Radiation-induced graft polymerization of acrylic acid and glycidyl methacrylate onto abaca/polyester nonwoven fabric
Surface modified fibrous materials that possess carboxylic and amine functional groups were developed from a nonwoven fabric (NWF) containing abaca fibers. A facile method was employed for graft polymerization of acrylic acid (AA) and glycidyl methacrylate (GMA) from an electron beam irradiated abac...
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Format: | Article |
Language: | English |
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Taylor & Francis Group
2018-09-01
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Series: | Journal of Natural Fibers |
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Online Access: | http://dx.doi.org/10.1080/15440478.2017.1349713 |
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author | Jordan F. Madrid Patrick Jay E. Cabalar Lucille V. Abad |
author_facet | Jordan F. Madrid Patrick Jay E. Cabalar Lucille V. Abad |
author_sort | Jordan F. Madrid |
collection | DOAJ |
description | Surface modified fibrous materials that possess carboxylic and amine functional groups were developed from a nonwoven fabric (NWF) containing abaca fibers. A facile method was employed for graft polymerization of acrylic acid (AA) and glycidyl methacrylate (GMA) from an electron beam irradiated abaca/polyester NWF. Materials with sufficient amount of graft chains were prepared after reaction of NWF, irradiated at a maximum absorbed dose of 40 kGy, with 15% AA aqueous solution and 5% GMA emulsion for 2 and 3 hours, respectively. Characterization of the pristine, grafted, and functionalized materials with FTIR, TGA, and SEM indicates that grafting and functionalization were successfully performed. The batch adsorption studies showed that the PAA-modified NWF exhibited higher affinity toward Ni2+, Cd2+, and Pb2+ than the EDA-modified abaca/polyester-g-PGMA. |
first_indexed | 2024-03-11T22:36:04Z |
format | Article |
id | doaj.art-a063e183a9ed4cd1976396eb075b4e3d |
institution | Directory Open Access Journal |
issn | 1544-0478 1544-046X |
language | English |
last_indexed | 2024-03-11T22:36:04Z |
publishDate | 2018-09-01 |
publisher | Taylor & Francis Group |
record_format | Article |
series | Journal of Natural Fibers |
spelling | doaj.art-a063e183a9ed4cd1976396eb075b4e3d2023-09-22T14:26:18ZengTaylor & Francis GroupJournal of Natural Fibers1544-04781544-046X2018-09-0115562563810.1080/15440478.2017.13497131349713Radiation-induced graft polymerization of acrylic acid and glycidyl methacrylate onto abaca/polyester nonwoven fabricJordan F. Madrid0Patrick Jay E. Cabalar1Lucille V. Abad2Philippine Nuclear Research InstitutePhilippine Nuclear Research InstitutePhilippine Nuclear Research InstituteSurface modified fibrous materials that possess carboxylic and amine functional groups were developed from a nonwoven fabric (NWF) containing abaca fibers. A facile method was employed for graft polymerization of acrylic acid (AA) and glycidyl methacrylate (GMA) from an electron beam irradiated abaca/polyester NWF. Materials with sufficient amount of graft chains were prepared after reaction of NWF, irradiated at a maximum absorbed dose of 40 kGy, with 15% AA aqueous solution and 5% GMA emulsion for 2 and 3 hours, respectively. Characterization of the pristine, grafted, and functionalized materials with FTIR, TGA, and SEM indicates that grafting and functionalization were successfully performed. The batch adsorption studies showed that the PAA-modified NWF exhibited higher affinity toward Ni2+, Cd2+, and Pb2+ than the EDA-modified abaca/polyester-g-PGMA.http://dx.doi.org/10.1080/15440478.2017.1349713abacaacrylic acidglycidyl methacrylatenatural fiberspolyesterradiation-induced grafting |
spellingShingle | Jordan F. Madrid Patrick Jay E. Cabalar Lucille V. Abad Radiation-induced graft polymerization of acrylic acid and glycidyl methacrylate onto abaca/polyester nonwoven fabric Journal of Natural Fibers abaca acrylic acid glycidyl methacrylate natural fibers polyester radiation-induced grafting |
title | Radiation-induced graft polymerization of acrylic acid and glycidyl methacrylate onto abaca/polyester nonwoven fabric |
title_full | Radiation-induced graft polymerization of acrylic acid and glycidyl methacrylate onto abaca/polyester nonwoven fabric |
title_fullStr | Radiation-induced graft polymerization of acrylic acid and glycidyl methacrylate onto abaca/polyester nonwoven fabric |
title_full_unstemmed | Radiation-induced graft polymerization of acrylic acid and glycidyl methacrylate onto abaca/polyester nonwoven fabric |
title_short | Radiation-induced graft polymerization of acrylic acid and glycidyl methacrylate onto abaca/polyester nonwoven fabric |
title_sort | radiation induced graft polymerization of acrylic acid and glycidyl methacrylate onto abaca polyester nonwoven fabric |
topic | abaca acrylic acid glycidyl methacrylate natural fibers polyester radiation-induced grafting |
url | http://dx.doi.org/10.1080/15440478.2017.1349713 |
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