A comparative study of volatile components of propolis (bee glue) collected from Haramaya University and Assela Beekeeping Centers, Ethiopia
The investigation of the volatile compounds of essential oils of propolis from two geographic origins of Ethiopia (Haramaya and Assela) was made by GC-MS. A total of 62 components of the oil were identified from both samples. The identified constituents of the oils may be divided into seven differen...
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Format: | Article |
Language: | English |
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Chemical Society of Ethiopia
2012-12-01
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Series: | Bulletin of the Chemical Society of Ethiopia |
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Online Access: | http://www.ajol.info/index.php/bcse/article/view/80266 |
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author | Kesatebrhan Haile Tesfahun Kebede Aman Dekebo |
author_facet | Kesatebrhan Haile Tesfahun Kebede Aman Dekebo |
author_sort | Kesatebrhan Haile |
collection | DOAJ |
description | The investigation of the volatile compounds of essential oils of propolis from two geographic origins of Ethiopia (Haramaya and Assela) was made by GC-MS. A total of 62 components of the oil were identified from both samples. The identified constituents of the oils may be divided into seven different groups: oxygenated monoterpenes (29.81% Haramaya, 9.45% Asella), sesquiterpenes (15.20% Haramaya, 19.05% Assela), oxygenated sesquiterpenes (11.86% Haramaya, 18.56% Assela), aromatic (14.93% Haramaya, 4.25% Assela), oxygenated aromatic (17.59% Haramaya, 4.58% Assela), aliphatic (5.06% Haramaya, 7.62% Assela) and oxygenated aliphatic (7.84% Haramaya, 25.17% Asella). The major volatile compounds of Haramaya propolis consist of calamenene (13.82%), 4-terpineol (8.57%), epi-bicyclosesquiphellandrene (8.37%), 4-(2-acetyl-5,5-dimethylcyclopent-2-enylidene)butan-2-one (7.83%) and 3-isopropyl-6-methyl-2-oxo-1-(3-oxobutyl)-cyclo- hexanecarbaldehyde (5.90%). Whereas the most abundant constituents of Assela propolis were 5,6,7,8-tetramethylbicyclo[4,1,0]hept-4-en-3-one (15.01%), acoradien (13.77%), epicedrol (6.80%) and (6E,6E)-3,7,11,15-tetramethyl-1,6,10,14-hexadecatetraen-3-ol (6.14%). Ten compounds which were found in both samples of propolis were <i>trans</i>-pinocarveol, α-cadinol, <i>cis</i>-verbenol, α-campholenal, 4-terpineol, <i>p</i>-cymen-8-ol, <i>p</i>-menth-1-en-8-ol, epi-bicyclosesquiphellandrene, calamenene and 3-isopropyl-6-methyl-2-oxo-1-(3-oxobutyl)-cyclohexanecarbaldehyde.DOI: http://dx.doi.org/10.4314/bcse.v26i3.4 |
first_indexed | 2024-04-11T22:56:26Z |
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issn | 1011-3924 1726-801X |
language | English |
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publishDate | 2012-12-01 |
publisher | Chemical Society of Ethiopia |
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series | Bulletin of the Chemical Society of Ethiopia |
spelling | doaj.art-a0baa585e1164830824d1551db3640a72022-12-22T03:58:23ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2012-12-01263353360A comparative study of volatile components of propolis (bee glue) collected from Haramaya University and Assela Beekeeping Centers, EthiopiaKesatebrhan HaileTesfahun KebedeAman DekeboThe investigation of the volatile compounds of essential oils of propolis from two geographic origins of Ethiopia (Haramaya and Assela) was made by GC-MS. A total of 62 components of the oil were identified from both samples. The identified constituents of the oils may be divided into seven different groups: oxygenated monoterpenes (29.81% Haramaya, 9.45% Asella), sesquiterpenes (15.20% Haramaya, 19.05% Assela), oxygenated sesquiterpenes (11.86% Haramaya, 18.56% Assela), aromatic (14.93% Haramaya, 4.25% Assela), oxygenated aromatic (17.59% Haramaya, 4.58% Assela), aliphatic (5.06% Haramaya, 7.62% Assela) and oxygenated aliphatic (7.84% Haramaya, 25.17% Asella). The major volatile compounds of Haramaya propolis consist of calamenene (13.82%), 4-terpineol (8.57%), epi-bicyclosesquiphellandrene (8.37%), 4-(2-acetyl-5,5-dimethylcyclopent-2-enylidene)butan-2-one (7.83%) and 3-isopropyl-6-methyl-2-oxo-1-(3-oxobutyl)-cyclo- hexanecarbaldehyde (5.90%). Whereas the most abundant constituents of Assela propolis were 5,6,7,8-tetramethylbicyclo[4,1,0]hept-4-en-3-one (15.01%), acoradien (13.77%), epicedrol (6.80%) and (6E,6E)-3,7,11,15-tetramethyl-1,6,10,14-hexadecatetraen-3-ol (6.14%). Ten compounds which were found in both samples of propolis were <i>trans</i>-pinocarveol, α-cadinol, <i>cis</i>-verbenol, α-campholenal, 4-terpineol, <i>p</i>-cymen-8-ol, <i>p</i>-menth-1-en-8-ol, epi-bicyclosesquiphellandrene, calamenene and 3-isopropyl-6-methyl-2-oxo-1-(3-oxobutyl)-cyclohexanecarbaldehyde.DOI: http://dx.doi.org/10.4314/bcse.v26i3.4http://www.ajol.info/index.php/bcse/article/view/80266PropolisBee glueMonoterpeneSesquiterpeneCalamenene4-Terpineol |
spellingShingle | Kesatebrhan Haile Tesfahun Kebede Aman Dekebo A comparative study of volatile components of propolis (bee glue) collected from Haramaya University and Assela Beekeeping Centers, Ethiopia Bulletin of the Chemical Society of Ethiopia Propolis Bee glue Monoterpene Sesquiterpene Calamenene 4-Terpineol |
title | A comparative study of volatile components of propolis (bee glue) collected from Haramaya University and Assela Beekeeping Centers, Ethiopia |
title_full | A comparative study of volatile components of propolis (bee glue) collected from Haramaya University and Assela Beekeeping Centers, Ethiopia |
title_fullStr | A comparative study of volatile components of propolis (bee glue) collected from Haramaya University and Assela Beekeeping Centers, Ethiopia |
title_full_unstemmed | A comparative study of volatile components of propolis (bee glue) collected from Haramaya University and Assela Beekeeping Centers, Ethiopia |
title_short | A comparative study of volatile components of propolis (bee glue) collected from Haramaya University and Assela Beekeeping Centers, Ethiopia |
title_sort | comparative study of volatile components of propolis bee glue collected from haramaya university and assela beekeeping centers ethiopia |
topic | Propolis Bee glue Monoterpene Sesquiterpene Calamenene 4-Terpineol |
url | http://www.ajol.info/index.php/bcse/article/view/80266 |
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