Effect of laser-induced groove morphology on the wettability and performance of Lithium-ion batteries

Lithium-ion batteries are widely used for their high energy density, high power density, long lifetime, and safety which are crucial for the environmentally friendly future energy system. Electrodes are the key component of LIBs that determines battery performance. LiFePO4 is a common electrode used...

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Main Authors: Mulugeta Gebrekiros Berhe, Hong Geun Oh, Seung-Keun Park, Mounarik Mondal, Dongkyoung Lee
Format: Article
Language:English
Published: Elsevier 2023-07-01
Series:Materials & Design
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0264127523004355
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author Mulugeta Gebrekiros Berhe
Hong Geun Oh
Seung-Keun Park
Mounarik Mondal
Dongkyoung Lee
author_facet Mulugeta Gebrekiros Berhe
Hong Geun Oh
Seung-Keun Park
Mounarik Mondal
Dongkyoung Lee
author_sort Mulugeta Gebrekiros Berhe
collection DOAJ
description Lithium-ion batteries are widely used for their high energy density, high power density, long lifetime, and safety which are crucial for the environmentally friendly future energy system. Electrodes are the key component of LIBs that determines battery performance. LiFePO4 is a common electrode used in battery technology due to its long cycle life and good safety. Laser structuring of electrodes has recently been considered a promising approach to increase energy density. In this work, LiFePO4 electrodes were structured into a grid-type pattern by varying the laser power, resulting in different aspect ratios. To evaluate the effects of the structuring, wettability and electrochemical performance were tested. The wetting property was investigated using spread area, wetting time, and contact angle measurements. Besides, the wetting rate was measured using the wetting balance test and capillary rise test. Lucas Washburn model and Zhmud extended model were used to quantitatively express the wetting rate. The influence of gravity on the wetting performance was also investigated by comparing those models. Furthermore, an electrochemical test was performed to see the cyclic stability, rate capability, and charge–discharge profile with a C rate up to 1C.
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spelling doaj.art-a15c391dec484f8899a7958997b72ec02023-06-28T04:28:29ZengElsevierMaterials & Design0264-12752023-07-01231112020Effect of laser-induced groove morphology on the wettability and performance of Lithium-ion batteriesMulugeta Gebrekiros Berhe0Hong Geun Oh1Seung-Keun Park2Mounarik Mondal3Dongkyoung Lee4MaPS - Department of Mechanical Engineering, KU Leuven, Leuven, Belgium; Flanders Make, KU Leuven, Leuven, BelgiumDepartment of Advanced Materials Engineering, Chung-Ang University, Anseong, South KoreaDepartment of Advanced Materials Engineering, Chung-Ang University, Anseong, South KoreaDepartment of Mechanical and Automotive Engineering, Cheonan College of Engineering, Kongju National University, Cheonan, South KoreaDepartment of Future Convergence Engineering, Cheonan College of Engineering, Kongju National University, Cheonan, South Korea; Department of Mechanical and Automotive Engineering, Cheonan College of Engineering, Kongju National University, Cheonan, South Korea; Center for Advanced Powder Materials and Parts of Powder (CAMP2), Cheonan College of Engineering, Kongju National University, Cheonan, South Korea; Global Institute of Manufacturing Technology (GITECH), Kongju National University, Cheonan, South Korea; Corresponding author at: Department of Mechanical and Automotive Engineering, Cheonan College of Engineering, Kongju National University, Cheonan, 31080, South Korea.Lithium-ion batteries are widely used for their high energy density, high power density, long lifetime, and safety which are crucial for the environmentally friendly future energy system. Electrodes are the key component of LIBs that determines battery performance. LiFePO4 is a common electrode used in battery technology due to its long cycle life and good safety. Laser structuring of electrodes has recently been considered a promising approach to increase energy density. In this work, LiFePO4 electrodes were structured into a grid-type pattern by varying the laser power, resulting in different aspect ratios. To evaluate the effects of the structuring, wettability and electrochemical performance were tested. The wetting property was investigated using spread area, wetting time, and contact angle measurements. Besides, the wetting rate was measured using the wetting balance test and capillary rise test. Lucas Washburn model and Zhmud extended model were used to quantitatively express the wetting rate. The influence of gravity on the wetting performance was also investigated by comparing those models. Furthermore, an electrochemical test was performed to see the cyclic stability, rate capability, and charge–discharge profile with a C rate up to 1C.http://www.sciencedirect.com/science/article/pii/S0264127523004355Laser structuring3D electrodeAspect-ratioWettabilityBattery performance
spellingShingle Mulugeta Gebrekiros Berhe
Hong Geun Oh
Seung-Keun Park
Mounarik Mondal
Dongkyoung Lee
Effect of laser-induced groove morphology on the wettability and performance of Lithium-ion batteries
Materials & Design
Laser structuring
3D electrode
Aspect-ratio
Wettability
Battery performance
title Effect of laser-induced groove morphology on the wettability and performance of Lithium-ion batteries
title_full Effect of laser-induced groove morphology on the wettability and performance of Lithium-ion batteries
title_fullStr Effect of laser-induced groove morphology on the wettability and performance of Lithium-ion batteries
title_full_unstemmed Effect of laser-induced groove morphology on the wettability and performance of Lithium-ion batteries
title_short Effect of laser-induced groove morphology on the wettability and performance of Lithium-ion batteries
title_sort effect of laser induced groove morphology on the wettability and performance of lithium ion batteries
topic Laser structuring
3D electrode
Aspect-ratio
Wettability
Battery performance
url http://www.sciencedirect.com/science/article/pii/S0264127523004355
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