Human exposure to per- and polyfluoroalkyl substances and other emerging contaminants in drinking water

Abstract A wide range of chemicals was measured in different types of drinking water and urine samples through target and non-target screening (NTS) to estimate human exposure. Tap water samples collected from 42 locations in Barcelona (August–October/2020, May/2021), tap water filtered with domesti...

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Main Authors: Dora Cserbik, Paula E. Redondo-Hasselerharm, Maria J. Farré, Josep Sanchís, Arantxa Bartolomé, Alexandra Paraian, Eva María Herrera, Josep Caixach, Cristina M. Villanueva, Cintia Flores
Format: Article
Language:English
Published: Nature Portfolio 2023-03-01
Series:npj Clean Water
Online Access:https://doi.org/10.1038/s41545-023-00236-y
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author Dora Cserbik
Paula E. Redondo-Hasselerharm
Maria J. Farré
Josep Sanchís
Arantxa Bartolomé
Alexandra Paraian
Eva María Herrera
Josep Caixach
Cristina M. Villanueva
Cintia Flores
author_facet Dora Cserbik
Paula E. Redondo-Hasselerharm
Maria J. Farré
Josep Sanchís
Arantxa Bartolomé
Alexandra Paraian
Eva María Herrera
Josep Caixach
Cristina M. Villanueva
Cintia Flores
author_sort Dora Cserbik
collection DOAJ
description Abstract A wide range of chemicals was measured in different types of drinking water and urine samples through target and non-target screening (NTS) to estimate human exposure. Tap water samples collected from 42 locations in Barcelona (August–October/2020, May/2021), tap water filtered with domestic activated carbon filters (AC, N = 6) and reverse osmosis (RO, N = 5), commercial bottled water (N = 10), and urine (N = 39) samples were included. 35 per- and polyfluoroalkyl substances (PFAS), bisphenol A, and nonylphenol were analyzed using LC–MS/MS and GC–MS/MS, and NTS using LC–HRMS. 9 PFAS were detected in unfiltered tap water of first sampling (79% samples, median = 30 ng/L), 6 in the second (69%, median = 9.8 ng/L), and 5 in 13% urine samples. NTS tentatively identified pharmaceuticals and other industrial chemicals in drinking water. PFAS were removed by RO and not by AC filters. Findings provide valuable information for exposure science and water quality monitoring of emerging drinking water contaminants.
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spelling doaj.art-a12f28e0f5014de3bd57cd57b48f603d2023-03-22T10:18:29ZengNature Portfolionpj Clean Water2059-70372023-03-016111010.1038/s41545-023-00236-yHuman exposure to per- and polyfluoroalkyl substances and other emerging contaminants in drinking waterDora Cserbik0Paula E. Redondo-Hasselerharm1Maria J. Farré2Josep Sanchís3Arantxa Bartolomé4Alexandra Paraian5Eva María Herrera6Josep Caixach7Cristina M. Villanueva8Cintia Flores9ISGlobalISGlobalCatalan Institute for Water Research, ICRACatalan Institute for Water Research, ICRAMass Spectrometry Laboratory/Organic Pollutants, Institute of Environmental Assessment and Water Research, IDAEA-CSICMass Spectrometry Laboratory/Organic Pollutants, Institute of Environmental Assessment and Water Research, IDAEA-CSICMass Spectrometry Laboratory/Organic Pollutants, Institute of Environmental Assessment and Water Research, IDAEA-CSICMass Spectrometry Laboratory/Organic Pollutants, Institute of Environmental Assessment and Water Research, IDAEA-CSICISGlobalMass Spectrometry Laboratory/Organic Pollutants, Institute of Environmental Assessment and Water Research, IDAEA-CSICAbstract A wide range of chemicals was measured in different types of drinking water and urine samples through target and non-target screening (NTS) to estimate human exposure. Tap water samples collected from 42 locations in Barcelona (August–October/2020, May/2021), tap water filtered with domestic activated carbon filters (AC, N = 6) and reverse osmosis (RO, N = 5), commercial bottled water (N = 10), and urine (N = 39) samples were included. 35 per- and polyfluoroalkyl substances (PFAS), bisphenol A, and nonylphenol were analyzed using LC–MS/MS and GC–MS/MS, and NTS using LC–HRMS. 9 PFAS were detected in unfiltered tap water of first sampling (79% samples, median = 30 ng/L), 6 in the second (69%, median = 9.8 ng/L), and 5 in 13% urine samples. NTS tentatively identified pharmaceuticals and other industrial chemicals in drinking water. PFAS were removed by RO and not by AC filters. Findings provide valuable information for exposure science and water quality monitoring of emerging drinking water contaminants.https://doi.org/10.1038/s41545-023-00236-y
spellingShingle Dora Cserbik
Paula E. Redondo-Hasselerharm
Maria J. Farré
Josep Sanchís
Arantxa Bartolomé
Alexandra Paraian
Eva María Herrera
Josep Caixach
Cristina M. Villanueva
Cintia Flores
Human exposure to per- and polyfluoroalkyl substances and other emerging contaminants in drinking water
npj Clean Water
title Human exposure to per- and polyfluoroalkyl substances and other emerging contaminants in drinking water
title_full Human exposure to per- and polyfluoroalkyl substances and other emerging contaminants in drinking water
title_fullStr Human exposure to per- and polyfluoroalkyl substances and other emerging contaminants in drinking water
title_full_unstemmed Human exposure to per- and polyfluoroalkyl substances and other emerging contaminants in drinking water
title_short Human exposure to per- and polyfluoroalkyl substances and other emerging contaminants in drinking water
title_sort human exposure to per and polyfluoroalkyl substances and other emerging contaminants in drinking water
url https://doi.org/10.1038/s41545-023-00236-y
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