2-Amino-5-chloropyridine–benzoic acid (1/1)
In the title compound, C5H5ClN2·C7H6O2, the carboxyl group of the benzoic acid molecule is twisted away from the attached ring by 14.22 (7)°. In the crystal, the 2-amino-5-chloropyridine molecules interact with the carboxyl groups of benzoic acid molecules thr...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810004447 |
| _version_ | 1818323417747685376 |
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| author | Hoong-Kun Fun Madhukar Hemamalini |
| author_facet | Hoong-Kun Fun Madhukar Hemamalini |
| author_sort | Hoong-Kun Fun |
| collection | DOAJ |
| description | In the title compound, C5H5ClN2·C7H6O2, the carboxyl group of the benzoic acid molecule is twisted away from the attached ring by 14.22 (7)°. In the crystal, the 2-amino-5-chloropyridine molecules interact with the carboxyl groups of benzoic acid molecules through N—H...O and O—H...N hydrogen bonds, forming cyclic R22(8) hydrogen-bonded motifs, and linking the molecules into chains parallel to the [001] direction. Neighbouring 2-amino-5-chloropyridine molecules are also centrosymmetrically paired through C—H...Cl hydrogen bonds, forming another R22(8) motif. The crystal structure is further stabilized by weak C—H...O hydrogen bonds. |
| first_indexed | 2024-12-13T11:12:22Z |
| format | Article |
| id | doaj.art-a1648b8c50cb4a789739ef555925089d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T11:12:22Z |
| publishDate | 2010-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a1648b8c50cb4a789739ef555925089d2022-12-21T23:48:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-03-01663o578o57810.1107/S16005368100044472-Amino-5-chloropyridine–benzoic acid (1/1)Hoong-Kun FunMadhukar HemamaliniIn the title compound, C5H5ClN2·C7H6O2, the carboxyl group of the benzoic acid molecule is twisted away from the attached ring by 14.22 (7)°. In the crystal, the 2-amino-5-chloropyridine molecules interact with the carboxyl groups of benzoic acid molecules through N—H...O and O—H...N hydrogen bonds, forming cyclic R22(8) hydrogen-bonded motifs, and linking the molecules into chains parallel to the [001] direction. Neighbouring 2-amino-5-chloropyridine molecules are also centrosymmetrically paired through C—H...Cl hydrogen bonds, forming another R22(8) motif. The crystal structure is further stabilized by weak C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536810004447 |
| spellingShingle | Hoong-Kun Fun Madhukar Hemamalini 2-Amino-5-chloropyridine–benzoic acid (1/1) Acta Crystallographica Section E |
| title | 2-Amino-5-chloropyridine–benzoic acid (1/1) |
| title_full | 2-Amino-5-chloropyridine–benzoic acid (1/1) |
| title_fullStr | 2-Amino-5-chloropyridine–benzoic acid (1/1) |
| title_full_unstemmed | 2-Amino-5-chloropyridine–benzoic acid (1/1) |
| title_short | 2-Amino-5-chloropyridine–benzoic acid (1/1) |
| title_sort | 2 amino 5 chloropyridine amp 8211 benzoic acid 1 1 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810004447 |
| work_keys_str_mv | AT hoongkunfun 2amino5chloropyridineamp8211benzoicacid11 AT madhukarhemamalini 2amino5chloropyridineamp8211benzoicacid11 |