Electrolyte and anode‐electrolyte interphase in solid‐state lithium metal polymer batteries: A perspective
Abstract The interest for solid‐state lithium metal (Li°) batteries (SSLMBs) has been growing exponentially in recent years in view of their higher energy density and eliminated safety concerns. Solid polymer electrolytes (SPEs) are soft ionic conductors which can be easily processed into thin films...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2021-03-01
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| Series: | SusMat |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/sus2.6 |
| _version_ | 1819156463940009984 |
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| author | Heng Zhang Yuhui Chen Chunmei Li Michel Armand |
| author_facet | Heng Zhang Yuhui Chen Chunmei Li Michel Armand |
| author_sort | Heng Zhang |
| collection | DOAJ |
| description | Abstract The interest for solid‐state lithium metal (Li°) batteries (SSLMBs) has been growing exponentially in recent years in view of their higher energy density and eliminated safety concerns. Solid polymer electrolytes (SPEs) are soft ionic conductors which can be easily processed into thin films at industrial level; these unique features confer solid‐state Li° polymer batteries (SSLMPBs, i.e., SSLMBs utilizing SPEs as electrolytes) distinct advantages compared to SSLMBs containing other electrolytes. In this article, we briefly review recent progresses and achievements in SSLMPBs including the improvement of ionic conductivity of SPEs and their interfacial stability with Li° anode. Moreover, we outline several advanced in‐situ and ex‐situ characterizing techniques which could assist in‐depth understanding of the anode‐electrolyte interphases in SSLMPBs. This article is hoped not only to update the state‐of‐the‐art in the research on SSLMPBs but also to bring intriguing insights that could improve the fundamental properties (e.g., transport, dendrite formation, and growth, etc.) and electrochemical performance of SSLMPBs. |
| first_indexed | 2024-12-22T15:53:17Z |
| format | Article |
| id | doaj.art-a26efc78b5814e56827964ea82d2fb1f |
| institution | Directory Open Access Journal |
| issn | 2692-4552 |
| language | English |
| last_indexed | 2024-12-22T15:53:17Z |
| publishDate | 2021-03-01 |
| publisher | Wiley |
| record_format | Article |
| series | SusMat |
| spelling | doaj.art-a26efc78b5814e56827964ea82d2fb1f2022-12-21T18:20:51ZengWileySusMat2692-45522021-03-0111243710.1002/sus2.6Electrolyte and anode‐electrolyte interphase in solid‐state lithium metal polymer batteries: A perspectiveHeng Zhang0Yuhui Chen1Chunmei Li2Michel Armand3Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) School of Chemistry and Chemical Engineering Huazhong University of Science and Technology Wuhan P. R. ChinaState Key Laboratory of Materials‐Oriented Chemical Engineering School of Energy Nanjing Tech University Nanjing Jiangsu P. R. ChinaCentre for Cooperative Research on Alternative Energies (CIC energiGUNE) Basque Research and Technology Alliance (BRTA) Gipuzkoa SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE) Basque Research and Technology Alliance (BRTA) Gipuzkoa SpainAbstract The interest for solid‐state lithium metal (Li°) batteries (SSLMBs) has been growing exponentially in recent years in view of their higher energy density and eliminated safety concerns. Solid polymer electrolytes (SPEs) are soft ionic conductors which can be easily processed into thin films at industrial level; these unique features confer solid‐state Li° polymer batteries (SSLMPBs, i.e., SSLMBs utilizing SPEs as electrolytes) distinct advantages compared to SSLMBs containing other electrolytes. In this article, we briefly review recent progresses and achievements in SSLMPBs including the improvement of ionic conductivity of SPEs and their interfacial stability with Li° anode. Moreover, we outline several advanced in‐situ and ex‐situ characterizing techniques which could assist in‐depth understanding of the anode‐electrolyte interphases in SSLMPBs. This article is hoped not only to update the state‐of‐the‐art in the research on SSLMPBs but also to bring intriguing insights that could improve the fundamental properties (e.g., transport, dendrite formation, and growth, etc.) and electrochemical performance of SSLMPBs.https://doi.org/10.1002/sus2.6anode‐electrolyte interphasesolid polymer electrolytessolid‐state batteriessolid‐state lithium metal polymer batteries |
| spellingShingle | Heng Zhang Yuhui Chen Chunmei Li Michel Armand Electrolyte and anode‐electrolyte interphase in solid‐state lithium metal polymer batteries: A perspective SusMat anode‐electrolyte interphase solid polymer electrolytes solid‐state batteries solid‐state lithium metal polymer batteries |
| title | Electrolyte and anode‐electrolyte interphase in solid‐state lithium metal polymer batteries: A perspective |
| title_full | Electrolyte and anode‐electrolyte interphase in solid‐state lithium metal polymer batteries: A perspective |
| title_fullStr | Electrolyte and anode‐electrolyte interphase in solid‐state lithium metal polymer batteries: A perspective |
| title_full_unstemmed | Electrolyte and anode‐electrolyte interphase in solid‐state lithium metal polymer batteries: A perspective |
| title_short | Electrolyte and anode‐electrolyte interphase in solid‐state lithium metal polymer batteries: A perspective |
| title_sort | electrolyte and anode electrolyte interphase in solid state lithium metal polymer batteries a perspective |
| topic | anode‐electrolyte interphase solid polymer electrolytes solid‐state batteries solid‐state lithium metal polymer batteries |
| url | https://doi.org/10.1002/sus2.6 |
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