2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide

In the title compound, C15H12Br2N2O2, the molecule adopts an E conformation about the C=N double bond and a transoid conformation about the central N—N bond, with a C(=O)—N—N—C(H) dihedral angle of 169.4 (4)°. In the...

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Main Authors: Hongqi Li, B. K. Sarojini, B. Narayana, H. S. Yathirajan, William T. A. Harrison
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809024921
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author Hongqi Li
B. K. Sarojini
B. Narayana
H. S. Yathirajan
William T. A. Harrison
author_facet Hongqi Li
B. K. Sarojini
B. Narayana
H. S. Yathirajan
William T. A. Harrison
author_sort Hongqi Li
collection DOAJ
description In the title compound, C15H12Br2N2O2, the molecule adopts an E conformation about the C=N double bond and a transoid conformation about the central N—N bond, with a C(=O)—N—N—C(H) dihedral angle of 169.4 (4)°. In the crystal, molecules are linked by N—H...O hydrogen bonds, leading to C(4) chains. The packing also features slipped π–π stacking interactions, with a centroid–centroid separation of 3.838 (3) Å and a slippage of 1.19 Å.
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spelling doaj.art-a180af15f38d46c299be24d3ad857cd92022-12-22T00:04:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658o1750o175010.1107/S16005368090249212-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazideHongqi LiB. K. SarojiniB. NarayanaH. S. YathirajanWilliam T. A. HarrisonIn the title compound, C15H12Br2N2O2, the molecule adopts an E conformation about the C=N double bond and a transoid conformation about the central N—N bond, with a C(=O)—N—N—C(H) dihedral angle of 169.4 (4)°. In the crystal, molecules are linked by N—H...O hydrogen bonds, leading to C(4) chains. The packing also features slipped π–π stacking interactions, with a centroid–centroid separation of 3.838 (3) Å and a slippage of 1.19 Å.http://scripts.iucr.org/cgi-bin/paper?S1600536809024921
spellingShingle Hongqi Li
B. K. Sarojini
B. Narayana
H. S. Yathirajan
William T. A. Harrison
2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide
Acta Crystallographica Section E
title 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide
title_full 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide
title_fullStr 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide
title_full_unstemmed 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide
title_short 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide
title_sort 2 bromo n amp 8242 z 2 bromobenzylidene 5 methoxybenzohydrazide
url http://scripts.iucr.org/cgi-bin/paper?S1600536809024921
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AT bnarayana 2bromonamp8242z2bromobenzylidene5methoxybenzohydrazide
AT hsyathirajan 2bromonamp8242z2bromobenzylidene5methoxybenzohydrazide
AT williamtaharrison 2bromonamp8242z2bromobenzylidene5methoxybenzohydrazide