μ-2,3,5,6-Tetra-2-pyridylpyrazine-κ3N1,N2,N6:κ3N3,N4,N5-bis[(methanol-κO)(nitrato-κ2O,O′)(nitrato-κO)cadmium(II)]
The title complex, [Cd2(NO3)4(C24H16N6)(CH4O)2], displays a centrosymmetric dinuclear structure, in which the 2,3,5,6-tetra-2-pyridinylpyrazine (tppz) ligand links two Cd ions separated by 7.323 (4) Å. Each CdII center is seven-coordinated by three N-atom donors of tppz...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808022320 |
| _version_ | 1819002767004401664 |
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| author | Mirabdullah Seyed Sadjadi Amin Ebadi Karim Zare Hamid Reza Khavasi Vahid Amani |
| author_facet | Mirabdullah Seyed Sadjadi Amin Ebadi Karim Zare Hamid Reza Khavasi Vahid Amani |
| author_sort | Mirabdullah Seyed Sadjadi |
| collection | DOAJ |
| description | The title complex, [Cd2(NO3)4(C24H16N6)(CH4O)2], displays a centrosymmetric dinuclear structure, in which the 2,3,5,6-tetra-2-pyridinylpyrazine (tppz) ligand links two Cd ions separated by 7.323 (4) Å. Each CdII center is seven-coordinated by three N-atom donors of tppz in one plane, by two O atoms nearly normal to this plane, and by two O atoms 0.393 (3) and 0.488 (3) Å from that plane. The two CdII ions are above and below the plane of the pyrazine ring of the tppz ligand, oriented with respect to the pyridine rings at dihedral angles of 38.01 (3) and 31.90 (3)°. The dihedral angle between the two pyridine rings is 41.11 (3)°. In the crystal structure, intermolecular O—H...O hydrogen bonds link the molecules. |
| first_indexed | 2024-12-20T23:10:20Z |
| format | Article |
| id | doaj.art-a2d35446bd4f4e8eb2be1387314260db |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T23:10:20Z |
| publishDate | 2008-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a2d35446bd4f4e8eb2be1387314260db2022-12-21T19:23:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-08-01648m1050m105110.1107/S1600536808022320μ-2,3,5,6-Tetra-2-pyridylpyrazine-κ3N1,N2,N6:κ3N3,N4,N5-bis[(methanol-κO)(nitrato-κ2O,O′)(nitrato-κO)cadmium(II)]Mirabdullah Seyed SadjadiAmin EbadiKarim ZareHamid Reza KhavasiVahid AmaniThe title complex, [Cd2(NO3)4(C24H16N6)(CH4O)2], displays a centrosymmetric dinuclear structure, in which the 2,3,5,6-tetra-2-pyridinylpyrazine (tppz) ligand links two Cd ions separated by 7.323 (4) Å. Each CdII center is seven-coordinated by three N-atom donors of tppz in one plane, by two O atoms nearly normal to this plane, and by two O atoms 0.393 (3) and 0.488 (3) Å from that plane. The two CdII ions are above and below the plane of the pyrazine ring of the tppz ligand, oriented with respect to the pyridine rings at dihedral angles of 38.01 (3) and 31.90 (3)°. The dihedral angle between the two pyridine rings is 41.11 (3)°. In the crystal structure, intermolecular O—H...O hydrogen bonds link the molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536808022320 |
| spellingShingle | Mirabdullah Seyed Sadjadi Amin Ebadi Karim Zare Hamid Reza Khavasi Vahid Amani μ-2,3,5,6-Tetra-2-pyridylpyrazine-κ3N1,N2,N6:κ3N3,N4,N5-bis[(methanol-κO)(nitrato-κ2O,O′)(nitrato-κO)cadmium(II)] Acta Crystallographica Section E |
| title | μ-2,3,5,6-Tetra-2-pyridylpyrazine-κ3N1,N2,N6:κ3N3,N4,N5-bis[(methanol-κO)(nitrato-κ2O,O′)(nitrato-κO)cadmium(II)] |
| title_full | μ-2,3,5,6-Tetra-2-pyridylpyrazine-κ3N1,N2,N6:κ3N3,N4,N5-bis[(methanol-κO)(nitrato-κ2O,O′)(nitrato-κO)cadmium(II)] |
| title_fullStr | μ-2,3,5,6-Tetra-2-pyridylpyrazine-κ3N1,N2,N6:κ3N3,N4,N5-bis[(methanol-κO)(nitrato-κ2O,O′)(nitrato-κO)cadmium(II)] |
| title_full_unstemmed | μ-2,3,5,6-Tetra-2-pyridylpyrazine-κ3N1,N2,N6:κ3N3,N4,N5-bis[(methanol-κO)(nitrato-κ2O,O′)(nitrato-κO)cadmium(II)] |
| title_short | μ-2,3,5,6-Tetra-2-pyridylpyrazine-κ3N1,N2,N6:κ3N3,N4,N5-bis[(methanol-κO)(nitrato-κ2O,O′)(nitrato-κO)cadmium(II)] |
| title_sort | 956 2 3 5 6 tetra 2 pyridylpyrazine 954 3n1 n2 n6 954 3n3 n4 n5 bis methanol 954 o nitrato 954 2o o 8242 nitrato 954 o cadmium ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808022320 |
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