Crystal structure of 1-(2-aminophenyl)-3-phenylurea
In the title compound, C13H13N3O, the phenyl ring makes a dihedral angle of 47.0 (1)° with the mean plane of the –NC(=O)N– unit, while the dihedral angle between the latter mean plane and the aminophenyl ring is 84.43 (7)°. In the crystal, molecules are linked via N—H...O hydrogen bonds involving th...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989014028175 |
| _version_ | 1818939170793455616 |
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| author | Joel T. Mague Shaaban K. Mohamed Mehmet Akkurt Omran A. Omran Mustafa R. Albayati |
| author_facet | Joel T. Mague Shaaban K. Mohamed Mehmet Akkurt Omran A. Omran Mustafa R. Albayati |
| author_sort | Joel T. Mague |
| collection | DOAJ |
| description | In the title compound, C13H13N3O, the phenyl ring makes a dihedral angle of 47.0 (1)° with the mean plane of the –NC(=O)N– unit, while the dihedral angle between the latter mean plane and the aminophenyl ring is 84.43 (7)°. In the crystal, molecules are linked via N—H...O hydrogen bonds involving the central –NHC(=O)NH– units, forming chains running parallel to the b axis. These chains associate with one another via N—H...O and N—H...N hydrogen bonds, from the pendant amino groups to the –NHC(=O)NH– units of adjacent molecules, forming columns propagating along [010]. The structure was refined as a two-component twin with a 0.933 (3):0.067 (3) domain ratio. |
| first_indexed | 2024-12-20T06:19:30Z |
| format | Article |
| id | doaj.art-a0ae3c3cc2e34cff8917fb3814735df1 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T06:19:30Z |
| publishDate | 2015-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-a0ae3c3cc2e34cff8917fb3814735df12022-12-21T19:50:27ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-02-01712o88o8910.1107/S2056989014028175su5051Crystal structure of 1-(2-aminophenyl)-3-phenylureaJoel T. Mague0Shaaban K. Mohamed1Mehmet Akkurt2Omran A. Omran3Mustafa R. Albayati4Department of Chemistry, Tulane University, New Orleans, LA 70118, USAChemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, EnglandDepartment of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, TurkeyChemistry Department, Faculty of Science, Sohag University, 82524 Sohag, EgyptKirkuk University, College of Science, Department of Chemistry, Kirkuk, IraqIn the title compound, C13H13N3O, the phenyl ring makes a dihedral angle of 47.0 (1)° with the mean plane of the –NC(=O)N– unit, while the dihedral angle between the latter mean plane and the aminophenyl ring is 84.43 (7)°. In the crystal, molecules are linked via N—H...O hydrogen bonds involving the central –NHC(=O)NH– units, forming chains running parallel to the b axis. These chains associate with one another via N—H...O and N—H...N hydrogen bonds, from the pendant amino groups to the –NHC(=O)NH– units of adjacent molecules, forming columns propagating along [010]. The structure was refined as a two-component twin with a 0.933 (3):0.067 (3) domain ratio.http://scripts.iucr.org/cgi-bin/paper?S2056989014028175crystal structureurea derivativesN—H...N hydrogen bondsN—H...O hydrogen bondstwinned structure |
| spellingShingle | Joel T. Mague Shaaban K. Mohamed Mehmet Akkurt Omran A. Omran Mustafa R. Albayati Crystal structure of 1-(2-aminophenyl)-3-phenylurea Acta Crystallographica Section E: Crystallographic Communications crystal structure urea derivatives N—H...N hydrogen bonds N—H...O hydrogen bonds twinned structure |
| title | Crystal structure of 1-(2-aminophenyl)-3-phenylurea |
| title_full | Crystal structure of 1-(2-aminophenyl)-3-phenylurea |
| title_fullStr | Crystal structure of 1-(2-aminophenyl)-3-phenylurea |
| title_full_unstemmed | Crystal structure of 1-(2-aminophenyl)-3-phenylurea |
| title_short | Crystal structure of 1-(2-aminophenyl)-3-phenylurea |
| title_sort | crystal structure of 1 2 aminophenyl 3 phenylurea |
| topic | crystal structure urea derivatives N—H...N hydrogen bonds N—H...O hydrogen bonds twinned structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989014028175 |
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