High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate
Layered silicates, as bitumen modifiers, have received increasing attention. The main objective of this study was to evaluate the influence of layered silicates on bitumen properties. For this study, montmorillonite (MMT), rectorite (REC), organic montmorillonite (OMMT), and organic rectorite (OREC)...
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2019-08-01
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author | Meng Jia Zengping Zhang Long Wei Jiange Li Dongdong Yuan Xingjiao Wu Zhiyong Mao |
author_facet | Meng Jia Zengping Zhang Long Wei Jiange Li Dongdong Yuan Xingjiao Wu Zhiyong Mao |
author_sort | Meng Jia |
collection | DOAJ |
description | Layered silicates, as bitumen modifiers, have received increasing attention. The main objective of this study was to evaluate the influence of layered silicates on bitumen properties. For this study, montmorillonite (MMT), rectorite (REC), organic montmorillonite (OMMT), and organic rectorite (OREC) were selected. The layered structure type of layered silicates was characterized by SEM (scanning electron microscope) and XRD (X-ray diffraction diffractometer). Tests for determining high-temperature properties included viscosity, DSR (dynamic shear rheometer), and TG (thermogravimetry) tests, and studies for determining the low-temperature properties were conducted by BBR (bending beam rheometer) and DSC (differential scanning calorimetry) tests. Our results show that MMT, REC, OMMT, and OREC were all intercalated structures. OREC had the largest <i>d<sub>001</sub></i> interlayer space, followed by REC, OMMT, and MMT. OREC improved the high-temperature property of virgin bitumen more effectively than OMMT. Meanwhile, REC-modified bitumen exhibited a high-temperature property similar to OMMT-modified bitumen. When compared with REC and OREC, MMT and OMMT were less efficient in reducing the low-temperature properties of virgin bitumen, and OMMT was the least efficient. Therefore, it can be concluded that the nature of pristine layered silicates has a great impact on the high- and low-temperature properties of bitumen. Moreover, organic treatment can simultaneously improve the high- and low-temperature properties of layered silicate-modified bitumens. |
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spelling | doaj.art-a28bcb48a1d04f998f88007630751df72022-12-21T19:43:38ZengMDPI AGApplied Sciences2076-34172019-08-01917356310.3390/app9173563app9173563High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered SilicateMeng Jia0Zengping Zhang1Long Wei2Jiange Li3Dongdong Yuan4Xingjiao Wu5Zhiyong Mao6Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an University, Xi’an 710064, Shanxi, ChinaKey Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an University, Xi’an 710064, Shanxi, ChinaZhengzhou Communications Planning Survey & Design Institute, Zhengzhou 450000, Henan, ChinaKey Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an University, Xi’an 710064, Shanxi, ChinaKey Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an University, Xi’an 710064, Shanxi, ChinaDepartment of Civil Engineering, Minnan University of Science and Technology, Shishi 362700, Fujian, ChinaNingbo Xinming Construction Engineering Test Co., Ltd., Ningbo 315000, Zhejiang, ChinaLayered silicates, as bitumen modifiers, have received increasing attention. The main objective of this study was to evaluate the influence of layered silicates on bitumen properties. For this study, montmorillonite (MMT), rectorite (REC), organic montmorillonite (OMMT), and organic rectorite (OREC) were selected. The layered structure type of layered silicates was characterized by SEM (scanning electron microscope) and XRD (X-ray diffraction diffractometer). Tests for determining high-temperature properties included viscosity, DSR (dynamic shear rheometer), and TG (thermogravimetry) tests, and studies for determining the low-temperature properties were conducted by BBR (bending beam rheometer) and DSC (differential scanning calorimetry) tests. Our results show that MMT, REC, OMMT, and OREC were all intercalated structures. OREC had the largest <i>d<sub>001</sub></i> interlayer space, followed by REC, OMMT, and MMT. OREC improved the high-temperature property of virgin bitumen more effectively than OMMT. Meanwhile, REC-modified bitumen exhibited a high-temperature property similar to OMMT-modified bitumen. When compared with REC and OREC, MMT and OMMT were less efficient in reducing the low-temperature properties of virgin bitumen, and OMMT was the least efficient. Therefore, it can be concluded that the nature of pristine layered silicates has a great impact on the high- and low-temperature properties of bitumen. Moreover, organic treatment can simultaneously improve the high- and low-temperature properties of layered silicate-modified bitumens.https://www.mdpi.com/2076-3417/9/17/3563bitumenlayered silicatemontmorilloniterectoritestructureproperty |
spellingShingle | Meng Jia Zengping Zhang Long Wei Jiange Li Dongdong Yuan Xingjiao Wu Zhiyong Mao High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate Applied Sciences bitumen layered silicate montmorillonite rectorite structure property |
title | High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate |
title_full | High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate |
title_fullStr | High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate |
title_full_unstemmed | High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate |
title_short | High- and Low-Temperature Properties of Layered Silicate-Modified Bitumens: View from the Nature of Pristine Layered Silicate |
title_sort | high and low temperature properties of layered silicate modified bitumens view from the nature of pristine layered silicate |
topic | bitumen layered silicate montmorillonite rectorite structure property |
url | https://www.mdpi.com/2076-3417/9/17/3563 |
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