Synthesis and Spectral Characteristics Investigation of the 2D-2D vdWs Heterostructure Materials

Due to the attractive optical and electrical properties, van der Waals (vdWs) heterostructures constructed from the different two-dimensional materials have received widespread attention. Here, MoS<sub>2</sub>/h-BN, MoS<sub>2</sub>/graphene, WS<sub>2</sub>/h-BN, a...

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Main Authors: Tao Han, Hongxia Liu, Shulong Wang, Shupeng Chen, Kun Yang, Zhandong Li
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:International Journal of Molecular Sciences
Subjects:
Online Access:https://www.mdpi.com/1422-0067/22/3/1246
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author Tao Han
Hongxia Liu
Shulong Wang
Shupeng Chen
Kun Yang
Zhandong Li
author_facet Tao Han
Hongxia Liu
Shulong Wang
Shupeng Chen
Kun Yang
Zhandong Li
author_sort Tao Han
collection DOAJ
description Due to the attractive optical and electrical properties, van der Waals (vdWs) heterostructures constructed from the different two-dimensional materials have received widespread attention. Here, MoS<sub>2</sub>/h-BN, MoS<sub>2</sub>/graphene, WS<sub>2</sub>/h-BN, and WS<sub>2</sub>/graphene vdWs heterostructures are successfully prepared by the CVD and wet transfer methods. The distribution, Raman and photoluminescence (PL) spectra of the above prepared heterostructure samples can be respectively observed and tested by optical microscopy and Raman spectrometry, which can be used to study their growth mechanisms and optical properties. Meanwhile, the uniformity and composition distribution of heterostructure films can also be analyzed by the Raman and PL spectra. The internal mechanism of Raman and PL spectral changes can be explained by comparing and analyzing the PL and Raman spectra of the junction and non-junction regions between 2D-2D vdWs heterostructure materials, and the effect of laser power on the optical properties of heterostructure materials can also be analyzed. These heterostructure materials exhibit novel and unique optical characteristics at the stacking or junction, which can provide a reliable experimental basis for the preparation of suitable TMDs heterostructure materials with excellent performance.
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spelling doaj.art-a1a4ac2f662d405caa8a50046138252a2023-12-03T14:55:23ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672021-01-01223124610.3390/ijms22031246Synthesis and Spectral Characteristics Investigation of the 2D-2D vdWs Heterostructure MaterialsTao Han0Hongxia Liu1Shulong Wang2Shupeng Chen3Kun Yang4Zhandong Li5Key Laboratory for Wide-Band Gap Semiconductor Materials and Devices of Education, The School of Microelectronics, Xidian University, Xi’an 710071, ChinaKey Laboratory for Wide-Band Gap Semiconductor Materials and Devices of Education, The School of Microelectronics, Xidian University, Xi’an 710071, ChinaKey Laboratory for Wide-Band Gap Semiconductor Materials and Devices of Education, The School of Microelectronics, Xidian University, Xi’an 710071, ChinaKey Laboratory for Wide-Band Gap Semiconductor Materials and Devices of Education, The School of Microelectronics, Xidian University, Xi’an 710071, ChinaKey Laboratory for Wide-Band Gap Semiconductor Materials and Devices of Education, The School of Microelectronics, Xidian University, Xi’an 710071, ChinaKey Laboratory for Wide-Band Gap Semiconductor Materials and Devices of Education, The School of Microelectronics, Xidian University, Xi’an 710071, ChinaDue to the attractive optical and electrical properties, van der Waals (vdWs) heterostructures constructed from the different two-dimensional materials have received widespread attention. Here, MoS<sub>2</sub>/h-BN, MoS<sub>2</sub>/graphene, WS<sub>2</sub>/h-BN, and WS<sub>2</sub>/graphene vdWs heterostructures are successfully prepared by the CVD and wet transfer methods. The distribution, Raman and photoluminescence (PL) spectra of the above prepared heterostructure samples can be respectively observed and tested by optical microscopy and Raman spectrometry, which can be used to study their growth mechanisms and optical properties. Meanwhile, the uniformity and composition distribution of heterostructure films can also be analyzed by the Raman and PL spectra. The internal mechanism of Raman and PL spectral changes can be explained by comparing and analyzing the PL and Raman spectra of the junction and non-junction regions between 2D-2D vdWs heterostructure materials, and the effect of laser power on the optical properties of heterostructure materials can also be analyzed. These heterostructure materials exhibit novel and unique optical characteristics at the stacking or junction, which can provide a reliable experimental basis for the preparation of suitable TMDs heterostructure materials with excellent performance.https://www.mdpi.com/1422-0067/22/3/1246vdWs heterostructureRaman spectrumPL spectrum
spellingShingle Tao Han
Hongxia Liu
Shulong Wang
Shupeng Chen
Kun Yang
Zhandong Li
Synthesis and Spectral Characteristics Investigation of the 2D-2D vdWs Heterostructure Materials
International Journal of Molecular Sciences
vdWs heterostructure
Raman spectrum
PL spectrum
title Synthesis and Spectral Characteristics Investigation of the 2D-2D vdWs Heterostructure Materials
title_full Synthesis and Spectral Characteristics Investigation of the 2D-2D vdWs Heterostructure Materials
title_fullStr Synthesis and Spectral Characteristics Investigation of the 2D-2D vdWs Heterostructure Materials
title_full_unstemmed Synthesis and Spectral Characteristics Investigation of the 2D-2D vdWs Heterostructure Materials
title_short Synthesis and Spectral Characteristics Investigation of the 2D-2D vdWs Heterostructure Materials
title_sort synthesis and spectral characteristics investigation of the 2d 2d vdws heterostructure materials
topic vdWs heterostructure
Raman spectrum
PL spectrum
url https://www.mdpi.com/1422-0067/22/3/1246
work_keys_str_mv AT taohan synthesisandspectralcharacteristicsinvestigationofthe2d2dvdwsheterostructurematerials
AT hongxialiu synthesisandspectralcharacteristicsinvestigationofthe2d2dvdwsheterostructurematerials
AT shulongwang synthesisandspectralcharacteristicsinvestigationofthe2d2dvdwsheterostructurematerials
AT shupengchen synthesisandspectralcharacteristicsinvestigationofthe2d2dvdwsheterostructurematerials
AT kunyang synthesisandspectralcharacteristicsinvestigationofthe2d2dvdwsheterostructurematerials
AT zhandongli synthesisandspectralcharacteristicsinvestigationofthe2d2dvdwsheterostructurematerials