Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization
Controlling multicomponent systems is difficult due to convoluted behavior, pathway complexity, and coupled equilibria. Here the authors showed modulation of aggregate morphology in a zinc porphyrin-based supramolecular system via judicious capping with a manganese porphyrin monomer, in which the mo...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-01-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-021-27831-2 |
| _version_ | 1828138426614939648 |
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| author | Elisabeth Weyandt Luigi Leanza Riccardo Capelli Giovanni M. Pavan Ghislaine Vantomme E. W. Meijer |
| author_facet | Elisabeth Weyandt Luigi Leanza Riccardo Capelli Giovanni M. Pavan Ghislaine Vantomme E. W. Meijer |
| author_sort | Elisabeth Weyandt |
| collection | DOAJ |
| description | Controlling multicomponent systems is difficult due to convoluted behavior, pathway complexity, and coupled equilibria. Here the authors showed modulation of aggregate morphology in a zinc porphyrin-based supramolecular system via judicious capping with a manganese porphyrin monomer, in which the monomer’s chirality can influence the supramolecular behavior. |
| first_indexed | 2024-04-11T18:36:38Z |
| format | Article |
| id | doaj.art-a1f7b7e18dd74df49fc6524a4a230b13 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-11T18:36:38Z |
| publishDate | 2022-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-a1f7b7e18dd74df49fc6524a4a230b132022-12-22T04:09:15ZengNature PortfolioNature Communications2041-17232022-01-011311910.1038/s41467-021-27831-2Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerizationElisabeth Weyandt0Luigi Leanza1Riccardo Capelli2Giovanni M. Pavan3Ghislaine Vantomme4E. W. Meijer5Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of TechnologyDepartment of Applied Science and Technology, Politecnico di TorinoDepartment of Applied Science and Technology, Politecnico di TorinoDepartment of Applied Science and Technology, Politecnico di TorinoLaboratory of Macromolecular and Organic Chemistry, Eindhoven University of TechnologyLaboratory of Macromolecular and Organic Chemistry, Eindhoven University of TechnologyControlling multicomponent systems is difficult due to convoluted behavior, pathway complexity, and coupled equilibria. Here the authors showed modulation of aggregate morphology in a zinc porphyrin-based supramolecular system via judicious capping with a manganese porphyrin monomer, in which the monomer’s chirality can influence the supramolecular behavior.https://doi.org/10.1038/s41467-021-27831-2 |
| spellingShingle | Elisabeth Weyandt Luigi Leanza Riccardo Capelli Giovanni M. Pavan Ghislaine Vantomme E. W. Meijer Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization Nature Communications |
| title | Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization |
| title_full | Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization |
| title_fullStr | Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization |
| title_full_unstemmed | Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization |
| title_short | Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization |
| title_sort | controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution induced supramolecular polymerization |
| url | https://doi.org/10.1038/s41467-021-27831-2 |
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