Quantitative Determination of Ethylene Using a Smartphone-Based Optical Fiber Sensor (SOFS) Coupled with Pyrene-Tagged Grubbs Catalyst
For rapid and portable detection of ethylene in commercial fruit ripening storage rooms, we designed a smartphone-based optical fiber sensor (SOFS), which is composed of a 15 mW 365 nm laser for fluorescence signal excitation and a bifurcated fiber system for signal flow direction from probe to smar...
Main Authors: | , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2022-05-01
|
Series: | Biosensors |
Subjects: | |
Online Access: | https://www.mdpi.com/2079-6374/12/5/316 |
_version_ | 1827670057799385088 |
---|---|
author | Xin Yang Justin Lee Kee Leong Mingtai Sun Linzhi Jing Yuannian Zhang Tian Wang Suhua Wang Dejian Huang |
author_facet | Xin Yang Justin Lee Kee Leong Mingtai Sun Linzhi Jing Yuannian Zhang Tian Wang Suhua Wang Dejian Huang |
author_sort | Xin Yang |
collection | DOAJ |
description | For rapid and portable detection of ethylene in commercial fruit ripening storage rooms, we designed a smartphone-based optical fiber sensor (SOFS), which is composed of a 15 mW 365 nm laser for fluorescence signal excitation and a bifurcated fiber system for signal flow direction from probe to smartphone. Paired with a pyrene-tagged Grubbs catalyst (PYG) probe, our SOFS showed a wide linearity range up to 350 ppm with a detection limit of 0.6 ppm. The common gases in the warehouse had no significant interference with the results. The device is portable (18 cm × 8 cm × 6 cm) with an inbuilt power supply and replaceable optical fiber sensor tip. The images are processed with a dedicated smartphone application for RGB analysis and ethylene concentration. The device was applied in detection of ethylene generated from apples, avocados, and bananas. The linear correlation data showed agreement with data generated from a fluorometer. The SOFS provides a rapid, compact, cost-effective solution for determination of the fruit ethylene concentration dynamic during ripening for better fruit harvest timing and postharvest management to minimize wastage. |
first_indexed | 2024-03-10T03:15:46Z |
format | Article |
id | doaj.art-a16aaff0779b42188332e6e9e58dce20 |
institution | Directory Open Access Journal |
issn | 2079-6374 |
language | English |
last_indexed | 2024-03-10T03:15:46Z |
publishDate | 2022-05-01 |
publisher | MDPI AG |
record_format | Article |
series | Biosensors |
spelling | doaj.art-a16aaff0779b42188332e6e9e58dce202023-11-23T10:15:44ZengMDPI AGBiosensors2079-63742022-05-0112531610.3390/bios12050316Quantitative Determination of Ethylene Using a Smartphone-Based Optical Fiber Sensor (SOFS) Coupled with Pyrene-Tagged Grubbs CatalystXin Yang0Justin Lee Kee Leong1Mingtai Sun2Linzhi Jing3Yuannian Zhang4Tian Wang5Suhua Wang6Dejian Huang7Department of Food Science and Technology, National University of Singapore, 2 Science Drive 2, Singapore 117542, SingaporeDepartment of Food Science and Technology, National University of Singapore, 2 Science Drive 2, Singapore 117542, SingaporeDepartment of Food Science and Technology, National University of Singapore, 2 Science Drive 2, Singapore 117542, SingaporeDepartment of Food Science and Technology, National University of Singapore, 2 Science Drive 2, Singapore 117542, SingaporeDepartment of Food Science and Technology, National University of Singapore, 2 Science Drive 2, Singapore 117542, SingaporeDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, SingaporeSchool of Environmental Science and Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, ChinaDepartment of Food Science and Technology, National University of Singapore, 2 Science Drive 2, Singapore 117542, SingaporeFor