Deposition of copper sulfide films on polyamide surface

In this paper, we present a novel and low - cost method for preparing copper sulfide films on polyamide. Non-treated as well as pre-treated PA6 films by 3 different methods (in boiled water; in NaOH solution; in boiled water and then in NaOH solution) were used for the formation of Cu2S lay...

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Main Authors: Petrasauskiene Neringa, Paluckiene Edita, Alaburdaite Rasa, Gilić Martina
Format: Article
Language:English
Published: International Institute for the Science of Sintering, Beograd 2022-01-01
Series:Science of Sintering
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0350-820X/2022/0350-820X2202139P.pdf
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author Petrasauskiene Neringa
Paluckiene Edita
Alaburdaite Rasa
Gilić Martina
author_facet Petrasauskiene Neringa
Paluckiene Edita
Alaburdaite Rasa
Gilić Martina
author_sort Petrasauskiene Neringa
collection DOAJ
description In this paper, we present a novel and low - cost method for preparing copper sulfide films on polyamide. Non-treated as well as pre-treated PA6 films by 3 different methods (in boiled water; in NaOH solution; in boiled water and then in NaOH solution) were used for the formation of Cu2S layers by the sorption-diffusion method. Molten sulfur has been used as a sulfurization agent. The XRD, FTIR, and UV-VIS methods were used to characterize the structural, optical, and electrical properties of samples and to track changes in samples after each treatment stage. The sheet resistance of Cu2S layers depends on the pre-treatment method and varied from 7 kΩ/sq to 6 MΩ/sq. The optical band gaps (Eg) for direct and indirect transitions are determined to be 2.61-2.67 eV and 1.40-1.44 eV, respectively. Furthermore, the optical constants n, k, and σ are determined from UV-VIS measurements.
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spelling doaj.art-a065d087990d44d4bf16e7b3039e0c422022-12-22T00:59:12ZengInternational Institute for the Science of Sintering, BeogradScience of Sintering0350-820X1820-74132022-01-0154213915210.2298/SOS2202139P0350-820X2202139PDeposition of copper sulfide films on polyamide surfacePetrasauskiene Neringa0Paluckiene Edita1Alaburdaite Rasa2Gilić Martina3Department of Physical and Inorganic Chemistry, Kaunas University of Technology, Kaunas, LithuaniaDepartment of Physical and Inorganic Chemistry, Kaunas University of Technology, Kaunas, LithuaniaDepartment of Physical and Inorganic Chemistry, Kaunas University of Technology, Kaunas, LithuaniaInstitute of Physics Belgrade, University of Belgrade, Zemun, Serbia + Institut of Experimental Physics, Freie Universität Berlin, Berlin, GermanyIn this paper, we present a novel and low - cost method for preparing copper sulfide films on polyamide. Non-treated as well as pre-treated PA6 films by 3 different methods (in boiled water; in NaOH solution; in boiled water and then in NaOH solution) were used for the formation of Cu2S layers by the sorption-diffusion method. Molten sulfur has been used as a sulfurization agent. The XRD, FTIR, and UV-VIS methods were used to characterize the structural, optical, and electrical properties of samples and to track changes in samples after each treatment stage. The sheet resistance of Cu2S layers depends on the pre-treatment method and varied from 7 kΩ/sq to 6 MΩ/sq. The optical band gaps (Eg) for direct and indirect transitions are determined to be 2.61-2.67 eV and 1.40-1.44 eV, respectively. Furthermore, the optical constants n, k, and σ are determined from UV-VIS measurements.http://www.doiserbia.nb.rs/img/doi/0350-820X/2022/0350-820X2202139P.pdfthin filmcopper sulfidepolyamide 6x-ray diffractionoptical properties
spellingShingle Petrasauskiene Neringa
Paluckiene Edita
Alaburdaite Rasa
Gilić Martina
Deposition of copper sulfide films on polyamide surface
Science of Sintering
thin film
copper sulfide
polyamide 6
x-ray diffraction
optical properties
title Deposition of copper sulfide films on polyamide surface
title_full Deposition of copper sulfide films on polyamide surface
title_fullStr Deposition of copper sulfide films on polyamide surface
title_full_unstemmed Deposition of copper sulfide films on polyamide surface
title_short Deposition of copper sulfide films on polyamide surface
title_sort deposition of copper sulfide films on polyamide surface
topic thin film
copper sulfide
polyamide 6
x-ray diffraction
optical properties
url http://www.doiserbia.nb.rs/img/doi/0350-820X/2022/0350-820X2202139P.pdf
work_keys_str_mv AT petrasauskieneneringa depositionofcoppersulfidefilmsonpolyamidesurface
AT paluckieneedita depositionofcoppersulfidefilmsonpolyamidesurface
AT alaburdaiterasa depositionofcoppersulfidefilmsonpolyamidesurface
AT gilicmartina depositionofcoppersulfidefilmsonpolyamidesurface