Structure, morphology, thermal and conductivity properties of gel electrolyte system based on polyvinyl chloride and LiClO4

The dynamics of atoms and molecules in gel electrolyte based on polyvinyl chloride and a solution of LiClO4 in propylene carbonate was studied by the method of quasielastic scattering of slow neutrons. The coefficients of self-diffusion of atoms and molecules are determined and a possible variant of...

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Main Authors: V. V. Klepko, V. I. Slisenko, K. M. Sukhyy, S. D. Nesin, V. L. Kovalenko, Y. O. Serhiienko, I. V. Sukha
Format: Article
Language:English
Published: Institute for Nuclear Research, National Academy of Sciences of Ukraine 2018-03-01
Series:Âderna Fìzika ta Energetika
Subjects:
Online Access:http://jnpae.kinr.kiev.ua/19.1/html/19.1.0043.html
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author V. V. Klepko
V. I. Slisenko
K. M. Sukhyy
S. D. Nesin
V. L. Kovalenko
Y. O. Serhiienko
I. V. Sukha
author_facet V. V. Klepko
V. I. Slisenko
K. M. Sukhyy
S. D. Nesin
V. L. Kovalenko
Y. O. Serhiienko
I. V. Sukha
author_sort V. V. Klepko
collection DOAJ
description The dynamics of atoms and molecules in gel electrolyte based on polyvinyl chloride and a solution of LiClO4 in propylene carbonate was studied by the method of quasielastic scattering of slow neutrons. The coefficients of self-diffusion of atoms and molecules are determined and a possible variant of the mechanism of charge transport in this system is proposed.
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spelling doaj.art-a26c4c0d4f42431f88a5669e247f54262022-12-21T19:07:31ZengInstitute for Nuclear Research, National Academy of Sciences of UkraineÂderna Fìzika ta Energetika1818-331X2074-05652018-03-011914347https://doi.org/10.15407/jnpae2018.01.043Structure, morphology, thermal and conductivity properties of gel electrolyte system based on polyvinyl chloride and LiClO4V. V. Klepko0V. I. Slisenko1K. M. Sukhyy2S. D. Nesin3V. L. Kovalenko4Y. O. Serhiienko5I. V. Sukha6Institute for Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kyiv, UkraineInstitute for Nuclear Research, National Academy of Sciences of Ukraine, Kyiv, UkraineUkrainian State University of Chemical Technology, Dnipro, UkraineInstitute for Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kyiv, UkraineUkrainian State University of Chemical Technology, Dnipro, Ukraine; Federal State Educational Institution of Higher Education "Vyatka State University", Kirov, RussiaUkrainian State University of Chemical Technology, Dnipro, UkraineUkrainian State University of Chemical Technology, Dnipro, UkraineThe dynamics of atoms and molecules in gel electrolyte based on polyvinyl chloride and a solution of LiClO4 in propylene carbonate was studied by the method of quasielastic scattering of slow neutrons. The coefficients of self-diffusion of atoms and molecules are determined and a possible variant of the mechanism of charge transport in this system is proposed.http://jnpae.kinr.kiev.ua/19.1/html/19.1.0043.htmlsolid polymer electrolytespolyvinyl chlorideX-ray scatteringcalorimetric scatteringquasi-elastic neutron scattering.
spellingShingle V. V. Klepko
V. I. Slisenko
K. M. Sukhyy
S. D. Nesin
V. L. Kovalenko
Y. O. Serhiienko
I. V. Sukha
Structure, morphology, thermal and conductivity properties of gel electrolyte system based on polyvinyl chloride and LiClO4
Âderna Fìzika ta Energetika
solid polymer electrolytes
polyvinyl chloride
X-ray scattering
calorimetric scattering
quasi-elastic neutron scattering.
title Structure, morphology, thermal and conductivity properties of gel electrolyte system based on polyvinyl chloride and LiClO4
title_full Structure, morphology, thermal and conductivity properties of gel electrolyte system based on polyvinyl chloride and LiClO4
title_fullStr Structure, morphology, thermal and conductivity properties of gel electrolyte system based on polyvinyl chloride and LiClO4
title_full_unstemmed Structure, morphology, thermal and conductivity properties of gel electrolyte system based on polyvinyl chloride and LiClO4
title_short Structure, morphology, thermal and conductivity properties of gel electrolyte system based on polyvinyl chloride and LiClO4
title_sort structure morphology thermal and conductivity properties of gel electrolyte system based on polyvinyl chloride and liclo4
topic solid polymer electrolytes
polyvinyl chloride
X-ray scattering
calorimetric scattering
quasi-elastic neutron scattering.
url http://jnpae.kinr.kiev.ua/19.1/html/19.1.0043.html
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