Geochemical Characteristics of the Chang 7 Source Rocks of the Triassic Yanchang Formation in Ordos Basin, China: Implications for Organic Matter Accumulation and Shale Oil Potential

The Chang 7 member of the Upper Triassic Yanchang Formation in the Ordos Basin is considered to hold the main source rocks for conventional and unconventional oil and gas. The lamination or lithology alteration in vertical and lateral directions, even over a short distance, is a common feature in la...

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Main Authors: Lewei Hao, Xiaofeng Ma, Wenqiang Gao, Zhaocai Ren, Huifei Tao, Weikai Huang
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/15/20/7815
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author Lewei Hao
Xiaofeng Ma
Wenqiang Gao
Zhaocai Ren
Huifei Tao
Weikai Huang
author_facet Lewei Hao
Xiaofeng Ma
Wenqiang Gao
Zhaocai Ren
Huifei Tao
Weikai Huang
author_sort Lewei Hao
collection DOAJ
description The Chang 7 member of the Upper Triassic Yanchang Formation in the Ordos Basin is considered to hold the main source rocks for conventional and unconventional oil and gas. The lamination or lithology alteration in vertical and lateral directions, even over a short distance, is a common feature in lacustrine source rocks. The differences in the geochemical characteristics of black shales, dark mudstones and interbedded sandstones have been scarcely reported, and their influences on the petroleum generation potential and shale oil potential are not clear. To this end, 22 core samples were collected from the Lower and Middle Chang 7 (C7-3 and C7-2) members of the Triassic from well CYX in the Qingcheng area. By conducting a series of geochemical analyses including TOC, Rock-Eval pyrolysis yields, bitumen extraction and quantification, and the separation and quantification of saturates, aromatics, resins and asphaltenes, along with biomarker analyses, several results were found. Firstly, the C7-3 and C7-2 source rocks are thermally mature and have entered into the stage of hydrocarbon generation. The C7-3 and C7-2 source rocks have a good to very good hydrocarbon generation potential especially the C7-3 black shales. Secondly, terrigenous source input is more abundant in C7-2, whereas the source input of phytoplankton, algae or microbial lipids is more abundant in C7-3. Moreover, a high TOC content basically corresponds to low wax indexes, terrigenous/aquatic ratios (TARs), and Pr/nC<sub>17</sub> and Ph/nC<sub>18</sub> ratios and high C<sub>27</sub>/C<sub>29</sub> regular sterane ratios, which suggests that the source input of phytoplankton, algae or microbial lipids is favorable for OM accumulation. Third, analyses of the molecular composition of saturated fractions in shales and interbedded sandstones and the production index demonstrate the migration of petroleum from organic-rich source rocks to their organic-lean counterparts. The C7-2 dark mudstones could be considered as a potential “sweet spot” since their oil saturation index (OSI) was the highest among all the studied samples and they are more enriched in light aliphatic fractions.
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spelling doaj.art-a174b2e5849e445a968087a84b2d76632023-11-24T00:01:32ZengMDPI AGEnergies1996-10732022-10-011520781510.3390/en15207815Geochemical Characteristics of the Chang 7 Source Rocks of the Triassic Yanchang Formation in Ordos Basin, China: Implications for Organic Matter Accumulation and Shale Oil PotentialLewei Hao0Xiaofeng Ma1Wenqiang Gao2Zhaocai Ren3Huifei Tao4Weikai Huang5Key Laboratory of Petroleum Resources, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730030, ChinaKey Laboratory of Petroleum Resources, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730030, ChinaKey Laboratory of Petroleum Resources, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730030, ChinaExploration and Development Research Institute of PetroChina Changqing Oilfield Company, Xi’an 710018, ChinaKey Laboratory of Petroleum Resources, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730030, ChinaKey Laboratory of Petroleum Resources, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730030, ChinaThe Chang 7 member of the Upper Triassic Yanchang Formation in the Ordos Basin is considered to hold the main source rocks for conventional and unconventional oil and gas. The lamination or lithology alteration in vertical and lateral directions, even over a short distance, is a common feature in lacustrine source rocks. The differences in the geochemical characteristics of black shales, dark mudstones and interbedded sandstones have been scarcely reported, and their influences on the petroleum generation potential and shale oil potential are not clear. To this end, 22 core samples were collected from the Lower and Middle Chang 7 (C7-3 and C7-2) members of the Triassic from well CYX in the Qingcheng area. By conducting a series of geochemical analyses including TOC, Rock-Eval pyrolysis yields, bitumen extraction and quantification, and the separation and quantification of saturates, aromatics, resins and asphaltenes, along with biomarker analyses, several results were found. Firstly, the C7-3 and C7-2 source rocks are thermally mature and have entered into the stage of hydrocarbon generation. The C7-3 and C7-2 source rocks have a good to very good hydrocarbon generation potential especially the C7-3 black shales. Secondly, terrigenous source input is more abundant in C7-2, whereas the source input of phytoplankton, algae or microbial lipids is more abundant in C7-3. Moreover, a high TOC content basically corresponds to low wax indexes, terrigenous/aquatic ratios (TARs), and Pr/nC<sub>17</sub> and Ph/nC<sub>18</sub> ratios and high C<sub>27</sub>/C<sub>29</sub> regular sterane ratios, which suggests that the source input of phytoplankton, algae or microbial lipids is favorable for OM accumulation. Third, analyses of the molecular composition of saturated fractions in shales and interbedded sandstones and the production index demonstrate the migration of petroleum from organic-rich source rocks to their organic-lean counterparts. The C7-2 dark mudstones could be considered as a potential “sweet spot” since their oil saturation index (OSI) was the highest among all the studied samples and they are more enriched in light aliphatic fractions.https://www.mdpi.com/1996-1073/15/20/7815source rocksorganic matter accumulationshale oil potentialYanchang FormationOrdos Basin
spellingShingle Lewei Hao
Xiaofeng Ma
Wenqiang Gao
Zhaocai Ren
Huifei Tao
Weikai Huang
Geochemical Characteristics of the Chang 7 Source Rocks of the Triassic Yanchang Formation in Ordos Basin, China: Implications for Organic Matter Accumulation and Shale Oil Potential
Energies
source rocks
organic matter accumulation
shale oil potential
Yanchang Formation
Ordos Basin
title Geochemical Characteristics of the Chang 7 Source Rocks of the Triassic Yanchang Formation in Ordos Basin, China: Implications for Organic Matter Accumulation and Shale Oil Potential
title_full Geochemical Characteristics of the Chang 7 Source Rocks of the Triassic Yanchang Formation in Ordos Basin, China: Implications for Organic Matter Accumulation and Shale Oil Potential
title_fullStr Geochemical Characteristics of the Chang 7 Source Rocks of the Triassic Yanchang Formation in Ordos Basin, China: Implications for Organic Matter Accumulation and Shale Oil Potential
title_full_unstemmed Geochemical Characteristics of the Chang 7 Source Rocks of the Triassic Yanchang Formation in Ordos Basin, China: Implications for Organic Matter Accumulation and Shale Oil Potential
title_short Geochemical Characteristics of the Chang 7 Source Rocks of the Triassic Yanchang Formation in Ordos Basin, China: Implications for Organic Matter Accumulation and Shale Oil Potential
title_sort geochemical characteristics of the chang 7 source rocks of the triassic yanchang formation in ordos basin china implications for organic matter accumulation and shale oil potential
topic source rocks
organic matter accumulation
shale oil potential
Yanchang Formation
Ordos Basin
url https://www.mdpi.com/1996-1073/15/20/7815
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