(1-Acetyl-2,6-diphenylpiperidin-4-ylidene)(phenyl)acetonitrile
In the title molecule, C27H24N2O, the piperidine ring adopts a boat conformation. The acetyl group at position 1 has a bisectional orientation. The two phenyl rings attached to the piperidine ring at positions 2 and 6 have bisectional and axial orientations, respectively, and make a dihedral angle o...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680800860X |
| _version_ | 1818974019063382016 |
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| author | R. J. Butcher A. Thiruvalluvar S. Balamurugan A. Balamurugan A. Manimekalai |
| author_facet | R. J. Butcher A. Thiruvalluvar S. Balamurugan A. Balamurugan A. Manimekalai |
| author_sort | R. J. Butcher |
| collection | DOAJ |
| description | In the title molecule, C27H24N2O, the piperidine ring adopts a boat conformation. The acetyl group at position 1 has a bisectional orientation. The two phenyl rings attached to the piperidine ring at positions 2 and 6 have bisectional and axial orientations, respectively, and make a dihedral angle of 75.27 (10)°. The phenylacetonitrile group at position 4 has an equatorial orientation. Molecules are linked by C—H...N, C—H...O intermolecular and C—H...π interactions. A C—H...O intramolecular interaction is also found in the molecule. |
| first_indexed | 2024-12-20T15:33:24Z |
| format | Article |
| id | doaj.art-a0e0dc1694774539b7e69a1ca7d63248 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T15:33:24Z |
| publishDate | 2008-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a0e0dc1694774539b7e69a1ca7d632482022-12-21T19:35:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645o797o79710.1107/S160053680800860X(1-Acetyl-2,6-diphenylpiperidin-4-ylidene)(phenyl)acetonitrileR. J. ButcherA. ThiruvalluvarS. BalamuruganA. BalamuruganA. ManimekalaiIn the title molecule, C27H24N2O, the piperidine ring adopts a boat conformation. The acetyl group at position 1 has a bisectional orientation. The two phenyl rings attached to the piperidine ring at positions 2 and 6 have bisectional and axial orientations, respectively, and make a dihedral angle of 75.27 (10)°. The phenylacetonitrile group at position 4 has an equatorial orientation. Molecules are linked by C—H...N, C—H...O intermolecular and C—H...π interactions. A C—H...O intramolecular interaction is also found in the molecule.http://scripts.iucr.org/cgi-bin/paper?S160053680800860X |
| spellingShingle | R. J. Butcher A. Thiruvalluvar S. Balamurugan A. Balamurugan A. Manimekalai (1-Acetyl-2,6-diphenylpiperidin-4-ylidene)(phenyl)acetonitrile Acta Crystallographica Section E |
| title | (1-Acetyl-2,6-diphenylpiperidin-4-ylidene)(phenyl)acetonitrile |
| title_full | (1-Acetyl-2,6-diphenylpiperidin-4-ylidene)(phenyl)acetonitrile |
| title_fullStr | (1-Acetyl-2,6-diphenylpiperidin-4-ylidene)(phenyl)acetonitrile |
| title_full_unstemmed | (1-Acetyl-2,6-diphenylpiperidin-4-ylidene)(phenyl)acetonitrile |
| title_short | (1-Acetyl-2,6-diphenylpiperidin-4-ylidene)(phenyl)acetonitrile |
| title_sort | 1 acetyl 2 6 diphenylpiperidin 4 ylidene phenyl acetonitrile |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680800860X |
| work_keys_str_mv | AT rjbutcher 1acetyl26diphenylpiperidin4ylidenephenylacetonitrile AT athiruvalluvar 1acetyl26diphenylpiperidin4ylidenephenylacetonitrile AT sbalamurugan 1acetyl26diphenylpiperidin4ylidenephenylacetonitrile AT abalamurugan 1acetyl26diphenylpiperidin4ylidenephenylacetonitrile AT amanimekalai 1acetyl26diphenylpiperidin4ylidenephenylacetonitrile |