decreased with increasing reaction temperature and became negligible at 400 ºC, while the formation of coke increased with temperature. This seemingly contradictory result is likely due to increased product polymerization occurring at higher temperatures. |
| first_indexed | 2024-04-13T19:29:12Z |
| format | Article |
| id | doaj.art-a04edd492b7645acbb4306447243ee07 |
| institution | Directory Open Access Journal |
| issn | 2333-8326 2333-8334 |
| language | English |
| last_indexed | 2024-04-13T19:29:12Z |
| publishDate | 2018-12-01 |
| publisher | AIMS Press |
| record_format | Article |
| series | AIMS Energy |
| spelling | doaj.art-a04edd492b7645acbb4306447243ee072022-12-22T02:33:14ZengAIMS PressAIMS Energy2333-83262333-83342018-12-0166993100810.3934/energy.2018.6.993Exploring large pore size alumina and silica-alumina based catalysts for decomposition of ligninSara Pourjafar0Jasmine Kreft1Honza Bilek2Evguenii Kozliak3Wayne Seames41 Chemical Engineering Department, University of North Dakota, Grand Forks, ND, USA1 Chemical Engineering Department, University of North Dakota, Grand Forks, ND, USA2 Department of Chemistry, University of North Dakota, Grand Forks, ND, USA2 Department of Chemistry, University of North Dakota, Grand Forks, ND, USA1 Chemical Engineering Department, University of North Dakota, Grand Forks, ND, USAEvaluation of copper doped silica-alumina and γ-alumina catalysts for lignin decomposition was conducted using a suite of chemical analysis protocols that enabled a comprehensive characterization of the reaction product. X-ray diffraction analysis was used to verify the concentration of doped copper on catalyst supports. Then, batch experiments were performed to study the significance of catalyst support type, catalyst dopant concentration, lignin concentration, catalyst-to-lignin ratio, reactor stirring rate and reaction time. Aqueous products were extracted with dichloromethane and analyzed using a detailed gas chromatography-mass spectrophotometry analytical protocol, allowing for quantification of over 20 compounds. Solid residues were analyzed by thermogravimetric analysis and scanning electron microscopy. The highest yield of monomeric products from these screening experiments occurred with 5 wt% Cu on silica-alumina with a 1:1 w/w ratio of catalyst to lignin. A second set of experiments were conducted at these conditions to evaluate the effect of varying the reaction temperature between 300 and 350 ºC. Lower reaction temperatures (300 ºC) resulted in more unreacted lignin while higher temperatures (>350 ºC) led to an increased formation of liquid phase products, but also increased char formation. While the total amount of liquid phase products increased, the combined yield of monomer phenolic products was only 5–7 wt% of the liquid extracted product and statistically independent of temperature and other operational parameters, although the yields of different chemicals varied with temperature. Unlike most pyrolytic processes, the concentration of gas phase products gradually decreased with increasing reaction temperature and became negligible at 400 ºC, while the formation of coke increased with temperature. This seemingly contradictory result is likely due to increased product polymerization occurring at higher temperatures.http://www.aimspress.com/article/10.3934/energy.2018.6.993/fulltext.htmllignin decomposition| doped catalysis| renewable fuels| renewable chemicals| zeolyte |
| spellingShingle | Sara Pourjafar Jasmine Kreft Honza Bilek Evguenii Kozliak Wayne Seames Exploring large pore size alumina and silica-alumina based catalysts for decomposition of lignin AIMS Energy lignin decomposition| doped catalysis| renewable fuels| renewable chemicals| zeolyte |
| title | Exploring large pore size alumina and silica-alumina based catalysts for decomposition of lignin |
| title_full | Exploring large pore size alumina and silica-alumina based catalysts for decomposition of lignin |
| title_fullStr | Exploring large pore size alumina and silica-alumina based catalysts for decomposition of lignin |
| title_full_unstemmed | Exploring large pore size alumina and silica-alumina based catalysts for decomposition of lignin |
| title_short | Exploring large pore size alumina and silica-alumina based catalysts for decomposition of lignin |
| title_sort | exploring large pore size alumina and silica alumina based catalysts for decomposition of lignin |
| topic | lignin decomposition| doped catalysis| renewable fuels| renewable chemicals| zeolyte |
| url | http://www.aimspress.com/article/10.3934/energy.2018.6.993/fulltext.html |
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