Influencing factors for the migration of zinc ions in metal oxide powders
Metal oxides can be doped by various metal ions to tune the properties. While the migration of metal ions especially extrinsic metal ions in metal oxides still needs to be clarified in order to adjust the composition and the structure of metal oxides properly. Here, 14 kinds of metal oxide powders w...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-05-01
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| Series: | Journal of Materials Research and Technology |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2238785423005690 |
| _version_ | 1797798816791920640 |
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| author | Dongzhu Lu Quantong Jiang Yishan Jiang Jiawei Li Qichao Zhang Yanliang Huang Baorong Hou |
| author_facet | Dongzhu Lu Quantong Jiang Yishan Jiang Jiawei Li Qichao Zhang Yanliang Huang Baorong Hou |
| author_sort | Dongzhu Lu |
| collection | DOAJ |
| description | Metal oxides can be doped by various metal ions to tune the properties. While the migration of metal ions especially extrinsic metal ions in metal oxides still needs to be clarified in order to adjust the composition and the structure of metal oxides properly. Here, 14 kinds of metal oxide powders were utilized to investigate the key factors of Zn ion migration in metal oxide powders experimentally. Results show that chemical reactions and/or phase transitions in metal oxides can hinder the migration of Zn ions in metal oxide powders. Compared with unstable metal oxides, it is easier for Zn ions to pass through stable metal oxides which maintain the same component phases at elevated temperatures. Transition from unstable metal oxide medium to stable metal oxide medium will make the transport of Zn ions in the medium from impossible to possible. These findings are helpful for selecting proper metal oxides in related industries such as battery designing, gas sensor development and so on. |
| first_indexed | 2024-03-13T04:10:34Z |
| format | Article |
| id | doaj.art-a25e6ce501cf42f5893b1c86fef78e36 |
| institution | Directory Open Access Journal |
| issn | 2238-7854 |
| language | English |
| last_indexed | 2024-03-13T04:10:34Z |
| publishDate | 2023-05-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Materials Research and Technology |
| spelling | doaj.art-a25e6ce501cf42f5893b1c86fef78e362023-06-21T06:55:53ZengElsevierJournal of Materials Research and Technology2238-78542023-05-012416381652Influencing factors for the migration of zinc ions in metal oxide powdersDongzhu Lu0Quantong Jiang1Yishan Jiang2Jiawei Li3Qichao Zhang4Yanliang Huang5Baorong Hou6CAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China; Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao 266237, China; Guangxi Key Laboratory of Marine Environmental Science, Guangxi Academy of Sciences, Nanning 530007, China; Center for Ocean Mega-Science, Chinese Academy of Sciences, Qingdao 266071, China; School of Materials Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China; Nantong Zhongke Marine Science and Technology Research and Development Center, Nantong 226006, China; Corresponding author.CAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China; Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao 266237, China; Center for Ocean Mega-Science, Chinese Academy of Sciences, Qingdao 266071, ChinaNavy Submarine Academy, Qingdao 260199, ChinaCAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China; Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao 266237, China; School of Materials Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, ChinaCAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China; Navy Submarine Academy, Qingdao 260199, China; Corresponding author.CAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China; Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao 266237, China; School of Materials Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, ChinaCAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China; Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao 266237, China; School of Materials Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, ChinaMetal oxides can be doped by various metal ions to tune the properties. While the migration of metal ions especially extrinsic metal ions in metal oxides still needs to be clarified in order to adjust the composition and the structure of metal oxides properly. Here, 14 kinds of metal oxide powders were utilized to investigate the key factors of Zn ion migration in metal oxide powders experimentally. Results show that chemical reactions and/or phase transitions in metal oxides can hinder the migration of Zn ions in metal oxide powders. Compared with unstable metal oxides, it is easier for Zn ions to pass through stable metal oxides which maintain the same component phases at elevated temperatures. Transition from unstable metal oxide medium to stable metal oxide medium will make the transport of Zn ions in the medium from impossible to possible. These findings are helpful for selecting proper metal oxides in related industries such as battery designing, gas sensor development and so on.http://www.sciencedirect.com/science/article/pii/S2238785423005690Metal oxideMetal ionReactionPhase transitionMigrationTransport |
| spellingShingle | Dongzhu Lu Quantong Jiang Yishan Jiang Jiawei Li Qichao Zhang Yanliang Huang Baorong Hou Influencing factors for the migration of zinc ions in metal oxide powders Journal of Materials Research and Technology Metal oxide Metal ion Reaction Phase transition Migration Transport |
| title | Influencing factors for the migration of zinc ions in metal oxide powders |
| title_full | Influencing factors for the migration of zinc ions in metal oxide powders |
| title_fullStr | Influencing factors for the migration of zinc ions in metal oxide powders |
| title_full_unstemmed | Influencing factors for the migration of zinc ions in metal oxide powders |
| title_short | Influencing factors for the migration of zinc ions in metal oxide powders |
| title_sort | influencing factors for the migration of zinc ions in metal oxide powders |
| topic | Metal oxide Metal ion Reaction Phase transition Migration Transport |
| url | http://www.sciencedirect.com/science/article/pii/S2238785423005690 |
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