Syn-selective silicon Mukaiyama-type aldol reactions of (pentafluoro-λ6-sulfanyl)acetic acid esters with aldehydes

Syn-selective silicon Mukaiyama-type aldol reactions of (pentafluoro-λ6-sulfanyl)acetic acid esters with aldehydes

Aldol reactions belong to the most frequently used C–C bond forming transformations utilized particularly for the construction of complex structures. The selectivity of these reactions depends on the geometry of the intermediate enolates. Here, we have reacted octyl pentafluoro-λ6-sulfanylacetate wi...

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Bibliographic Details
Main Authors: Anna-Lena Dreier, Andrej V. Matsnev, Joseph S. Thrasher, Günter Haufe
Format: Article
Language:English
Published: Beilstein-Institut 2018-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
aldol reaction
ester enolate
fluorine
SF5 compounds
stereochemistry
Online Access:https://doi.org/10.3762/bjoc.14.25

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