High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate

Layered silicates, as bitumen modifiers, have received increasing attention. The main objective of this study was to evaluate the influence of layered silicates on bitumen properties. For this study, montmorillonite (MMT), rectorite (REC), organic montmorillonite (OMMT), and organic rectorite (OREC)...

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Main Authors: Meng Jia, Zengping Zhang, Long Wei, Jiange Li, Dongdong Yuan, Xingjiao Wu, Zhiyong Mao
Format: Article
Language:English
Published: MDPI AG 2019-08-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/9/17/3563
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author Meng Jia
Zengping Zhang
Long Wei
Jiange Li
Dongdong Yuan
Xingjiao Wu
Zhiyong Mao
author_facet Meng Jia
Zengping Zhang
Long Wei
Jiange Li
Dongdong Yuan
Xingjiao Wu
Zhiyong Mao
author_sort Meng Jia
collection DOAJ
description Layered silicates, as bitumen modifiers, have received increasing attention. The main objective of this study was to evaluate the influence of layered silicates on bitumen properties. For this study, montmorillonite (MMT), rectorite (REC), organic montmorillonite (OMMT), and organic rectorite (OREC) were selected. The layered structure type of layered silicates was characterized by SEM (scanning electron microscope) and XRD (X-ray diffraction diffractometer). Tests for determining high-temperature properties included viscosity, DSR (dynamic shear rheometer), and TG (thermogravimetry) tests, and studies for determining the low-temperature properties were conducted by BBR (bending beam rheometer) and DSC (differential scanning calorimetry) tests. Our results show that MMT, REC, OMMT, and OREC were all intercalated structures. OREC had the largest <i>d<sub>001</sub></i> interlayer space, followed by REC, OMMT, and MMT. OREC improved the high-temperature property of virgin bitumen more effectively than OMMT. Meanwhile, REC-modified bitumen exhibited a high-temperature property similar to OMMT-modified bitumen. When compared with REC and OREC, MMT and OMMT were less efficient in reducing the low-temperature properties of virgin bitumen, and OMMT was the least efficient. Therefore, it can be concluded that the nature of pristine layered silicates has a great impact on the high- and low-temperature properties of bitumen. Moreover, organic treatment can simultaneously improve the high- and low-temperature properties of layered silicate-modified bitumens.
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spelling doaj.art-a28bcb48a1d04f998f88007630751df72022-12-21T19:43:38ZengMDPI AGApplied Sciences2076-34172019-08-01917356310.3390/app9173563app9173563High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered SilicateMeng Jia0Zengping Zhang1Long Wei2Jiange Li3Dongdong Yuan4Xingjiao Wu5Zhiyong Mao6Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an University, Xi’an 710064, Shanxi, ChinaKey Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an University, Xi’an 710064, Shanxi, ChinaZhengzhou Communications Planning Survey &amp; Design Institute, Zhengzhou 450000, Henan, ChinaKey Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an University, Xi’an 710064, Shanxi, ChinaKey Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an University, Xi’an 710064, Shanxi, ChinaDepartment of Civil Engineering, Minnan University of Science and Technology, Shishi 362700, Fujian, ChinaNingbo Xinming Construction Engineering Test Co., Ltd., Ningbo 315000, Zhejiang, ChinaLayered silicates, as bitumen modifiers, have received increasing attention. The main objective of this study was to evaluate the influence of layered silicates on bitumen properties. For this study, montmorillonite (MMT), rectorite (REC), organic montmorillonite (OMMT), and organic rectorite (OREC) were selected. The layered structure type of layered silicates was characterized by SEM (scanning electron microscope) and XRD (X-ray diffraction diffractometer). Tests for determining high-temperature properties included viscosity, DSR (dynamic shear rheometer), and TG (thermogravimetry) tests, and studies for determining the low-temperature properties were conducted by BBR (bending beam rheometer) and DSC (differential scanning calorimetry) tests. Our results show that MMT, REC, OMMT, and OREC were all intercalated structures. OREC had the largest <i>d<sub>001</sub></i> interlayer space, followed by REC, OMMT, and MMT. OREC improved the high-temperature property of virgin bitumen more effectively than OMMT. Meanwhile, REC-modified bitumen exhibited a high-temperature property similar to OMMT-modified bitumen. When compared with REC and OREC, MMT and OMMT were less efficient in reducing the low-temperature properties of virgin bitumen, and OMMT was the least efficient. Therefore, it can be concluded that the nature of pristine layered silicates has a great impact on the high- and low-temperature properties of bitumen. Moreover, organic treatment can simultaneously improve the high- and low-temperature properties of layered silicate-modified bitumens.https://www.mdpi.com/2076-3417/9/17/3563bitumenlayered silicatemontmorilloniterectoritestructureproperty
spellingShingle Meng Jia
Zengping Zhang
Long Wei
Jiange Li
Dongdong Yuan
Xingjiao Wu
Zhiyong Mao
High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate
Applied Sciences
bitumen
layered silicate
montmorillonite
rectorite
structure
property
title High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate
title_full High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate
title_fullStr High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate
title_full_unstemmed High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate
title_short High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate
title_sort high and low temperature properties of layered silicate modified bitumens view from the nature of pristine layered silicate
topic bitumen
layered silicate
montmorillonite
rectorite
structure
property
url https://www.mdpi.com/2076-3417/9/17/3563
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