Hydrogen-bond interactions in morpholinium bromide
In the title compound, C4H10NO+·Br−, which was synthesized by dehydration of diethanolamine with HBr, morpholinium and bromide ions are linked into chains by N—H...Br hydrogen bonds describing a C21(4) graph-set motif. Weaker bifurcated N—H...Br...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811035598 |
| _version_ | 1819294465299316736 |
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| author | Alvaro S. de Sousa Helder M. Marques Manuel A. Fernandes Zolani Mgcima Kamentheren Padayachy |
| author_facet | Alvaro S. de Sousa Helder M. Marques Manuel A. Fernandes Zolani Mgcima Kamentheren Padayachy |
| author_sort | Alvaro S. de Sousa |
| collection | DOAJ |
| description | In the title compound, C4H10NO+·Br−, which was synthesized by dehydration of diethanolamine with HBr, morpholinium and bromide ions are linked into chains by N—H...Br hydrogen bonds describing a C21(4) graph-set motif. Weaker bifurcated N—H...Br interactions join centrosymmetrically related chains through alternating binary graph-set R42(8) and R22(4) motifs, to form ladders along [100]. In addition, C—H...O interactions between centrosymmetric morpholinium cations link ladders, via R^2_2(8) motifs, to yield sheets parallel to (101), which in turn are crosslinked by weak C—H...O interactions, related across a glide plane, to form a three-dimensional network. |
| first_indexed | 2024-12-24T04:26:45Z |
| format | Article |
| id | doaj.art-a2d66bb987ff4748827b1cc817868d1b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T04:26:45Z |
| publishDate | 2011-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a2d66bb987ff4748827b1cc817868d1b2022-12-21T17:15:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710o2594o259410.1107/S1600536811035598Hydrogen-bond interactions in morpholinium bromideAlvaro S. de SousaHelder M. MarquesManuel A. FernandesZolani MgcimaKamentheren PadayachyIn the title compound, C4H10NO+·Br−, which was synthesized by dehydration of diethanolamine with HBr, morpholinium and bromide ions are linked into chains by N—H...Br hydrogen bonds describing a C21(4) graph-set motif. Weaker bifurcated N—H...Br interactions join centrosymmetrically related chains through alternating binary graph-set R42(8) and R22(4) motifs, to form ladders along [100]. In addition, C—H...O interactions between centrosymmetric morpholinium cations link ladders, via R^2_2(8) motifs, to yield sheets parallel to (101), which in turn are crosslinked by weak C—H...O interactions, related across a glide plane, to form a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536811035598 |
| spellingShingle | Alvaro S. de Sousa Helder M. Marques Manuel A. Fernandes Zolani Mgcima Kamentheren Padayachy Hydrogen-bond interactions in morpholinium bromide Acta Crystallographica Section E |
| title | Hydrogen-bond interactions in morpholinium bromide |
| title_full | Hydrogen-bond interactions in morpholinium bromide |
| title_fullStr | Hydrogen-bond interactions in morpholinium bromide |
| title_full_unstemmed | Hydrogen-bond interactions in morpholinium bromide |
| title_short | Hydrogen-bond interactions in morpholinium bromide |
| title_sort | hydrogen bond interactions in morpholinium bromide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811035598 |
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