rapid and portable detection of ethylene in commercial fruit ripening storage rooms, we designed a smartphone-based optical fiber sensor (SOFS), which is composed of a 15 mW 365 nm laser for fluorescence signal excitation and a bifurcated fiber system for signal flow direction from probe to smartphone. Paired with a pyrene-tagged Grubbs catalyst (PYG) probe, our SOFS showed a wide linearity range up to 350 ppm with a detection limit of 0.6 ppm. The common gases in the warehouse had no significant interference with the results. The device is portable (18 cm × 8 cm × 6 cm) with an inbuilt power supply and replaceable optical fiber sensor tip. The images are processed with a dedicated smartphone application for RGB analysis and ethylene concentration. The device was applied in detection of ethylene generated from apples, avocados, and bananas. The linear correlation data showed agreement with data generated from a fluorometer. The SOFS provides a rapid, compact, cost-effective solution for determination of the fruit ethylene concentration dynamic during ripening for better fruit harvest timing and postharvest management to minimize wastage.https://www.mdpi.com/2079-6374/12/5/316ethylenefluorescence probesmartphoneGrubbs catalystfruit ripening |
spellingShingle | Xin Yang Justin Lee Kee Leong Mingtai Sun Linzhi Jing Yuannian Zhang Tian Wang Suhua Wang Dejian Huang Quantitative Determination of Ethylene Using a Smartphone-Based Optical Fiber Sensor (SOFS) Coupled with Pyrene-Tagged Grubbs Catalyst Biosensors ethylene fluorescence probe smartphone Grubbs catalyst fruit ripening |
title | Quantitative Determination of Ethylene Using a Smartphone-Based Optical Fiber Sensor (SOFS) Coupled with Pyrene-Tagged Grubbs Catalyst |
title_full | Quantitative Determination of Ethylene Using a Smartphone-Based Optical Fiber Sensor (SOFS) Coupled with Pyrene-Tagged Grubbs Catalyst |
title_fullStr | Quantitative Determination of Ethylene Using a Smartphone-Based Optical Fiber Sensor (SOFS) Coupled with Pyrene-Tagged Grubbs Catalyst |
title_full_unstemmed | Quantitative Determination of Ethylene Using a Smartphone-Based Optical Fiber Sensor (SOFS) Coupled with Pyrene-Tagged Grubbs Catalyst |
title_short | Quantitative Determination of Ethylene Using a Smartphone-Based Optical Fiber Sensor (SOFS) Coupled with Pyrene-Tagged Grubbs Catalyst |
title_sort | quantitative determination of ethylene using a smartphone based optical fiber sensor sofs coupled with pyrene tagged grubbs catalyst |
topic | ethylene fluorescence probe smartphone Grubbs catalyst fruit ripening |
url | https://www.mdpi.com/2079-6374/12/5/316 |
work_keys_str_mv | AT xinyang quantitativedeterminationofethyleneusingasmartphonebasedopticalfibersensorsofscoupledwithpyrenetaggedgrubbscatalyst AT justinleekeeleong quantitativedeterminationofethyleneusingasmartphonebasedopticalfibersensorsofscoupledwithpyrenetaggedgrubbscatalyst AT mingtaisun quantitativedeterminationofethyleneusingasmartphonebasedopticalfibersensorsofscoupledwithpyrenetaggedgrubbscatalyst AT linzhijing quantitativedeterminationofethyleneusingasmartphonebasedopticalfibersensorsofscoupledwithpyrenetaggedgrubbscatalyst AT yuannianzhang quantitativedeterminationofethyleneusingasmartphonebasedopticalfibersensorsofscoupledwithpyrenetaggedgrubbscatalyst AT tianwang quantitativedeterminationofethyleneusingasmartphonebasedopticalfibersensorsofscoupledwithpyrenetaggedgrubbscatalyst AT suhuawang quantitativedeterminationofethyleneusingasmartphonebasedopticalfibersensorsofscoupledwithpyrenetaggedgrubbscatalyst AT dejianhuang quantitativedeterminationofethyleneusingasmartphonebasedopticalfibersensorsofscoupledwithpyrenetaggedgrubbscatalyst |