Poly[[tetra-μ3-acetato-hexa-μ2-acetatodiaqua-μ2-oxalato-tetralanthanum(III)] dihydrate]
The title compound, {[La4(CH3CO2)10(C2O4)(H2O)2]·2H2O}n, exhibits a two-dimensional layered structure with the oxalate and acetate ligands acting as bridges. The asymmetric unit contains two crystallographically independent lanthanum(III) ions, half of an oxalate ligand, five acetate li...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811038037 |
| _version_ | 1798031617057357824 |
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| author | Yun-Xiao Liang Qun Zhang Shao-Min Lan Wen-Jing Di |
| author_facet | Yun-Xiao Liang Qun Zhang Shao-Min Lan Wen-Jing Di |
| author_sort | Yun-Xiao Liang |
| collection | DOAJ |
| description | The title compound, {[La4(CH3CO2)10(C2O4)(H2O)2]·2H2O}n, exhibits a two-dimensional layered structure with the oxalate and acetate ligands acting as bridges. The asymmetric unit contains two crystallographically independent lanthanum(III) ions, half of an oxalate ligand, five acetate ligands, one coordinated water molecule and one uncoordinated water molecule. The coordination numbers of the two La ions are 9 and 10. Adjacent layers of the structure, which extend parallel to (100), are linked by O–H...O hydrogen bonds and are also held together by van der Waals interactions between the CH3 groups of the acetate anions. |
| first_indexed | 2024-04-11T19:59:19Z |
| format | Article |
| id | doaj.art-a2750e105b5f495f9b4663e9f21ef9f8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:59:19Z |
| publishDate | 2011-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a2750e105b5f495f9b4663e9f21ef9f82022-12-22T04:05:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1436m143710.1107/S1600536811038037Poly[[tetra-μ3-acetato-hexa-μ2-acetatodiaqua-μ2-oxalato-tetralanthanum(III)] dihydrate]Yun-Xiao LiangQun ZhangShao-Min LanWen-Jing DiThe title compound, {[La4(CH3CO2)10(C2O4)(H2O)2]·2H2O}n, exhibits a two-dimensional layered structure with the oxalate and acetate ligands acting as bridges. The asymmetric unit contains two crystallographically independent lanthanum(III) ions, half of an oxalate ligand, five acetate ligands, one coordinated water molecule and one uncoordinated water molecule. The coordination numbers of the two La ions are 9 and 10. Adjacent layers of the structure, which extend parallel to (100), are linked by O–H...O hydrogen bonds and are also held together by van der Waals interactions between the CH3 groups of the acetate anions.http://scripts.iucr.org/cgi-bin/paper?S1600536811038037 |
| spellingShingle | Yun-Xiao Liang Qun Zhang Shao-Min Lan Wen-Jing Di Poly[[tetra-μ3-acetato-hexa-μ2-acetatodiaqua-μ2-oxalato-tetralanthanum(III)] dihydrate] Acta Crystallographica Section E |
| title | Poly[[tetra-μ3-acetato-hexa-μ2-acetatodiaqua-μ2-oxalato-tetralanthanum(III)] dihydrate] |
| title_full | Poly[[tetra-μ3-acetato-hexa-μ2-acetatodiaqua-μ2-oxalato-tetralanthanum(III)] dihydrate] |
| title_fullStr | Poly[[tetra-μ3-acetato-hexa-μ2-acetatodiaqua-μ2-oxalato-tetralanthanum(III)] dihydrate] |
| title_full_unstemmed | Poly[[tetra-μ3-acetato-hexa-μ2-acetatodiaqua-μ2-oxalato-tetralanthanum(III)] dihydrate] |
| title_short | Poly[[tetra-μ3-acetato-hexa-μ2-acetatodiaqua-μ2-oxalato-tetralanthanum(III)] dihydrate] |
| title_sort | poly tetra amp 956 3 acetato hexa amp 956 2 acetatodiaqua amp 956 2 oxalato tetralanthanum iii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811038037 |
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