Influence of Solvothermal Temperatures and Times on Crystallinity and Morphology of MOF-5
MOF-5 (metal-organic frameworks-5) have been synthesized using solvothermal method in which reaction mixtures of zinc nitrate hexahydrate and 1,4-benzenedicarboxylic acid (BDC) in dimethylformamide (DMF) were heated at various heating temperatures and times in order to observe the influence of heati...
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| Format: | Article |
| Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2015-07-01
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| Series: | Indonesian Journal of Chemistry |
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| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/21202 |
| _version_ | 1818743265949646848 |
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| author | Tri Ana Mulyati Ratna Ediati Afifah Rosyidah |
| author_facet | Tri Ana Mulyati Ratna Ediati Afifah Rosyidah |
| author_sort | Tri Ana Mulyati |
| collection | DOAJ |
| description | MOF-5 (metal-organic frameworks-5) have been synthesized using solvothermal method in which reaction mixtures of zinc nitrate hexahydrate and 1,4-benzenedicarboxylic acid (BDC) in dimethylformamide (DMF) were heated at various heating temperatures and times in order to observe the influence of heating temperature and time on crystallinity and morphology of the obtained MOF-5. The heating temperatures used were 105, 120 and 140 °C, respectively with heating times of 12–144 h. Determination of the best reaction conditionswas based on the observation of phase purity and crystal morphology of MOF-5 using XRD and SEM. The characterization results showed that MOF-5 crystals with a higher crystallinity were obtained when the reaction mixtures were heated at 105 °C for 144 h, 120 °C for 24 h or 140 °C for 12 h. The maximum weight of MOF-5 crystal was generated from reaction mixture heated at 120 °C for 72 h. |
| first_indexed | 2024-12-18T02:25:40Z |
| format | Article |
| id | doaj.art-a1c3d6a519d541a48cb51d4c9db58974 |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-12-18T02:25:40Z |
| publishDate | 2015-07-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-a1c3d6a519d541a48cb51d4c9db589742022-12-21T21:24:04ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782015-07-0115210110710.22146/ijc.2120214300Influence of Solvothermal Temperatures and Times on Crystallinity and Morphology of MOF-5Tri Ana Mulyati0Ratna Ediati1Afifah Rosyidah2Department of Chemistry, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo Surabaya 60111Department of Chemistry, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo Surabaya 60111Department of Chemistry, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo Surabaya 60111MOF-5 (metal-organic frameworks-5) have been synthesized using solvothermal method in which reaction mixtures of zinc nitrate hexahydrate and 1,4-benzenedicarboxylic acid (BDC) in dimethylformamide (DMF) were heated at various heating temperatures and times in order to observe the influence of heating temperature and time on crystallinity and morphology of the obtained MOF-5. The heating temperatures used were 105, 120 and 140 °C, respectively with heating times of 12–144 h. Determination of the best reaction conditionswas based on the observation of phase purity and crystal morphology of MOF-5 using XRD and SEM. The characterization results showed that MOF-5 crystals with a higher crystallinity were obtained when the reaction mixtures were heated at 105 °C for 144 h, 120 °C for 24 h or 140 °C for 12 h. The maximum weight of MOF-5 crystal was generated from reaction mixture heated at 120 °C for 72 h.https://jurnal.ugm.ac.id/ijc/article/view/21202MOF-5solvothermalsynthesiscrystallinitymorphology |
| spellingShingle | Tri Ana Mulyati Ratna Ediati Afifah Rosyidah Influence of Solvothermal Temperatures and Times on Crystallinity and Morphology of MOF-5 Indonesian Journal of Chemistry MOF-5 solvothermal synthesis crystallinity morphology |
| title | Influence of Solvothermal Temperatures and Times on Crystallinity and Morphology of MOF-5 |
| title_full | Influence of Solvothermal Temperatures and Times on Crystallinity and Morphology of MOF-5 |
| title_fullStr | Influence of Solvothermal Temperatures and Times on Crystallinity and Morphology of MOF-5 |
| title_full_unstemmed | Influence of Solvothermal Temperatures and Times on Crystallinity and Morphology of MOF-5 |
| title_short | Influence of Solvothermal Temperatures and Times on Crystallinity and Morphology of MOF-5 |
| title_sort | influence of solvothermal temperatures and times on crystallinity and morphology of mof 5 |
| topic | MOF-5 solvothermal synthesis crystallinity morphology |
| url | https://jurnal.ugm.ac.id/ijc/article/view/21202 |
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