3-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-d-glucofuranose
The title compound, C24H27NO9, is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropylidene-a-d-glucofuran-5-one with nitromethane. The conformation of the five membered rings is as expected from the precursor compound and the molecule is folded with a dihedral angle of 5...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808043353 |
| Summary: | The title compound, C24H27NO9, is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropylidene-a-d-glucofuran-5-one with nitromethane. The conformation of the five membered rings is as expected from the precursor compound and the molecule is folded with a dihedral angle of 51.4 (2)° between the aromatic rings. One O—H...O hydrogen bond and some intramolecular and intermolecular C—H...O interactions are observed in the structure. |
|---|---|
| ISSN: | 1600-5368 |