Synthesis and characterization of a novel microporous lanthanide based metal-organic framework (MOF) using napthalenedicarboxylate acid
A novel metal-organic framework based on naphthalenedicarboxylic acid is described. By solvothermal reaction method, 2,6-Naphthalenedicarboxylic acid, existing organic ligands that have never been used to support La-MOFs, was synthesized using acetic acid as the solvent and lanthanum nitrate hexahyd...
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| Format: | Article |
| Language: | English |
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Elsevier
2020-07-01
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| Series: | Journal of Materials Research and Technology |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2238785420312813 |
| _version_ | 1811276714841473024 |
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| author | Nasruddin A Zulys Fayza Yulia Achmad Buhori Naufal Muhadzib Muhammad Ghiyats Bidyut B. Saha |
| author_facet | Nasruddin A Zulys Fayza Yulia Achmad Buhori Naufal Muhadzib Muhammad Ghiyats Bidyut B. Saha |
| author_sort | Nasruddin |
| collection | DOAJ |
| description | A novel metal-organic framework based on naphthalenedicarboxylic acid is described. By solvothermal reaction method, 2,6-Naphthalenedicarboxylic acid, existing organic ligands that have never been used to support La-MOFs, was synthesized using acetic acid as the solvent and lanthanum nitrate hexahydrate as a metal source. So far, this type of metal-organic framework based lanthanum ion has not been investigated before. La-NDC MOFs were characterized to determine its functional groups contained in La-MOFs, morphology and particle size, crystallinity, optical and thermal stability by SEM (Scanning Electron Microscopy), FTIR (Fourier transform infrared) spectroscopy, XRD (X-ray Diffraction), UV-vis and TGA (thermogravimetric analysis) sequencely. The adsorption/desorption isotherms of N2 were measured at 77.4 K to know the specific surface area and pore volume of La-NDC MOF. BET (Brunauer-Emmet-Teller) equation was also applied to calculate the surface area of compounds. |
| first_indexed | 2024-04-13T00:01:48Z |
| format | Article |
| id | doaj.art-a0a4bdbef86a47a3976daaf1629cba67 |
| institution | Directory Open Access Journal |
| issn | 2238-7854 |
| language | English |
| last_indexed | 2024-04-13T00:01:48Z |
| publishDate | 2020-07-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Materials Research and Technology |
| spelling | doaj.art-a0a4bdbef86a47a3976daaf1629cba672022-12-22T03:11:20ZengElsevierJournal of Materials Research and Technology2238-78542020-07-019474097417Synthesis and characterization of a novel microporous lanthanide based metal-organic framework (MOF) using napthalenedicarboxylate acid Nasruddin0A Zulys1Fayza Yulia2Achmad Buhori3Naufal Muhadzib4Muhammad Ghiyats5Bidyut B. Saha6Department of Mechanical Engineering, Faculty of Engineering, Universitas Indonesia, Depok, 16424, Indonesia; Corresponding author.Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok, 16424, IndonesiaDepartment of Mechanical Engineering, Faculty of Engineering, Universitas Indonesia, Depok, 16424, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok, 16424, IndonesiaDepartment of Mechanical Engineering, Faculty of Engineering, Universitas Indonesia, Depok, 16424, IndonesiaDepartment of Mechanical Engineering, Faculty of Engineering, Universitas Indonesia, Depok, 16424, IndonesiaIndonesia International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan; Mechanical Engineering Department, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, JapanA novel metal-organic framework based on naphthalenedicarboxylic acid is described. By solvothermal reaction method, 2,6-Naphthalenedicarboxylic acid, existing organic ligands that have never been used to support La-MOFs, was synthesized using acetic acid as the solvent and lanthanum nitrate hexahydrate as a metal source. So far, this type of metal-organic framework based lanthanum ion has not been investigated before. La-NDC MOFs were characterized to determine its functional groups contained in La-MOFs, morphology and particle size, crystallinity, optical and thermal stability by SEM (Scanning Electron Microscopy), FTIR (Fourier transform infrared) spectroscopy, XRD (X-ray Diffraction), UV-vis and TGA (thermogravimetric analysis) sequencely. The adsorption/desorption isotherms of N2 were measured at 77.4 K to know the specific surface area and pore volume of La-NDC MOF. BET (Brunauer-Emmet-Teller) equation was also applied to calculate the surface area of compounds.http://www.sciencedirect.com/science/article/pii/S2238785420312813LanthanideLanthanumMetal-Organic frameworks (MOFs)NDC. |
| spellingShingle | Nasruddin A Zulys Fayza Yulia Achmad Buhori Naufal Muhadzib Muhammad Ghiyats Bidyut B. Saha Synthesis and characterization of a novel microporous lanthanide based metal-organic framework (MOF) using napthalenedicarboxylate acid Journal of Materials Research and Technology Lanthanide Lanthanum Metal-Organic frameworks (MOFs) NDC. |
| title | Synthesis and characterization of a novel microporous lanthanide based metal-organic framework (MOF) using napthalenedicarboxylate acid |
| title_full | Synthesis and characterization of a novel microporous lanthanide based metal-organic framework (MOF) using napthalenedicarboxylate acid |
| title_fullStr | Synthesis and characterization of a novel microporous lanthanide based metal-organic framework (MOF) using napthalenedicarboxylate acid |
| title_full_unstemmed | Synthesis and characterization of a novel microporous lanthanide based metal-organic framework (MOF) using napthalenedicarboxylate acid |
| title_short | Synthesis and characterization of a novel microporous lanthanide based metal-organic framework (MOF) using napthalenedicarboxylate acid |
| title_sort | synthesis and characterization of a novel microporous lanthanide based metal organic framework mof using napthalenedicarboxylate acid |
| topic | Lanthanide Lanthanum Metal-Organic frameworks (MOFs) NDC. |
| url | http://www.sciencedirect.com/science/article/pii/S2238785420312813 |
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