Produção de monoacilgliceróis e diacilgliceróis via glicerólise enzimática e destilação molecular Production of monoglycerides and diglycerides through lipase-catalyzed glycerolysis and molecular distillation

<abstract language="eng">Monoacilglycerides and diacilglycerides are produced through lipase-catalyzed glycerolysis of soybean oil using Candida antarctica B in a solvent-free system. The reaction was carried out at a glycerol to triacylglycerol molar ratio of 8:1 with 2% of lipase....

Full description

Bibliographic Details
Main Authors: Patricia Bogalhos Lucente Fregolente, Gláucia Maria F. Pinto, Maria Regina Wolf-Maciel, Rubens Maciel Filho, César Benedito Batistella
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2009-01-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000600034
_version_ 1819057710028554240
author Patricia Bogalhos Lucente Fregolente
Gláucia Maria F. Pinto
Maria Regina Wolf-Maciel
Rubens Maciel Filho
César Benedito Batistella
author_facet Patricia Bogalhos Lucente Fregolente
Gláucia Maria F. Pinto
Maria Regina Wolf-Maciel
Rubens Maciel Filho
César Benedito Batistella
author_sort Patricia Bogalhos Lucente Fregolente
collection DOAJ
description <abstract language="eng">Monoacilglycerides and diacilglycerides are produced through lipase-catalyzed glycerolysis of soybean oil using Candida antarctica B in a solvent-free system. The reaction was carried out at a glycerol to triacylglycerol molar ratio of 8:1 with 2% of lipase. Acylglycerides, free fatty acids (FFA) and glycerol produced were separated employing the molecular distillation process. Starting from a product of enzymatic reaction 25.06% of triacylglycerols, 46.63% of diacylglycerides, 21.72% of monoacylglycerides, 5.38% of FFA and 1.21% of glycerol and after consecutively distillations, monoacylglycerides with 80% of purity was obtained and also oil with 54% of diacylglycerides to be used in human dietary.
first_indexed 2024-12-21T13:43:38Z
format Article
id doaj.art-a0921e000e7a4ef58921d9d52fd0f0bf
institution Directory Open Access Journal
issn 0100-4042
1678-7064
language English
last_indexed 2024-12-21T13:43:38Z
publishDate 2009-01-01
publisher Sociedade Brasileira de Química
record_format Article
series Química Nova
spelling doaj.art-a0921e000e7a4ef58921d9d52fd0f0bf2022-12-21T19:01:57ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642009-01-013261539154310.1590/S0100-40422009000600034Produção de monoacilgliceróis e diacilgliceróis via glicerólise enzimática e destilação molecular Production of monoglycerides and diglycerides through lipase-catalyzed glycerolysis and molecular distillationPatricia Bogalhos Lucente FregolenteGláucia Maria F. PintoMaria Regina Wolf-MacielRubens Maciel FilhoCésar Benedito Batistella<abstract language="eng">Monoacilglycerides and diacilglycerides are produced through lipase-catalyzed glycerolysis of soybean oil using Candida antarctica B in a solvent-free system. The reaction was carried out at a glycerol to triacylglycerol molar ratio of 8:1 with 2% of lipase. Acylglycerides, free fatty acids (FFA) and glycerol produced were separated employing the molecular distillation process. Starting from a product of enzymatic reaction 25.06% of triacylglycerols, 46.63% of diacylglycerides, 21.72% of monoacylglycerides, 5.38% of FFA and 1.21% of glycerol and after consecutively distillations, monoacylglycerides with 80% of purity was obtained and also oil with 54% of diacylglycerides to be used in human dietary.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000600034monoacylglyceroldiacylglycerolmolecular distillation
spellingShingle Patricia Bogalhos Lucente Fregolente
Gláucia Maria F. Pinto
Maria Regina Wolf-Maciel
Rubens Maciel Filho
César Benedito Batistella
Produção de monoacilgliceróis e diacilgliceróis via glicerólise enzimática e destilação molecular Production of monoglycerides and diglycerides through lipase-catalyzed glycerolysis and molecular distillation
Química Nova
monoacylglycerol
diacylglycerol
molecular distillation
title Produção de monoacilgliceróis e diacilgliceróis via glicerólise enzimática e destilação molecular Production of monoglycerides and diglycerides through lipase-catalyzed glycerolysis and molecular distillation
title_full Produção de monoacilgliceróis e diacilgliceróis via glicerólise enzimática e destilação molecular Production of monoglycerides and diglycerides through lipase-catalyzed glycerolysis and molecular distillation
title_fullStr Produção de monoacilgliceróis e diacilgliceróis via glicerólise enzimática e destilação molecular Production of monoglycerides and diglycerides through lipase-catalyzed glycerolysis and molecular distillation
title_full_unstemmed Produção de monoacilgliceróis e diacilgliceróis via glicerólise enzimática e destilação molecular Production of monoglycerides and diglycerides through lipase-catalyzed glycerolysis and molecular distillation
title_short Produção de monoacilgliceróis e diacilgliceróis via glicerólise enzimática e destilação molecular Production of monoglycerides and diglycerides through lipase-catalyzed glycerolysis and molecular distillation
title_sort producao de monoacilglicerois e diacilglicerois via glicerolise enzimatica e destilacao molecular production of monoglycerides and diglycerides through lipase catalyzed glycerolysis and molecular distillation
topic monoacylglycerol
diacylglycerol
molecular distillation
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000600034
work_keys_str_mv AT patriciabogalhoslucentefregolente producaodemonoacilgliceroisediacilgliceroisviagliceroliseenzimaticaedestilacaomolecularproductionofmonoglyceridesanddiglyceridesthroughlipasecatalyzedglycerolysisandmoleculardistillation
AT glauciamariafpinto producaodemonoacilgliceroisediacilgliceroisviagliceroliseenzimaticaedestilacaomolecularproductionofmonoglyceridesanddiglyceridesthroughlipasecatalyzedglycerolysisandmoleculardistillation
AT mariareginawolfmaciel producaodemonoacilgliceroisediacilgliceroisviagliceroliseenzimaticaedestilacaomolecularproductionofmonoglyceridesanddiglyceridesthroughlipasecatalyzedglycerolysisandmoleculardistillation
AT rubensmacielfilho producaodemonoacilgliceroisediacilgliceroisviagliceroliseenzimaticaedestilacaomolecularproductionofmonoglyceridesanddiglyceridesthroughlipasecatalyzedglycerolysisandmoleculardistillation
AT cesarbeneditobatistella producaodemonoacilgliceroisediacilgliceroisviagliceroliseenzimaticaedestilacaomolecularproductionofmonoglyceridesanddiglyceridesthroughlipasecatalyzedglycerolysisandmoleculardistillation