Supramolecular Cluster Catalysis: A Case Study of Benzene Hydrogenation
The hydrogenation of benzene to give cyclohexane, catalysed under biphasic conditions by the water-soluble trinuclear arene ruthenium cluster cations [H3Ru3(C6H6)(C6Me6)2(O)]+ (1), [H3Ru3(C6H5Me)(C6Me6)2(O)]+ (2), [H3Ru3(1,4-MeC6H4Pri)(C6Me6)2(O)]+ (3), [H3Ru3(1,2,4,5-C6H2Me4)3(O)]+ (4), [...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | deu |
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Swiss Chemical Society
2003-10-01
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| Series: | CHIMIA |
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| Online Access: | https://chimia.ch/chimia/article/view/3748 |
| _version_ | 1811320264721432576 |
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| author | Bruno Therrien Ludovic Vieille-Petit Mathieu Tschan Vladimir B. Romakh Georg Süss-Fink |
| author_facet | Bruno Therrien Ludovic Vieille-Petit Mathieu Tschan Vladimir B. Romakh Georg Süss-Fink |
| author_sort | Bruno Therrien |
| collection | DOAJ |
| description |
The hydrogenation of benzene to give cyclohexane, catalysed under biphasic conditions by the water-soluble trinuclear arene ruthenium cluster cations [H3Ru3(C6H6)(C6Me6)2(O)]+ (1), [H3Ru3(C6H5Me)(C6Me6)2(O)]+
(2), [H3Ru3(1,4-MeC6H4Pri)(C6Me6)2(O)]+ (3), [H3Ru3(1,2,4,5-C6H2Me4)3(O)]+ (4), [H3Ru3{C6H5(CH2)2OH}(C6Me6)2(O)]+
(5), and [H3Ru3{C6H5(CH2)3OH}(C6Me6)2(O)]+ (6), is believed to occur within the hydrophobic pocket spanned by the three arene ligands of the trinuclear cluster, thus
forming a supramolecular catalyst–substrate host–guest complex. This paper is a short overview of our research efforts directed to a new catalytic concept for which we coined the term 'supramolecular cluster catalysis'.
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| first_indexed | 2024-04-13T12:56:52Z |
| format | Article |
| id | doaj.art-a2179869bca74dfe8367ee9aad5bab17 |
| institution | Directory Open Access Journal |
| issn | 0009-4293 2673-2424 |
| language | deu |
| last_indexed | 2024-04-13T12:56:52Z |
| publishDate | 2003-10-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj.art-a2179869bca74dfe8367ee9aad5bab172022-12-22T02:46:02ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242003-10-01571010.2533/000942903777678768Supramolecular Cluster Catalysis: A Case Study of Benzene HydrogenationBruno TherrienLudovic Vieille-PetitMathieu TschanVladimir B. RomakhGeorg Süss-Fink The hydrogenation of benzene to give cyclohexane, catalysed under biphasic conditions by the water-soluble trinuclear arene ruthenium cluster cations [H3Ru3(C6H6)(C6Me6)2(O)]+ (1), [H3Ru3(C6H5Me)(C6Me6)2(O)]+ (2), [H3Ru3(1,4-MeC6H4Pri)(C6Me6)2(O)]+ (3), [H3Ru3(1,2,4,5-C6H2Me4)3(O)]+ (4), [H3Ru3{C6H5(CH2)2OH}(C6Me6)2(O)]+ (5), and [H3Ru3{C6H5(CH2)3OH}(C6Me6)2(O)]+ (6), is believed to occur within the hydrophobic pocket spanned by the three arene ligands of the trinuclear cluster, thus forming a supramolecular catalyst–substrate host–guest complex. This paper is a short overview of our research efforts directed to a new catalytic concept for which we coined the term 'supramolecular cluster catalysis'. https://chimia.ch/chimia/article/view/3748Arene hydrogenationBiphasic catalysisCluster catalysisHost-guest complexesHydrophobic forcesIntermolecular interactions |
| spellingShingle | Bruno Therrien Ludovic Vieille-Petit Mathieu Tschan Vladimir B. Romakh Georg Süss-Fink Supramolecular Cluster Catalysis: A Case Study of Benzene Hydrogenation CHIMIA Arene hydrogenation Biphasic catalysis Cluster catalysis Host-guest complexes Hydrophobic forces Intermolecular interactions |
| title | Supramolecular Cluster Catalysis: A Case Study of Benzene Hydrogenation |
| title_full | Supramolecular Cluster Catalysis: A Case Study of Benzene Hydrogenation |
| title_fullStr | Supramolecular Cluster Catalysis: A Case Study of Benzene Hydrogenation |
| title_full_unstemmed | Supramolecular Cluster Catalysis: A Case Study of Benzene Hydrogenation |
| title_short | Supramolecular Cluster Catalysis: A Case Study of Benzene Hydrogenation |
| title_sort | supramolecular cluster catalysis a case study of benzene hydrogenation |
| topic | Arene hydrogenation Biphasic catalysis Cluster catalysis Host-guest complexes Hydrophobic forces Intermolecular interactions |
| url | https://chimia.ch/chimia/article/view/3748 |
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