{Bis[2-(diphenylphosphino)phenyl] ether-κ2P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2N:N′)copper(I) hexafluoridophosphate acetonitrile solvate
In the title compound, [Cu(C14H12N2O4)(C36H28OP2)]PF6·CH3CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2′-biphenyl-4,4′-dicarboxylate ligand and two P atoms from the bis[2-(diphenylphosphino)phenyl] ether ligand in a distorted tetrahedra...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809024982 |
| _version_ | 1828856587035344896 |
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| author | Yu-Guang Ma Ling Ye Guang-Di Yang Ming Zhang Ai-Guo Yu |
| author_facet | Yu-Guang Ma Ling Ye Guang-Di Yang Ming Zhang Ai-Guo Yu |
| author_sort | Yu-Guang Ma |
| collection | DOAJ |
| description | In the title compound, [Cu(C14H12N2O4)(C36H28OP2)]PF6·CH3CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2′-biphenyl-4,4′-dicarboxylate ligand and two P atoms from the bis[2-(diphenylphosphino)phenyl] ether ligand in a distorted tetrahedral environment. In the cation, the short distance of 3.870 (4) Å between the centroids of the benzene and phenyl rings suggests the existence of intramolecular π–π interactions. |
| first_indexed | 2024-12-13T01:18:32Z |
| format | Article |
| id | doaj.art-a0b794656a5643ed8e3f58c0c7ed43c9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:18:32Z |
| publishDate | 2009-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a0b794656a5643ed8e3f58c0c7ed43c92022-12-22T00:04:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m875m87510.1107/S1600536809024982{Bis[2-(diphenylphosphino)phenyl] ether-κ2P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2N:N′)copper(I) hexafluoridophosphate acetonitrile solvateYu-Guang MaLing YeGuang-Di YangMing ZhangAi-Guo YuIn the title compound, [Cu(C14H12N2O4)(C36H28OP2)]PF6·CH3CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2′-biphenyl-4,4′-dicarboxylate ligand and two P atoms from the bis[2-(diphenylphosphino)phenyl] ether ligand in a distorted tetrahedral environment. In the cation, the short distance of 3.870 (4) Å between the centroids of the benzene and phenyl rings suggests the existence of intramolecular π–π interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536809024982 |
| spellingShingle | Yu-Guang Ma Ling Ye Guang-Di Yang Ming Zhang Ai-Guo Yu {Bis[2-(diphenylphosphino)phenyl] ether-κ2P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2N:N′)copper(I) hexafluoridophosphate acetonitrile solvate Acta Crystallographica Section E |
| title | {Bis[2-(diphenylphosphino)phenyl] ether-κ2P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2N:N′)copper(I) hexafluoridophosphate acetonitrile solvate |
| title_full | {Bis[2-(diphenylphosphino)phenyl] ether-κ2P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2N:N′)copper(I) hexafluoridophosphate acetonitrile solvate |
| title_fullStr | {Bis[2-(diphenylphosphino)phenyl] ether-κ2P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2N:N′)copper(I) hexafluoridophosphate acetonitrile solvate |
| title_full_unstemmed | {Bis[2-(diphenylphosphino)phenyl] ether-κ2P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2N:N′)copper(I) hexafluoridophosphate acetonitrile solvate |
| title_short | {Bis[2-(diphenylphosphino)phenyl] ether-κ2P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2N:N′)copper(I) hexafluoridophosphate acetonitrile solvate |
| title_sort | bis 2 diphenylphosphino phenyl ether amp 954 2p p amp 8242 dimethyl 2 2 amp 8242 biphenyl 4 4 amp 8242 dicarboxylate amp 954 2n n amp 8242 copper i hexafluoridophosphate acetonitrile solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809024982 |
| work_keys_str_mv | AT yuguangma bis2diphenylphosphinophenyletheramp9542ppamp8242dimethyl22amp8242biphenyl44amp8242dicarboxylateamp9542nnamp8242copperihexafluoridophosphateacetonitrilesolvate AT lingye bis2diphenylphosphinophenyletheramp9542ppamp8242dimethyl22amp8242biphenyl44amp8242dicarboxylateamp9542nnamp8242copperihexafluoridophosphateacetonitrilesolvate AT guangdiyang bis2diphenylphosphinophenyletheramp9542ppamp8242dimethyl22amp8242biphenyl44amp8242dicarboxylateamp9542nnamp8242copperihexafluoridophosphateacetonitrilesolvate AT mingzhang bis2diphenylphosphinophenyletheramp9542ppamp8242dimethyl22amp8242biphenyl44amp8242dicarboxylateamp9542nnamp8242copperihexafluoridophosphateacetonitrilesolvate AT aiguoyu bis2diphenylphosphinophenyletheramp9542ppamp8242dimethyl22amp8242biphenyl44amp8242dicarboxylateamp9542nnamp8242copperihexafluoridophosphateacetonitrilesolvate |