2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide
In the title compound, C15H12Br2N2O2, the molecule adopts an E conformation about the C=N double bond and a transoid conformation about the central N—N bond, with a C(=O)—N—N—C(H) dihedral angle of 169.4 (4)°. In the...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
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International Union of Crystallography
2009-08-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809024921 |
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author | Hongqi Li B. K. Sarojini B. Narayana H. S. Yathirajan William T. A. Harrison |
author_facet | Hongqi Li B. K. Sarojini B. Narayana H. S. Yathirajan William T. A. Harrison |
author_sort | Hongqi Li |
collection | DOAJ |
description | In the title compound, C15H12Br2N2O2, the molecule adopts an E conformation about the C=N double bond and a transoid conformation about the central N—N bond, with a C(=O)—N—N—C(H) dihedral angle of 169.4 (4)°. In the crystal, molecules are linked by N—H...O hydrogen bonds, leading to C(4) chains. The packing also features slipped π–π stacking interactions, with a centroid–centroid separation of 3.838 (3) Å and a slippage of 1.19 Å. |
first_indexed | 2024-12-13T01:18:32Z |
format | Article |
id | doaj.art-a180af15f38d46c299be24d3ad857cd9 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-13T01:18:32Z |
publishDate | 2009-08-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-a180af15f38d46c299be24d3ad857cd92022-12-22T00:04:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658o1750o175010.1107/S16005368090249212-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazideHongqi LiB. K. SarojiniB. NarayanaH. S. YathirajanWilliam T. A. HarrisonIn the title compound, C15H12Br2N2O2, the molecule adopts an E conformation about the C=N double bond and a transoid conformation about the central N—N bond, with a C(=O)—N—N—C(H) dihedral angle of 169.4 (4)°. In the crystal, molecules are linked by N—H...O hydrogen bonds, leading to C(4) chains. The packing also features slipped π–π stacking interactions, with a centroid–centroid separation of 3.838 (3) Å and a slippage of 1.19 Å.http://scripts.iucr.org/cgi-bin/paper?S1600536809024921 |
spellingShingle | Hongqi Li B. K. Sarojini B. Narayana H. S. Yathirajan William T. A. Harrison 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide Acta Crystallographica Section E |
title | 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide |
title_full | 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide |
title_fullStr | 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide |
title_full_unstemmed | 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide |
title_short | 2-Bromo-N′-[(Z)-2-bromobenzylidene]-5-methoxybenzohydrazide |
title_sort | 2 bromo n amp 8242 z 2 bromobenzylidene 5 methoxybenzohydrazide |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536809024921 |
work_keys_str_mv | AT hongqili 2bromonamp8242z2bromobenzylidene5methoxybenzohydrazide AT bksarojini 2bromonamp8242z2bromobenzylidene5methoxybenzohydrazide AT bnarayana 2bromonamp8242z2bromobenzylidene5methoxybenzohydrazide AT hsyathirajan 2bromonamp8242z2bromobenzylidene5methoxybenzohydrazide AT williamtaharrison 2bromonamp8242z2bromobenzylidene5methoxybenzohydrazide |