Poly[bis[μ2-4,4′-bis(imidazol-1-ylmethyl)biphenyl-κ2N:N′]dichloridonickel(II)]
In the title compound, [NiCl2(C20H18N4)2]n, the Ni2+ cation is situated on an inversion center and is coordinated by two chloride ions and four imidazole N atoms of four different 4,4′-bis[(1H-imidazol-1-yl)methyl]-1,1′-biphenyl (BIMB), forming a slightly distorted octahedral geometry. Each BIMB lig...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2022-04-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314622003777 |
| _version_ | 1818207182949187584 |
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| author | Min Deng Yue Yin Shan-Shan Wang Xin-Yi Qi Ai-Xin Zhu |
| author_facet | Min Deng Yue Yin Shan-Shan Wang Xin-Yi Qi Ai-Xin Zhu |
| author_sort | Min Deng |
| collection | DOAJ |
| description | In the title compound, [NiCl2(C20H18N4)2]n, the Ni2+ cation is situated on an inversion center and is coordinated by two chloride ions and four imidazole N atoms of four different 4,4′-bis[(1H-imidazol-1-yl)methyl]-1,1′-biphenyl (BIMB), forming a slightly distorted octahedral geometry. Each BIMB ligand adopts a linear linker to connect Ni2+ ions, forming a two-dimensional layer with an sql network. In the crystal, neighboring layers repeat in an ABAB stacking mode, and weak intermolecular C—H...Cl hydrogen bonds between alternate layers lead to a three-dimensional, twofold interpenetrated, supramolecular framework with a pcu topology net. |
| first_indexed | 2024-12-12T04:24:52Z |
| format | Article |
| id | doaj.art-a086e00c8e8544adab5a24269ca023e2 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-12T04:24:52Z |
| publishDate | 2022-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-a086e00c8e8544adab5a24269ca023e22022-12-22T00:38:13ZengInternational Union of CrystallographyIUCrData2414-31462022-04-0174x22037710.1107/S2414314622003777zl4050Poly[bis[μ2-4,4′-bis(imidazol-1-ylmethyl)biphenyl-κ2N:N′]dichloridonickel(II)]Min Deng0Yue Yin1Shan-Shan Wang2Xin-Yi Qi3Ai-Xin Zhu4Faculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650050, People's Republic of ChinaFaculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650050, People's Republic of ChinaFaculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650050, People's Republic of ChinaFaculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650050, People's Republic of ChinaFaculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650050, People's Republic of ChinaIn the title compound, [NiCl2(C20H18N4)2]n, the Ni2+ cation is situated on an inversion center and is coordinated by two chloride ions and four imidazole N atoms of four different 4,4′-bis[(1H-imidazol-1-yl)methyl]-1,1′-biphenyl (BIMB), forming a slightly distorted octahedral geometry. Each BIMB ligand adopts a linear linker to connect Ni2+ ions, forming a two-dimensional layer with an sql network. In the crystal, neighboring layers repeat in an ABAB stacking mode, and weak intermolecular C—H...Cl hydrogen bonds between alternate layers lead to a three-dimensional, twofold interpenetrated, supramolecular framework with a pcu topology net.http://scripts.iucr.org/cgi-bin/paper?S2414314622003777crystal structurecoordination polymerimidazolenickel |
| spellingShingle | Min Deng Yue Yin Shan-Shan Wang Xin-Yi Qi Ai-Xin Zhu Poly[bis[μ2-4,4′-bis(imidazol-1-ylmethyl)biphenyl-κ2N:N′]dichloridonickel(II)] IUCrData crystal structure coordination polymer imidazole nickel |
| title | Poly[bis[μ2-4,4′-bis(imidazol-1-ylmethyl)biphenyl-κ2N:N′]dichloridonickel(II)] |
| title_full | Poly[bis[μ2-4,4′-bis(imidazol-1-ylmethyl)biphenyl-κ2N:N′]dichloridonickel(II)] |
| title_fullStr | Poly[bis[μ2-4,4′-bis(imidazol-1-ylmethyl)biphenyl-κ2N:N′]dichloridonickel(II)] |
| title_full_unstemmed | Poly[bis[μ2-4,4′-bis(imidazol-1-ylmethyl)biphenyl-κ2N:N′]dichloridonickel(II)] |
| title_short | Poly[bis[μ2-4,4′-bis(imidazol-1-ylmethyl)biphenyl-κ2N:N′]dichloridonickel(II)] |
| title_sort | poly bis μ2 4 4 bis imidazol 1 ylmethyl biphenyl κ2n n dichloridonickel ii |
| topic | crystal structure coordination polymer imidazole nickel |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314622003777 |
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