Impact of microcapsules wettability on thermal conductivity of microencapsulated phase change material(MPCM) suspensions

The purpose of this paper is to investigate the effect of the wettability on MPCM suspensions thermal conductivity. The wettability of the capsules, characterized by contact angle between solid capsules and carrying fluid, was modified by mixing two selected surfactants into the suspensions, i.e.,ce...

Full description

Bibliographic Details
Main Authors: Zhongzhu QIU, Chengfang QIN, Weiting JIANG, Puyan ZHENG, Tao ZHANG, Chengyao WANG, Chunying LI
Format: Article
Language:English
Published: The Japan Society of Mechanical Engineers 2018-01-01
Series:Journal of Thermal Science and Technology
Subjects:
Online Access:https://www.jstage.jst.go.jp/article/jtst/13/1/13_2018jtst0002/_pdf/-char/en
_version_ 1819183189816508416
author Zhongzhu QIU
Chengfang QIN
Weiting JIANG
Puyan ZHENG
Tao ZHANG
Chengyao WANG
Chunying LI
author_facet Zhongzhu QIU
Chengfang QIN
Weiting JIANG
Puyan ZHENG
Tao ZHANG
Chengyao WANG
Chunying LI
author_sort Zhongzhu QIU
collection DOAJ
description The purpose of this paper is to investigate the effect of the wettability on MPCM suspensions thermal conductivity. The wettability of the capsules, characterized by contact angle between solid capsules and carrying fluid, was modified by mixing two selected surfactants into the suspensions, i.e.,cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulfate(SDS) and changing such surfactants’ additive amount. Meanwhile, the Hot Disk 2500s thermal analyzer was applied to test the static thermal conductivity of the MPCM suspensions in which the mass fraction of capsules is 10wt.% and obtained the relation between the thermal conductivity and the contact angle. The results indicated, when the mass fraction of surfactants falls into the range of 0 -0.05wt.%, the effect of the CTAB is more significant than the SDS. However, when the mass fraction of surfactants continue to increase from 0.05wt.%, the significance of the SDS exceeded the CTAB. It was also found that the decrease in the contact angle led to the growth in thermal conductivity for both Maxwell model’s theoretical value and experimental results. When the contact angle fell into the range of 45°-95°, the Maxwell model’s theoretical results of the thermal conductivity could predict the thermal conductivity of MPCM suspensions with a good accuracy, but inversely when the contact angles were smaller than 45°, a significant gap was found between the two results. To remove such gap a correction factor “A” which is associated with contact angles was proposed.
first_indexed 2024-12-22T22:58:04Z
format Article
id doaj.art-a177e0b05c304e07a97edd474e84a6ca
institution Directory Open Access Journal
issn 1880-5566
language English
last_indexed 2024-12-22T22:58:04Z
publishDate 2018-01-01
publisher The Japan Society of Mechanical Engineers
record_format Article
series Journal of Thermal Science and Technology
spelling doaj.art-a177e0b05c304e07a97edd474e84a6ca2022-12-21T18:09:45ZengThe Japan Society of Mechanical EngineersJournal of Thermal Science and Technology1880-55662018-01-01131JTST0002JTST000210.1299/jtst.2018jtst0002jtstImpact of microcapsules wettability on thermal conductivity of microencapsulated phase change material(MPCM) suspensionsZhongzhu QIU0Chengfang QIN1Weiting JIANG2Puyan ZHENG3Tao ZHANG4Chengyao WANG5Chunying LI6College of Energy and Mechanical Engineering, Shanghai University of Electric PowerCollege of Energy and Mechanical Engineering, Shanghai University of Electric PowerCollege of Energy and Mechanical Engineering, Shanghai University of Electric PowerCollege of Energy and Mechanical Engineering, Shanghai University of Electric PowerCollege of Energy and Mechanical Engineering, Shanghai University of Electric PowerCollege of Energy and Mechanical Engineering, Shanghai University of Electric PowerCollege of Real Estate, Beijing Normal University, ZhuhaiThe purpose of this paper is to investigate the effect of the wettability on MPCM suspensions thermal conductivity. The wettability of the capsules, characterized by contact angle between solid capsules and carrying fluid, was modified by mixing two selected surfactants into the suspensions, i.e.,cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulfate(SDS) and changing such surfactants’ additive amount. Meanwhile, the Hot Disk 2500s thermal analyzer was applied to test the static thermal conductivity of the MPCM suspensions in which the mass fraction of capsules is 10wt.