Study on the Microstructure and Spectra of Regrown Quartz Crystals from Chinese Jewelry Market

Regrown quartz crystals consist of the natural section and the synthetic section grown by hydrothermal technique, which has become popular on the Chinese jewelry market in recent years. Similar gemological properties to those of natural quartz have brought challenges to gem identification and also n...

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Main Authors: Danyi Zhou, Taijin Lu, Huiru Dai, Jieran Lv, Shouming Chen, Zhonghua Song, Jian Zhang
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/11/9/1145
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author Danyi Zhou
Taijin Lu
Huiru Dai
Jieran Lv
Shouming Chen
Zhonghua Song
Jian Zhang
author_facet Danyi Zhou
Taijin Lu
Huiru Dai
Jieran Lv
Shouming Chen
Zhonghua Song
Jian Zhang
author_sort Danyi Zhou
collection DOAJ
description Regrown quartz crystals consist of the natural section and the synthetic section grown by hydrothermal technique, which has become popular on the Chinese jewelry market in recent years. Similar gemological properties to those of natural quartz have brought challenges to gem identification and also new questions to scientific research. In this study, microstructure and spectral characteristics of the two sections of regrown quartz crystals were investigated by three dimensional computed tomography system and infrared spectroscopy. Results showed that the natural section has a higher porosity and there are also many micron- to millimeter-sized pores on the interface of the two sections. Different infrared absorption peaks of the two sections at the 3300–3600 cm<sup>−1</sup> range were mainly attributed to the different existence state of OH groups. The distinction of microstructure and spectral characteristics between the natural and synthetic sections indicate their different growth condition. Compared with natural quartz, a relatively stable growth environment during the synthetic process leads to a lower porosity and the alkali growth solution could result in the change of the existence state of OH groups in the regrown quartz crystals.
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spelling doaj.art-a0848a53535846eeb09a89c057b7a8712023-11-22T12:36:35ZengMDPI AGCrystals2073-43522021-09-01119114510.3390/cryst11091145Study on the Microstructure and Spectra of Regrown Quartz Crystals from Chinese Jewelry MarketDanyi Zhou0Taijin Lu1Huiru Dai2Jieran Lv3Shouming Chen4Zhonghua Song5Jian Zhang6Beijing Institute of Gemology, National Gems & Jewelry Technology Administrative Center, Ministry of Natural Resources, Beijing 100013, ChinaBeijing Institute of Gemology, National Gems & Jewelry Technology Administrative Center, Ministry of Natural Resources, Beijing 100013, ChinaBeijing Lab, National Gemstone Testing Center, Beijing 100013, ChinaBeijing Lab, National Gemstone Testing Center, Beijing 100013, ChinaInstitute of Geology, Chinese Academy of Geological Science, Beijing 100037, ChinaBeijing Institute of Gemology, National Gems & Jewelry Technology Administrative Center, Ministry of Natural Resources, Beijing 100013, ChinaBeijing Institute of Gemology, National Gems & Jewelry Technology Administrative Center, Ministry of Natural Resources, Beijing 100013, ChinaRegrown quartz crystals consist of the natural section and the synthetic section grown by hydrothermal technique, which has become popular on the Chinese jewelry market in recent years. Similar gemological properties to those of natural quartz have brought challenges to gem identification and also new questions to scientific research. In this study, microstructure and spectral characteristics of the two sections of regrown quartz crystals were investigated by three dimensional computed tomography system and infrared spectroscopy. Results showed that the natural section has a higher porosity and there are also many micron- to millimeter-sized pores on the interface of the two sections. Different infrared absorption peaks of the two sections at the 3300–3600 cm<sup>−1</sup> range were mainly attributed to the different existence state of OH groups. The distinction of microstructure and spectral characteristics between the natural and synthetic sections indicate their different growth condition. Compared with natural quartz, a relatively stable growth environment during the synthetic process leads to a lower porosity and the alkali growth solution could result in the change of the existence state of OH groups in the regrown quartz crystals.https://www.mdpi.com/2073-4352/11/9/1145quartzcrystalsregrownmicrostructurespectra
spellingShingle Danyi Zhou
Taijin Lu
Huiru Dai
Jieran Lv
Shouming Chen
Zhonghua Song
Jian Zhang
Study on the Microstructure and Spectra of Regrown Quartz Crystals from Chinese Jewelry Market
Crystals
quartz
crystals
regrown
microstructure
spectra
title Study on the Microstructure and Spectra of Regrown Quartz Crystals from Chinese Jewelry Market
title_full Study on the Microstructure and Spectra of Regrown Quartz Crystals from Chinese Jewelry Market
title_fullStr Study on the Microstructure and Spectra of Regrown Quartz Crystals from Chinese Jewelry Market
title_full_unstemmed Study on the Microstructure and Spectra of Regrown Quartz Crystals from Chinese Jewelry Market
title_short Study on the Microstructure and Spectra of Regrown Quartz Crystals from Chinese Jewelry Market
title_sort study on the microstructure and spectra of regrown quartz crystals from chinese jewelry market
topic quartz
crystals
regrown
microstructure
spectra
url https://www.mdpi.com/2073-4352/11/9/1145
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