Mechanisms of Hydride Nucleation, Growth, Reorientation, and Embrittlement in Zirconium: A Review

Zirconium (Zr) hydrides threaten the reliability of fuel assembly and have repeatedly induced failures in cladding tubes and pressure vessels. Thus, they attract a broad range of research interests. For example, delayed hydride cracking induced a severe fracture and failure in a Zircaloy-2 pressure...

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Main Authors: Yu-Jie Jia, Wei-Zhong Han
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/6/2419
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author Yu-Jie Jia
Wei-Zhong Han
author_facet Yu-Jie Jia
Wei-Zhong Han
author_sort Yu-Jie Jia
collection DOAJ
description Zirconium (Zr) hydrides threaten the reliability of fuel assembly and have repeatedly induced failures in cladding tubes and pressure vessels. Thus, they attract a broad range of research interests. For example, delayed hydride cracking induced a severe fracture and failure in a Zircaloy-2 pressure tube in 1983, causing the emergency shutdown of the Pickering nuclear reactor. Hydride has high hardness and very low toughness, and it tends to aggregate toward cooler or tensile regions, which initiates localized hydride precipitation and results in delayed hydride cracking. Notably, hydride reorientation under tensile stress substantially decreases the fracture toughness and increases the ductile-to-brittle transition temperature of Zr alloys, which reduces the safety of the long-term storage of spent nuclear fuel. Therefore, improving our knowledge of Zr hydrides is useful for effectively controlling hydride embrittlement in fuel assembly. The aim of this review is to reorganize the mechanisms of hydride nucleation and growth behaviors, hydride reorientation under external stress, and hydride-induced embrittlement. We revisit important examples of progress of research in this field and emphasize the key future aspects of research on Zr hydrides.
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spelling doaj.art-a1a68edd059b4d9ab606b08cdfe9dc0b2023-11-17T12:21:59ZengMDPI AGMaterials1996-19442023-03-01166241910.3390/ma16062419Mechanisms of Hydride Nucleation, Growth, Reorientation, and Embrittlement in Zirconium: A ReviewYu-Jie Jia0Wei-Zhong Han1Center for Advancing Materials Performance from the Nanoscale, State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an 710049, ChinaCenter for Advancing Materials Performance from the Nanoscale, State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an 710049, ChinaZirconium (Zr) hydrides threaten the reliability of fuel assembly and have repeatedly induced failures in cladding tubes and pressure vessels. Thus, they attract a broad range of research interests. For example, delayed hydride cracking induced a severe fracture and failure in a Zircaloy-2 pressure tube in 1983, causing the emergency shutdown of the Pickering nuclear reactor. Hydride has high hardness and very low toughness, and it tends to aggregate toward cooler or tensile regions, which initiates localized hydride precipitation and results in delayed hydride cracking. Notably, hydride reorientation under tensile stress substantially decreases the fracture toughness and increases the ductile-to-brittle transition temperature of Zr alloys, which reduces the safety of the long-term storage of spent nuclear fuel. Therefore, improving our knowledge of Zr hydrides is useful for effectively controlling hydride embrittlement in fuel assembly. The aim of this review is to reorganize the mechanisms of hydride nucleation and growth behaviors, hydride reorientation under external stress, and hydride-induced embrittlement. We revisit important examples of progress of research in this field and emphasize the key future aspects of research on Zr hydrides.https://www.mdpi.com/1996-1944/16/6/2419zirconium hydridenucleationgrowthreorientationembrittlement
spellingShingle Yu-Jie Jia
Wei-Zhong Han
Mechanisms of Hydride Nucleation, Growth, Reorientation, and Embrittlement in Zirconium: A Review
Materials
zirconium hydride
nucleation
growth
reorientation
embrittlement
title Mechanisms of Hydride Nucleation, Growth, Reorientation, and Embrittlement in Zirconium: A Review
title_full Mechanisms of Hydride Nucleation, Growth, Reorientation, and Embrittlement in Zirconium: A Review
title_fullStr Mechanisms of Hydride Nucleation, Growth, Reorientation, and Embrittlement in Zirconium: A Review
title_full_unstemmed Mechanisms of Hydride Nucleation, Growth, Reorientation, and Embrittlement in Zirconium: A Review
title_short Mechanisms of Hydride Nucleation, Growth, Reorientation, and Embrittlement in Zirconium: A Review
title_sort mechanisms of hydride nucleation growth reorientation and embrittlement in zirconium a review
topic zirconium hydride
nucleation
growth
reorientation
embrittlement
url https://www.mdpi.com/1996-1944/16/6/2419
work_keys_str_mv AT yujiejia mechanismsofhydridenucleationgrowthreorientationandembrittlementinzirconiumareview
AT weizhonghan mechanismsofhydridenucleationgrowthreorientationandembrittlementinzirconiumareview