% and obtained the relation between the thermal conductivity and the contact angle. The results indicated, when the mass fraction of surfactants falls into the range of 0 -0.05wt.%, the effect of the CTAB is more significant than the SDS. However, when the mass fraction of surfactants continue to increase from 0.05wt.%, the significance of the SDS exceeded the CTAB. It was also found that the decrease in the contact angle led to the growth in thermal conductivity for both Maxwell model’s theoretical value and experimental results. When the contact angle fell into the range of 45°-95°, the Maxwell model’s theoretical results of the thermal conductivity could predict the thermal conductivity of MPCM suspensions with a good accuracy, but inversely when the contact angles were smaller than 45°, a significant gap was found between the two results. To remove such gap a correction factor “A” which is associated with contact angles was proposed.https://www.jstage.jst.go.jp/article/jtst/13/1/13_2018jtst0002/_pdf/-char/enmicroencapsulated phase change material suspensionscontact anglethermal conductivitymaxwell formulacorrection factor
spellingShingle Zhongzhu QIU
Chengfang QIN
Weiting JIANG
Puyan ZHENG
Tao ZHANG
Chengyao WANG
Chunying LI
Impact of microcapsules wettability on thermal conductivity of microencapsulated phase change material(MPCM) suspensions
Journal of Thermal Science and Technology
microencapsulated phase change material suspensions
contact angle
thermal conductivity
maxwell formula
correction factor
title Impact of microcapsules wettability on thermal conductivity of microencapsulated phase change material(MPCM) suspensions
title_full Impact of microcapsules wettability on thermal conductivity of microencapsulated phase change material(MPCM) suspensions
title_fullStr Impact of microcapsules wettability on thermal conductivity of microencapsulated phase change material(MPCM) suspensions
title_full_unstemmed Impact of microcapsules wettability on thermal conductivity of microencapsulated phase change material(MPCM) suspensions
title_short Impact of microcapsules wettability on thermal conductivity of microencapsulated phase change material(MPCM) suspensions
title_sort impact of microcapsules wettability on thermal conductivity of microencapsulated phase change material mpcm suspensions
topic microencapsulated phase change material suspensions
contact angle
thermal conductivity
maxwell formula
correction factor
url https://www.jstage.jst.go.jp/article/jtst/13/1/13_2018jtst0002/_pdf/-char/en
work_keys_str_mv AT zhongzhuqiu impactofmicrocapsuleswettabilityonthermalconductivityofmicroencapsulatedphasechangematerialmpcmsuspensions
AT chengfangqin impactofmicrocapsuleswettabilityonthermalconductivityofmicroencapsulatedphasechangematerialmpcmsuspensions
AT weitingjiang impactofmicrocapsuleswettabilityonthermalconductivityofmicroencapsulatedphasechangematerialmpcmsuspensions
AT puyanzheng impactofmicrocapsuleswettabilityonthermalconductivityofmicroencapsulatedphasechangematerialmpcmsuspensions
AT taozhang impactofmicrocapsuleswettabilityonthermalconductivityofmicroencapsulatedphasechangematerialmpcmsuspensions
AT chengyaowang impactofmicrocapsuleswettabilityonthermalconductivityofmicroencapsulatedphasechangematerialmpcmsuspensions
AT chunyingli impactofmicrocapsuleswettabilityonthermalconductivityofmicroencapsulatedphasechangematerialmpcmsuspensions