3-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-d-glucofuranose
The title compound, C24H27NO9, is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropylidene-a-d-glucofuran-5-one with nitromethane. The conformation of the five membered rings is as expected from the precursor compound and the molecule is folded with a dihedral angle of 5...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808043353 |
| _version_ | 1819289010595430400 |
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| author | Ramón J. Estévez Juan C. Estévez Laura Valencia Begoña Pampín |
| author_facet | Ramón J. Estévez Juan C. Estévez Laura Valencia Begoña Pampín |
| author_sort | Ramón J. Estévez |
| collection | DOAJ |
| description | The title compound, C24H27NO9, is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropylidene-a-d-glucofuran-5-one with nitromethane. The conformation of the five membered rings is as expected from the precursor compound and the molecule is folded with a dihedral angle of 51.4 (2)° between the aromatic rings. One O—H...O hydrogen bond and some intramolecular and intermolecular C—H...O interactions are observed in the structure. |
| first_indexed | 2024-12-24T03:00:03Z |
| format | Article |
| id | doaj.art-a1673d0962b74e42850f2d0fccabee5c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:00:03Z |
| publishDate | 2009-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a1673d0962b74e42850f2d0fccabee5c2022-12-21T17:18:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652o332o33310.1107/S16005368080433533-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-d-glucofuranoseRamón J. EstévezJuan C. EstévezLaura ValenciaBegoña PampínThe title compound, C24H27NO9, is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropylidene-a-d-glucofuran-5-one with nitromethane. The conformation of the five membered rings is as expected from the precursor compound and the molecule is folded with a dihedral angle of 51.4 (2)° between the aromatic rings. One O—H...O hydrogen bond and some intramolecular and intermolecular C—H...O interactions are observed in the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808043353 |
| spellingShingle | Ramón J. Estévez Juan C. Estévez Laura Valencia Begoña Pampín 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-d-glucofuranose Acta Crystallographica Section E |
| title | 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-d-glucofuranose |
| title_full | 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-d-glucofuranose |
| title_fullStr | 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-d-glucofuranose |
| title_full_unstemmed | 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-d-glucofuranose |
| title_short | 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-d-glucofuranose |
| title_sort | 3 o benzyl 6 o benzoyl 1 2 o isopropilidene 5 c nitromethyl a d glucofuranose |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808043353 |
| work_keys_str_mv | AT ram243njest233vez 3obenzyl6obenzoyl12oisopropilidene5cnitromethyladglucofuranose AT juancest233vez 3obenzyl6obenzoyl12oisopropilidene5cnitromethyladglucofuranose AT lauravalencia 3obenzyl6obenzoyl12oisopropilidene5cnitromethyladglucofuranose AT bego241apamp237n 3obenzyl6obenzoyl12oisopropilidene5cnitromethyladglucofuranose |