Characterization of localized corrosion pathways in 2195-T8 Al–Li alloys exposed to acidic solution

The corrosion properties of aluminum-lithium (Al–Li) alloys, which are potential materials used to construct for tanks of liquid rockets or missiles, are essential for safe propellant storage and transport. In order to manifest the corrosion resistance of the 2195 Al–Li alloy in practical propellant...

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Main Authors: De-jun Liu, Gan Tian, Guo-feng Jin, Wei Zhang, You-hong Zhang
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2023-07-01
Series:Defence Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2214914722000976
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author De-jun Liu
Gan Tian
Guo-feng Jin
Wei Zhang
You-hong Zhang
author_facet De-jun Liu
Gan Tian
Guo-feng Jin
Wei Zhang
You-hong Zhang
author_sort De-jun Liu
collection DOAJ
description The corrosion properties of aluminum-lithium (Al–Li) alloys, which are potential materials used to construct for tanks of liquid rockets or missiles, are essential for safe propellant storage and transport. In order to manifest the corrosion resistance of the 2195 Al–Li alloy in practical propellant tanks filled with N2O4, the alloy was soaked in 30% nitric acid solution, an accelerating corrosion environment, to test its corrosion behavior. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to characterize microstructure and corrosion morphology of the alloy. Focused ion beam (FIB), combined with SEM, was used to demonstrate localized corrosion features and the propagation of corrosion pathways beneath the alloy surface. It was found that the corrosion network was formed with most intergranular corrosion and sparse intragranular corrosion. Additionally, the distribution and number of intermetallic particles influenced the localized corrosion degree and the direction of corrosion pathways. Aggregated particles made corrosion pathways continuously and caused more severe corrosion. The results from this work were valid and useful to corrosion prevention and protection for storage safety on propellant tanks in N2O4.
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spelling doaj.art-a2caa71f36a8411cb08662f2814356fd2023-07-19T04:23:32ZengKeAi Communications Co., Ltd.Defence Technology2214-91472023-07-0125152165Characterization of localized corrosion pathways in 2195-T8 Al–Li alloys exposed to acidic solutionDe-jun Liu0Gan Tian1Guo-feng Jin2Wei Zhang3You-hong Zhang4Rocket Force University of Engineering, College of Missile Engineering, ChinaCorresponding author.; Rocket Force University of Engineering, College of Missile Engineering, ChinaRocket Force University of Engineering, College of Missile Engineering, ChinaRocket Force University of Engineering, College of Missile Engineering, ChinaRocket Force University of Engineering, College of Missile Engineering, ChinaThe corrosion properties of aluminum-lithium (Al–Li) alloys, which are potential materials used to construct for tanks of liquid rockets or missiles, are essential for safe propellant storage and transport. In order to manifest the corrosion resistance of the 2195 Al–Li alloy in practical propellant tanks filled with N2O4, the alloy was soaked in 30% nitric acid solution, an accelerating corrosion environment, to test its corrosion behavior. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to characterize microstructure and corrosion morphology of the alloy. Focused ion beam (FIB), combined with SEM, was used to demonstrate localized corrosion features and the propagation of corrosion pathways beneath the alloy surface. It was found that the corrosion network was formed with most intergranular corrosion and sparse intragranular corrosion. Additionally, the distribution and number of intermetallic particles influenced the localized corrosion degree and the direction of corrosion pathways. Aggregated particles made corrosion pathways continuously and caused more severe corrosion. The results from this work were valid and useful to corrosion prevention and protection for storage safety on propellant tanks in N2O4.http://www.sciencedirect.com/science/article/pii/S2214914722000976Al-Li alloyCorrosion behaviorCorrosion featuresImmersion testIntermetallic particles
spellingShingle De-jun Liu
Gan Tian
Guo-feng Jin
Wei Zhang
You-hong Zhang
Characterization of localized corrosion pathways in 2195-T8 Al–Li alloys exposed to acidic solution
Defence Technology
Al-Li alloy
Corrosion behavior
Corrosion features
Immersion test
Intermetallic particles
title Characterization of localized corrosion pathways in 2195-T8 Al–Li alloys exposed to acidic solution
title_full Characterization of localized corrosion pathways in 2195-T8 Al–Li alloys exposed to acidic solution
title_fullStr Characterization of localized corrosion pathways in 2195-T8 Al–Li alloys exposed to acidic solution
title_full_unstemmed Characterization of localized corrosion pathways in 2195-T8 Al–Li alloys exposed to acidic solution
title_short Characterization of localized corrosion pathways in 2195-T8 Al–Li alloys exposed to acidic solution
title_sort characterization of localized corrosion pathways in 2195 t8 al li alloys exposed to acidic solution
topic Al-Li alloy
Corrosion behavior
Corrosion features
Immersion test
Intermetallic particles
url http://www.sciencedirect.com/science/article/pii/S2214914722000976
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AT gantian characterizationoflocalizedcorrosionpathwaysin2195t8allialloysexposedtoacidicsolution
AT guofengjin characterizationoflocalizedcorrosionpathwaysin2195t8allialloysexposedtoacidicsolution
AT weizhang characterizationoflocalizedcorrosionpathwaysin2195t8allialloysexposedtoacidicsolution
AT youhongzhang characterizationoflocalizedcorrosionpathwaysin2195t8allialloysexposedtoacidicsolution